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Au-Ag-Pd-Pt mineralization in sedimentary rocks associated with Triassic carbonaceous silicites of Sikhote-Alin

https://doi.org/10.24930/1681-9004-2018-18-6-892-913

Abstract

Subject. The paper is devoted to the study of the gold-silver-palladium-platinum mineralization of the streaky systems in the sedimentary rocks associated within the Triassic carbonaceous silicites of the Taukhinsky and Samarkinsky terranes of the Sikhote-Alin. Materials and methods. In the process of investigations we studied the metamorphosed carbonaceous siliceous-clay rocks and systems of the mineralized fractures in the Triassic siliceous-clay and siliceous (including jaspers) rocks of Shirokopadninskaya, Vysokogorskaya and Gornaya areas, as well as in the sandstones (unclarified age) of Gornaya area. The samples for the analytical study were taken with the lump way. To estimate the content of precious metals in the rocks, cut by the systems of the mineralized fractures, we used the fire assay and atomic-absorption methods. The analyses of minerals (in polished sections) have been done using the JXA-5A and JXA8100 microanalysers. Results. The gold-silver-palladium-platinum mineralization in the siliceous and clay-siliceous rocks, as well as in the sandstones is restricted to the systems of the mineralized fractures and by many features are analogous to the precious-metal mineralization of the black-shale formations. It is represented by native forms, disordered solid solutions, and intermetallic compounds of different metals. The specificity of the Au-Ag-Pd-Pt mineralization is a wide distribution of copper gold, Ni-, Cu-, and Pbbearing gold, and Zn-bearing platinum. Native elements and intermetallic compounds, including those of precious metals, are not rarely associated with the organic matter testifying to the active participation of carbon and, probably, hydrogen that provided the high- and ultra-reduction character of the processes of mineral formation. Conclusions. The presence of the mineral forms of different maximum reduced metals is caused by the influence of the organic matter of the Triassic carbonaceous silicites. This consisted in the removal of the most volatile components, and first of all the poorly bound water and hydrocarbons from the carbonaceous rocks through the contact metamorphism related with the injection of the granitoid intrusions of Cretaceous plutonic and volcanoplutonic belts.

About the Authors

Valentin T. Kazachenko
Far Eastern Geological Institute, Far Eastern Branch of the Russian Academy of Sciences
Russian Federation
159 Vladivostok 100th Anniversary, Vladivostok 690022


Elena V. Perevoznikova
Far Eastern Geological Institute, Far Eastern Branch of the Russian Academy of Sciences
Russian Federation
159 Vladivostok 100th Anniversary, Vladivostok 690022


References

1. Ashley P.M. (1975) Opaque mineral assemblage formed during serpentinization in the Coolac ultramafic belt, New South Wales. J. Geol. Soc. Australia, 22, 91-102.

2. Clarc A.H., Sillitoe R.H. (1970) Native Zn and α-Cu, Zn from mina Dulcinea de Llampos, Copiapo, Chile. Amer. Miner., 55(5-6), 1019-1021.

3. Damdinov B.B., Zhmodik S.M., Mironov A.G., Ochirov Yu.Ch. (2004) Precious-metal mineralization in rodingites of the southwestern part of the East Sayan. Geol. Geofiz., 45(5), 577-587. (In Russian)

4. Delura K. (2005) Magnetite-nickel sulphides-awaruite associations in serpentinites from Braszowice-Brzeznica massif (Sudetic ophiolite, SW Poland). 12 Meeting of the Petrology Group of the Mineralogical Society of Poland. “Crystalline Rocks of the East-European Craton”, Scientific Communications. Krakow, Univ. SI, 147-150.

5. Distler V.V., Mitrofanov G.L., Semeikina L.K., Nemerov V.K., Kovalenker V.A., Mokhov A.V., Yudovskaya M.A. (1996) Forms of occurrence of the platinum group metals and their genesis at the Sukhoy Log gold deposit (Russia). Geol. Rudn. Mestorozhd., 38(6), 467- 484. (In Russian)

6. Erokhin Yu.V., Ivanov K.S., Kozlov P.S., Shagalov E.S. (2004). Native iron from ultrabasic detrital rocks (Petrovsky mine, the Middle Urals). Ural’skaya mineralogicheskaya shkola-2004 “Pod znakom shchelochnykh pegmatitov” [Urals Mineralogical School-44 “Under Signe of alkaline pegmatites”]. Ekaterinburg, Urals St. Univ. Publ., 84-85. (In Russian)

