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LITHOSPHERE (Russia)

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Vol 21, No 5 (2021)
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601-608 525
Abstract

Research subject. Magmatic complexes that are developed in the lower (volcanogenic-sedimentary) part of the Ai Formation of the Lower Riphean of the Taratash anticline in the Southern Urals. Results. For the frst time, the Lower Permian SHRIMP dating (288.6 ± 3.1 Ma by U-Pb method on zircon from monzogabbro) was obtained for a dike cutting the basalts of the Lower Paleozoic (420–450 Ma) age. Conclusions. On the eastern slope of the Urals there is a chain of massifs which are close in the age. The chain belongs to the Lower Permian Stepninsky monzogabbro-granosyenite-granite complex, represented by the Uiski, Vandyshevski, Biryukovski and Stepninski intrusions with the age of 281 ± 2, 280 ± 2 and 286 ± 2 Ma, correspondingly (U-Pb method after zircons, SHRIMP-II, VSEGEI) and earlier obtained dates 281 ± 4 Ma (Rb-Sr isochrone) and 283 ± 2 Ma (isotope Pb-Pb method after zircons). The Stepninsky complex was described earlier as plume-dependent. The monzogabbro dike, described in this paper, although being at a considerable distance from the Sepninsky complex, is situated at a strike of the chain of the stepninsky intrusions, is close to them by the composition and age and can be ascribed to the same plume episode. The idea of the plume character of the complex was ехрressed by us relatively long ago based on a superimposed character of the chain of the intrusions over the earlier, collisional Uralian structures. As for the geochemical character (monzogabbro) the dike conforms with one of two standard trends of the Stepninsky complex – monzonite (monzogabbro, monzodiorites, syenites).

609-624 487
Abstract

Research subject. Organogenic structures such as the Moscowian-Kasimovian skeletal mounds from the Verkhnie vorota section on the Shchuger River (Northern Urals). Materials and methods. The lithological-paleoecological analysis of biohermal limestones and the determination of their fauna in thin sections (60 samples) and polished slabs (10 samples) taken in outcrops 39 on the Shchuger River, 89 m thick. Results. It is revealed that the Middle-Upper Carboniferous skeletal mounds were characterized by a three-level food chain at three stages of their development. Cyanobacteria, calcimicrobes and green algae were the suppliers of organic matter. Their further consumers were bryozoans, brachiopods, fusulinids, small foraminifera and bacteria. Omnivores and predators were absent. It is found that, heterotrophs were the most common organisms at the stabilization stage, while autotrophs were typical of the colonization stage. The paleocenoses of the Kasimovian skeletal mound had a more extensive composition. Here, each developmental stage was represented by two types of paleocenosis, compared to the Moscowian mound. Conclusions. It is found that the main external abiotic factors that controlled the development of the biocenosis in the sites under study were the hydrodynamic regime and sea level fluctuations. An important internal factor was the development of bio-induced cement on the skeletons of organisms, which contributed to the formation of solid frameworks of buildings. Another internal factor was the widespread occurrence of Anchicodiaceae algae, which caused a decrease in the biodiversity of other groups of organisms. The data obtained allowed us to conclude that a shallow sea basin with a good aeration and low hydrodynamic regime existed in this area in the MiddleLate Carboniferous. A decrease in the basin area in the Late Carboniferous was manifested by a reduction in not only algal taxa, but also the biodiversity of the entire ecosystem.

625-643 534
Abstract

Research subject. Terrigenous rocks of the Sargaevo stage of sedimentation in various structural-facies settings within the Tsilma area (Middle Timan). Material and methods. The composition, structural features of rocks, and the species diversity of spores of higher plants were studied in the most complete natural outcrops proposed as a stratotype of the Paladinskaya Formation – a new straton of the Sargaevo age in the Middle Timan. Over a large area of the region, the deposits contain very few remains of fossil fauna, often indifferent. As a result, palynostratigraphy was selected as the main biostratigraphic method. Results. In the Middle Timan, a new straton, the Paladinskaya Formation, is described, which characterizes the Sargaevo stage of sedimentation in various structural-facies settings within the Tsil’ma area. The new straton has clear lithological and detailed palynological characteristics; a description of the limitotypes was performed.

At present, the Paladinskaya Formation is the most complete sequence of Early Frasnian sedimentation in the European North-East of Russia, where it was possible to record regional responses to the global Frasnes event and to determine the position of the controversial level of the boundary between the Middle and Upper Devonian. Conclusions. The name “Ust’e Yarega” Formation in the Middle Timan cannot be considered valid, since it is a homonym of the sediments of the same age in the South Timan. The section is represented mainly by continental, rather than marine, deposits. A new name for the identifed formation is proposed – “Paladinskaya” with a description of the stratum section and limitotype.