7. Erokhin Yu.V., Shagalov E.S. (2005). Awaruite from the Bazhenovo ophiolite complex. VI Vserossiiskie nauchnye chteniya pamyati Il’menskogo mineraloga V.O. Polyakova [IV Oll-Russian sci. Conf. in memory Ilmeny mineralogist V.O. Polyakov]. Miass, IMin UrO RAN Publ., 23-26. (In Russian)

8. Geodinamika, magmatizm i metallogeniya Vostoka Rossii [Geodynamics, magmatism, and metallogeny of East Russia]. (2006) Book 1 (Ed. A.I. Khanchuk). Vladivostok, Dal’nauka Publ., 572 p. (In Russian)

9. Gorshkov A.I., Bershov L.V., Titkov S.V., Vinokurov S.F., Ryabchikov I.D., Magazina L.O., Sivtsov A.V., Teilor V.R. (2003) Features of mineral inclusions and admixtures in diamonds from lamproites of Argail Pipe (West Australia). Geokhimiya, (12), 1251-1261. (In Russian)

10. Kazachenko V.T., Lavrik S.N., Perevoznikova E.V., Skosareva N.V. (2015) Gabbroids of the Sergeevsky and Kalinovsky complexes of the Sikhote-Alin: geochemistry and isotope ratios of samarium, neodymium, strontium, and lead. Vestnik Kol’skogo nauchnogo tsentra RAN, 3(22), 21-39. (In Russian)

11. Kazachenko V.T., Miroshnichenko N.V., Perevoznikova E.V., Karabtsov A.A. (2008) Mineral forms of precious metals in metal-bearing deposits of the TriassicJurassic carbonaceous bed of the Sikhote-Alin. Dokl. Akad. Nauk, 421(3), 383-386. (In Russian)

12. Kazachenko V.T., Perevoznikova E.V., Lavrik S.N. (2016) Geochemical and isotopic “marks” of ancient gabbroids in the Triassic metamorphosed metal-bearing sediments, skarns, and ores of skarn deposits of the Sikhote-Alin. Vestn. Kol’skogo NTs RAN, 4(27), 16-36. (In Russian)

13. Kazachenko V.T., Sapin V.I. (1990) Mineralogiya i genesis zhelezo-margantsevogo orudeneniya Pribrezhnoi zony Primor’ya [Mineralogy and genesis of the ironmanganese mineralization of Pribrezhnaya zone of Primorye]. Vladivostok, DVO AN SSSR Publ., 248 p. (In Russian)

14. Khanchuk A.I., Plyusnina L.P., Molchanov V.P., Medvedev E.I. (2007) Native metals in graphite rocks of Khanka terrane. Chteniya, posvyashchennye pamyati akademika K.V. Simakova. Tezisy dokl. Vserossiiskoi konf. [Conf. in memory Akademician K.V. Simakov. Thesis of reports]. Magadan, 107-108.

15. (In Russian) Kudryavtseva A.I., Kudryavtsev V.I. (2003) Occurrence of copper and silver gold in precious-metal mineralization of the South Tuva ultrabasite belt. Geoecologiya prirodnoi sredy i obshchestva [Geoecology of the natural environment and society]. Kyzyl, TuvIKOPR, SO RAN Publ., 45-48. (In Russian)

16. Miroshnichenko N.V., Perevoznikova E.V. (2010) Ni3Au intermetallic compound and solid solutions of gold and nickel in the metamorphosed metal-bearing sediments of the Triassic silicic formation of the Sikhote-Alin. Tikhookean. Geol., 29(1), 60-66. (In Russian)

17. Murzin V.V., Sazonov V.N., Varlamov D.A., Shanina S.I. (2006) Gold mineralization in rodingites of the massifs of alpine-type ultrabasites. Litosfera, (1), 113-134. (In Russian)

18. Novgorodova M.I. (1983) Samorodnye mineraly v gidrotermalnykh rudakh [Native minerals in hydrothermal ores]. Мoscow, Nauka Publ., 288 p. (In Russian)

19. Park J. (1981) Occurrence of Native Zinc at Hape Creek, Thames. Trans. N.Z. Inst., ХХIV, 386.

20. Perevoznikova E.V. (2010) Margantsevosilikatnye porody Yuzhnogo Sikhote-Alinya: mineralogiya i genesis. Dis. kand. geol.-min. nauk [Manganese-silicated rocks of the South Sikhote-Alin: mineralogy and genesis. Cand. geol. and min. sci. diss.]. Vladivostok, 192 p. (In Russian)

21. Petrovskii V.A., Karfunkel’ I., Martins M., Lyutoev V.P., Glukhov Yu.V., Sukharev A.E., Filippov V.N., Magazina L.O. (2004) Morphological and substructural struture of natural carbonado. Poverkhnost’. Rent., sikhrotron. neitron. Issled., (9), 73-85. (In Russian)