The Paladinskaya Formation is characterized by subcomplexes of spores (А and Б) of the regional miospore zone Cristatisporites pseudodeliquescens, which made it possible to correlate the marine and continental deposits of the Early Frasnian on the territory of the entire Timan-Pechora region and establish its exact position in the stratigraphic scheme of the Devonian.

653-659 766
Abstract

Research subject. The mineral compositions of titanomagnetitic (apatite, titanomagnetite) and copper-titanomagnetitic (bornite, chalcopyrite, apatite, titanomagnetite) ores of the Volkovskoe Cu-Fe-Ti-V deposit (Middle Urals, Russia).

Methods. The research was carried out using a Jeol JSM-6390LV scanning electron microscope and X-ray spectral microanalyzers JXA-5 (Jeol) at the Geoanalitik Collective Use Center of the IGG UB RAS. Results and conclusions.

Native gold (with ≤ 0.3 wt % Pd, 0.2–0.4 wt % Cu; fneness 800–914 ‰), tellurides of Pd, Au and Ag (merenskyite, keithconnite, sylvanite, hessite) and Pt arsenide (sperrylite) were found in the copper-titanomagnetitic ores. For the frst time, two generations of native gold (fneness 1000 and 850–860 ‰) and palladium telluride (keithconnite Pd3-xTe) were detected in titanomagnetitic ores. The sequence of ore mineral formation and the features of their genesis were revealed. Native gold (fneness 1000‰) in the form of microinclusions in titanomagnetite was attributed to the magmatic stage. Noble metal minerals, intergrown with copper sulfdes (bornite, chalcopyrite, digenite) and associated with late hydroxyl-bearing minerals (amphibole, epidote, chlorite), are superimposed in relation to the magmatic minerals (pyroxene, plagioclase, hornblende, apatite, titanomagnetite, ilmenite, etc.) of these ores. Merenskyite, sperrylite, high fneness gold (800–914 ‰), as well as carrolite, cobaltite, copper-cobalt telluride and bismuth tellurium-selenide kawazulite Вi2Te2Se are syngenetic with copper sulfdes. The Au-Ag tellurides were deposited later than these minerals. It is shown that the high fugacity of tellurium, which binds Pd, Au, and Ag into tellurides, prevents the occurrence of native gold containing high concentrations of palladium and silver.

660-682 822
Abstract

Research subject. World-class sulphide platinum-group-element (PGE)-Cu-Ni deposits occur within the Noril’sk-Talnakh region of northern Siberia, Russia. The signifcance of these deposits presents opportunities to determine the most effective approaches for the search of similar deposits using commercial PGE-Cu-Ni deposit examples. Materials and methods. Petrological and geochemical analysis of the ultramafc-mafc intrusions of the Noril’sk province ranks them into three types in terms of sulphide mineralization style and economic signifcance: 1) economic intrusions containing unique and large sulphide PGE-Cu-Ni deposits (Oktyabr’sk, Talnakh and Noril’sk-1); 2) subeconomic intrusions that contain small- to medium-sized Cu-Ni sulphide deposits, and medium-sized to large PGE deposits (Chernogorsk, Zub-Marksheider, Vologochan, etc.); 3) uneconomic intrusions that contain low-grade disseminated Cu-Ni ores with ≈0.2 wt % of Cu and Ni, and low Cr and PGE (Nizhny Talnakh, Zelyonaya Griva, etc.). Results and conclusions. Principal sources used in exploration for rich sulphide PGE-Cu-Ni ores include structural, magmatic, stratigraphic-lithological, geochemical, mineralogical, metamorphic and some others. Based on an analysis of isotope-geochemical data, new indicators for locating sulphide PGE-Cu-Ni mineralization are suggested. A restricted range of S-isotope values, and a negative trend for coupled S-Cu isotope compositions can be employed as useful guides to assess the economic potential of a PGE-Cu-Ni sulphide deposit. It is proposed that the Chernogorsk ultramafc-mafc intrusion of the Noril’sk province is the most promising target in a search for rich PGE-Cu-Ni ores. It is suggested that the previously known mineralogical-geochemical and novel isotope-geochemical characteristics of sulphide and silicate minerals are important indicators in assessing the potential ore content of ultramafc-mafc intrusions of the Noril’sk province.

683-698 1081
Abstract

Research subject. The results of studying the geology and mineralogy of the Poldnevskoye deposit of demantoid are presented. Material and methods. The factual material was collected during feld research. Demantoid samples were pro vided by mine owners. Rock and vein minerals were studied in hand specimens, polished specimens and thin sections; the chemical composition was determined by X-ray fluorescence spectroscopy, scanning electron microscopy, electron probe X-ray spectral microanalysis, inductively coupled plasma mass spectrometry with laser sampling (LA-ICP-MS).

Results. The Korkodinsky ultrabasic massif containing the deposit experienced strong decompression and syndecompression mineral formation during the ascent. At an early stage, veins of clinopyroxenite formed in dunite, which also experienced decompression cracking. Then the rocks underwent antigoritization and the appearance of vein antigorite, which was replaced by veins of clinochrysotile (+ magnetite ± carbonate ± demantoid). This was followed by the formation of lizardite (+ magnetite ± carbonate ± demantoid), which also developed along the earlier vein serpentines. Demantoid is represented by rounded grains and rounded grain aggregates with the signs of growth under the conditions of allround extension. The predominant color is brownish-green, yellow-green, rarely green and dark green. Green and dark green demantoids contain Cr2O3 0.52–2.3 wt %. In the central part of some grains and demantoid aggregates, a brown color is observed, which binds to TiO2, the content of which reaches 1 wt %. The demantoids of the Poldnevskoye deposit bear typomorphic features of the Ural-type demantoids (inclusions of the “horse’s tail” type). The distribution of demantoid is nested. The length of the veins with demantoid is frst meters. Their pillar-like shape is assumed. Conclusion.

Demantoids from nests in serpentinized massive or brecciform dunites are more intact; demantoid nests in strongly serpentinized rocks were tectonic crushed and contain little gemstone.

699-711 531
Abstract

Research subject. Deposits of the Upper Jurassic Bazhenov-Georgievsky complex situated in central West Siberian regions. At a frst approximation, the deposits are represented by interlayering pure or carbonatized radiolarites and organic-clay mixites. Materials and methods. A collection of core samples taken from the deposits was analyzed to study the geological and geophysical features of borehole sections, photographs of core samples, and micrographs of thin section. Soft sediment deformations, which appeared within the Bazhenov-Georgievsky complex as a result of earthquakes, were investigated using data obtained by Chinese researchers. Results. It is shown that, at different stages of diagenesis, layers with sharply differing density and mechanical properties came into contact, which led to various deformations of weakly lithifed layers during earthquakes. In the early and middle diagenesis, mobile carbonated radiolarites deformed plastic clay interlayers with the formation of carbonate nodules. In the middle diagenesis, in radiolarites, areas of weak lithifcation and mobile radiolarites coexisted. Along with plastic deformations, the processes of autobrecciation and autofluid fracturing of radiolarites, abrasion erosion of the boundaries of clayey varieties took place. In the late diagenesis, lithifed varieties predominated in radiolarites and clayey silicites; as a result of deformations, radiolarites and the argillaceous bridges separating them were transformed into fragments, polished surfaces, and pellets. If, under the influence of differential loads, fluidization (softening) and movement of weakly lithifed radiolarites occurred, then the rates of such movements in adjacent layers inevitably differed. Each of the described cases is demonstrated by the core material of specifc boreholes and petrographic thin sections. The scale of the phenomenon is shown from the signs of loading of millimeter interlayers to pressure shafts of brecciated limestones with a thickness of 7–10 m. Conclusions. The West Siberian Plate is epicontinental; therefore, the most intense earthquakes occurred at consolidated basement block boundaries during isostatic subduction and compensations in the Neocomian clinoform ultrafast sedimentation zones. Soft sediment deformations occurred within the Bazhenov-Georgievsky layers recorded the rock history of intense seismic events of the past, their temporary and spatial distribution.

712-723 433
Abstract

Research subject. The Sm/Nd isotope system was investigated using inter-laboratory natural samples of apatite, titanite, allanite, monazite, as well as intra-laboratory samples of apatite (from carbonatites, Ilmenogorsk massif, Ural), monazite (from pegmatites of the Aduy granite massif and its framing, Middle Urals) and titanite (from calcite veins, Saranov skoye chromite deposit, Middle Urals and from alkaline pegmatite, Shpat mine, Vishnevy mountains, South Urals). The Sr isotope system was investigated using inter-laboratory natural apatite samples and intra-laboratory apatite samples (from the apatite-carbonate vein, Slyudyanogorskoe deposit, Irkutsk region and from carbonatites, Ilmenogorsk massif, Ural).