22. Petrovskii V.A., Martins M., Karfunkel’ I., Samoilovich M.I., Belyankin A.F., Lyutoev V.P., Sukharev A.E., Glukhov Yu.V. (2003) Carbonado: physical properties, mineral inclusions, and formation conditions. “Vysokie tekhnologii v promyshlennosti Rossii (materially i ustroistva elektronnoi tekhniki)”. Materialy IX Mezhdunarodnoi nauchno-tekhnicheskoi konferentsii [“High technologies in the industry of Russia (materials and devices of electronic equipment)”. Materials 9 Intern. scientific-techn. Conf. V. 2]. Moscow, 206-220. (In Russian)

23. Reith F., Zammit C.M., Shar S.S. et al. (2016) Biological role in the transformation of platinum-group mineral grains. Nat. Geosci., 9(4), 294.

24. Spiridonov E.M., Pletnev P.A. (2002) Mestorozhdenie medistogo zolota Zolotaya gora (o “zoloto-rodingitovoi” formatsii) [Zolotaya Gora copper-gold deposit (about “gold-rodingite” formation)]. Moscow, Nauchnyi Mir Publ., 220 p. (In Russian)

25. Titkov S.V., Gorshkov A.I., Solodova Yu.P., Ryabchikov I.D., Magazina L.O., Sivtsov A.V., Gasanov M.D., Samosorov G.G. (2005) Carbonate inclusions in imperfect diamonds from the Yakutia deposits on the data of the analytical electron microscopy. “Mineralogicheskie issledovaniya v reshenii geologicheskikh problem”. Materialy Godichnogo sobraniya MO RMO [Mineralogical researches in the solution of geological problems. Materials of the Annual Meeting of Moscow Department Russ. Mineral. Soc.]. Moscow, VIMS Publ., 124-125. (In Russian)

26. Titkov S.V., Gorshkov A.I., Solodova Yu.P., Ryabchikov I.D., Magazina L.O., Sivtsov A.V., Gasanov M.D., Sedova E.A., Samosorov G.G. (2006) Mineral microinclusions in diamonds of cubic habit from the deposits of Yakutia from the data of the analytical electron microscopy. Dokl. Akad. Nauk, 410(2), 255- 258. (In Russian)

27. Tishchenko A.I. (2003) Native metals in kimberlites of the East Azov area. “Sovremennye problemy formatsionnogo analiza, petrologiya i rudonosnost’ magmaticheskikh obrazovanii”. Tezisy dokl. Vserossiiskogo soveshchaniya, posvyashchennogo 100-letiyu so dnya rozhdeniya akademika Ju.A. Kuznetsova [Modern problems of formation analysis, petrology and orebearing magmatic formations. Abstracts of rep. AllRussia Conf., dedicated 100th anniversary of the birth of Academician Yu.A. Kuznetsov]. Novosibirsk, Branch of GEO Publ., 329-330. (In Russian)

28. Tishchenko A.I. (2005) Finding of native aluminium in Ukraine. Mineralogicheskii zhurnal, 27(10), 38-43. (In Russian)

29. Volokhin Yu.G., Ivanov V.V. (2007) Geochemistry and metal content of the Triassic carbonaceous silicites of the Sikhote-Alin. Litol. Polezn. Iskop., (4), 406-425. (In Russian)

30. Volokhin Yu.G., Karabtsov A.A. (2016) Minerals in the Triassic carbonaceous silicites of the Sikhote-Alin. Litol. Polezn. Iskop., (5), 465-484. (In Russian)

31. Volokhin Yu.G., Mikhailik E.V., Buriy G.I. (2003). Triasovaya kremnevaya formatsiya Sikhote-Alinya [The Triassic silicic formation of the Sikhote-Alin]. Vladivostok, Dal’nauka Publ., 252 p. (In Russian)

32. Zhmodik S.M., Mironov A.G., Derevenets V.G., Agafonov L.V., Ochirov Yu.Ch. (1998) A new type of the tingold-(mercury)-platinum-bearing ore mineralization in the East Sayan. Dokl. Akad. Nauk, 361(4), 510-513. (In Russian)


Review

For citations:


Kazachenko V.T., Perevoznikova E.V. Au-Ag-Pd-Pt mineralization in sedimentary rocks associated with Triassic carbonaceous silicites of Sikhote-Alin. LITHOSPHERE (Russia). 2018;(6):892-913. (In Russ.) https://doi.org/10.24930/1681-9004-2018-18-6-892-913

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