Methods. The research was carried using a Neptune Plus multicollector mass spectrometer with inductively coupled plasma (ThermoFisher) equipped with an NWR 213 (ESI) laser ablation attachment, located in a room of ISO class 7 at the “Geoanalyst” Center for Collective Use (IGG Ural Branch of the Russian Academy of Sciences, Ekaterinburg). Results. The article describes methodological approaches for studying Sm/Nd and Sr isotope systems in natural phosphate and silicate minerals by inductively coupled plasma mass spectrometry with laser ablation, implemented on the equipment of the Center for Collective Use “Geoanalyst” (IGG Ural Branch of the Russian Academy of Sciences, Ekaterinburg). A comparative analysis of the obtained results with those reported in literature showed their satisfactory agreement. The developed analytical approaches were used to study apatite samples (analysis of the Sr isotope system) and those of apatite, monazite, titanite (analysis of the Sr isotope system). Conclusions. The developed approaches to the analysis of Sm/Nd and Sr isotopic systems can be recommended for investigating such minerals, as apatite, titanite, allanite, monazite (analysis of the Sm/Nd isotope system); apatite (analysis of the Sr isotope system). The achieved analysis errors allow the results to be used for interpreting various geochemical processes.

724-733 507
Abstract

Research subject. Earthquakes are a global problem for the entire world population. Therefore, a search for ways to predict and prevent tectonic events is a highly relevant task. Despite the existence of controversial opinions on the possibility of predicting tectonic earthquakes, research in this direction continues. Among numerous possible precursors of earthquakes, anomalies in the volume radon activity (VRA) are the most physically justifed ones. The aim of this research was to compare the observed anomalies of soil radon with the recorded seismic events in order to fnd common patterns. The research area was the Kuril Islands. VRA monitoring was conducted at the South Kuril Geophysical Station of the Institute of Marine Geology and Geophysics of the Far Eastern Branch of the Russian Academy of Sciences.

Methods and materials. Measurements were carried out in the advective mode: soil air from a depth of 70 cm was forcibly delivered to the detector using a pump. For a retrospective analysis, we took registered seismic events with a magnitude greater than 4 that occurred within a radius of 500 km from the monitoring station in Yuzhno-Kurilsk during 2011–2018. Statistical data were processed using Microsoft Excel, Statistica software. Results. A method for comparing radon anomalies and earthquakes was developed. Using the developed methodology, it was found that the geodynamic criterion of ≥2 (the ratio of earthquake magnitude to logarithm of distance from event epicenter to the monitoring station in km) can be used when comparing VRA anomalies with tectonic earthquakes. Out of the 166 considered tectonic earthquakes meeting the geodynamic criterion of ≥2.148, the events were preceded by VRA anomalies. The position of the earthquakes was determined relative to the extremum of previous anomalous radon values in the time interval. Eac  of the considered earthquakes meeting the geodynamic criterion ≥2, which had been preceded by a radon anomaly, occurred either after its extremum or coincided with it in time. Conclusions. The manifestation of tectonic earthquakes in VRA anomalies after passing the extremum can be considered as a short-term prognostic criterion and be used for distinguishing between “near” and “far” events.

734-742 387
Abstract

Research subject and methods. The seismicity of the Krilyon Peninsula (Sakhalin Island) after the earthquake on April 23, 2017 (M = 5.0) during the 2018–2021 period was investigated by the method of self-developing processes (SDP).

Results. The seismic activity showed a damping trend after the earthquake (and several following aftershocks), with the activation of SDP seismicity observed in two cases. In the study area (40 km within the radius from the epicenter of the Krillon earthquake) and its immediate vicinity (up to 80 km), earthquakes with M = 3.9 and M = 4.3 were observed 74 and 26 days after seismic activations. These earthquakes are considered to be the strongest events occurred in the study area in the period under consideration. The results of the study were compared with the monitoring data of the Kamchatka branch of the Geophysical Survey Russian Academy of Sciences (KB GS RAS) on the volumetric activity of subsoil radon (OA Rn). It was revealed that the OA Rn anomalies detected in November 2018 and January 2020 had appeared several weeks after the identifed SDP. The anomalies were registered at observation points remote from the study area (as well as from the above-mentioned earthquakes) by no more than 50 km. Earthquakes in 2018 (M = 3.9) and 2020 (M = 4.3) occurred 19 and 32 days after the appearance of OA Rn anomalies. In general, the current situation can be assessed as calm, since, according to the analysis data, the seismic activity has no prerequisites for the transition from the decaying stage to the stage of stabilization. As shown in the work, this is a sign for preparing an earthquake with a magnitude higher than 5. Nevertheless, activation and (as a result) earthquakes of moderate strength (M < 5) are possible on a damping trend. Conclusion. It is proposed to take into account the self-developing processes of activation as a primary sign for a change in the geodynamic state of the environment, under which the appearance of OA Rn anomalies is possible. These anomalies are associated with the forecast of moderate seismicity during foreshock or aftershock activations.



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ISSN 1681-9004 (Print)
ISSN 2500-302X (Online)