Carbon and oxygen isotopic composition of Paleozoic carbonate deposits of the Pechora Sea
https://doi.org/10.24930/2500-302X-2026-26-1-100-121
EDN: LIVVWN
Abstract
Research subject. Paleozoic carbonate complexes in the offshore area of the Timan–Pechora oil and gas basin.
Aim. To evaluate the possibility of using data on the isotopic composition of carbon and oxygen in carbonate rocks for the interpretation of depositional environments and stratigraphic correlation of geological sections.
Materials and methods. Within the framework of the RN-Shelf-Arctic LLC (RNSHA) regional projects focused on a geological study of offshore areas, the isotopic composition of carbon and oxygen of Paleozoic carbonate deposits from the core of five wells were analyzed.
Results. The value of δ13Ccarb increases up the section from -5.9‰ in S2 to 6.0‰ in P1a-s. The most significant weighting of δ13Ccarb from -1 to 6‰ occurred in the Upper Carboniferous interval. The variations of δ18Ocarb from 23 to 33‰ are characterized by the absence of a general trend along the section combined with more frequent and abrupt excursions, which are most pronounced in the Carboniferous.
Discussion and conclusion. Four local factors of isotopic variations were considered, including mineral, facial, post-sedimentary, and stratigraphic. Two of them – depositional environments and secondary (postdepositional) changes – are regarded as the major factors, being controlled in varying degrees on different stages by either local or global factors. The final result of their influence was integral and expressed by the “stratigraphic” curve of isotopic composition variability.
Keywords
About the Authors
E. O. MalyshevaRussian Federation
Elena O. Malysheva
10/2 Shabolovka st., Moscow 119049
S. A. Gorbunova
Russian Federation
Sonya A. Gorbunova
10/2 Shabolovka st., Moscow 119049
M. S. Doronina
Russian Federation
Mariya S. Doronina
10/2 Shabolovka st., Moscow 119049
G. V. Ulyanov
Russian Federation
Grigory V. Ulyanov
10/2 Shabolovka st., Moscow 119049
References
1. Antoshkina A.I. (2015) Ooid-stromatolite association – a stress for benthic ecosystems. Izv. vuzov. Geologiya i razvedka, (3), 19-25. (In Russ.) https://doi.org/10.32454/0016-7762-2015-3-19-25
2. Antoshkina A.I., Shmeleva L.A., Leonova L.V., Dobretsova I.G., Smoleva I.V. (2021) Genetically different organogenic build-ups in isotopic composition of δ13С and δ18О. Vestn. geonauk, 11(323), 27-42. (In Russ.) https://doi.org/10.19110/geov.2021.11.3
3. Basharan M. (2011) Environmental Isotope Geochemistry: Past, Present and Future. Handbook of Environmental Isotope Geochemistry. Berlin, Heidelberg, 3-10. https://doi.org/10.1007/978-3-642-10637-8_1
4. Belyaev A.A., Kuleshov V.N. (1994) Isotopic composition and origin of carbonate manganese ores of the Kara PaiKhoi zone. Tr. IG Komi NTS UrO RAN, vyp. 84, 71-84. (In Russ.)
5. Beznosova T.M., Matveev V.A., Shamsutdinova L.L. (2020) New data on stratigraphy and renewed correlation scheme of the Upper Ordovician and Silurian of TimanPechora oil and gas province and Northern Urals. Izv. Komi NTS UrO RAN. Ser.: Nauki o Zemle, 46(6), 75-89. https://doi.org/10.19110/1994-5655-2020-6-75-89
6. Beznosova T.M., Myannik P., Maidl’ T.V. (2006). Depositional сonditions and faunas in the Landovery–Wenlock boundary interval (Chernov Swell). Syktyvkar: Vestn. IG Komi NTs UrO RAN (10), 11-15. (In Russ.)
7. Clayton R.N., Degens E.T. (1959) Use of carbon isotope analysis of carbonates in differentiating freshwater and marine sediments. Bull. AAPG, 43(4), 890-897.
8. Degens E.T. (1971) Distribution of stable isotopes in carbonates. Earth Sciences, v. 30: Carbonate rocks: physico-chemical characteristics and research methods, v. 2, 141-153. (In Russ.)
9. Erofeevskii A.V., Zhuravlev A.V. (2019) Prospects of application of the isotopic stratigraphic method (δ13Ccarb) for correlation of the Upper Devonian-Carboniferous interval in the east of the Timan-Pechora province. Neftegazovaia geologiia. Teoriia i praktika, 14(1), 7-17. (In Russ.) https://doi.org/10.17353/2070-5379/9_2019
10. Esteban M., Klappa C.F. (1983) Subaerial exposure environment. Carbonate depositional environments. AAPG Mem., 33, 1-54.
11. Galimov E.M. (1968) Geochemistry of stable carbon isotopes. Moscow, Nedra Publ., 226 p. (In Russ.)
12. Galimov E.M. (2016) Periods of glaciation and oil generation in the early history of the Earth: a common cause. Biosfera (Russia), 8(2), 134-142. (In Russ.)
13. Getsen V.G., Dedeev V.A., Zaporozhtseva I.V., Kuznetsov A.G., Malyshev N.A., Ryzhov I.N., Timonin N.I., Udot G.D., Yudin V.V. (1982) Geological structure of the sedimentary cover of the European North of the USSR. Leningrad, Nauka Publ., 200 p. (In Russ.)
14. Grossman E.L. (2012) Oxygen Isotope Stratigraphy. The Geologic Time Scale. Amsterdam, Elsevier, 181-206. https://doi.org/10.1016/B978-0-444-59425-9.00010-X
15. Hudson J.D. (1977) Stable isotopes and limestone lithification. J. Geol. Soc., (133), 637-660. https://doi.org/10.1144/gsjgs.133.6.0637
16. Inkina N.S. (2024) Isotopic composition of carbon and oxygen of the Lower Permian carbonate rocks of the Losinoostrovsky formation (Circumpolar Urals, Kozhym River). Vestn. geonauk, (3), 3-14. (In Russ.) https://doi.org/10.19110/geov.2024.3.1
17. Keith M.L., Weber J.N. (1964) Carbon and oxygen isotopic composition of selected limestones and fossils. Geochim. Cosmohim. Acta, 28(11), 1787-1816. https://doi.org/10.1016/0016-7037(64)90022-5
18. Kuleshov V.N. (2001) Evolution of isotopic carbon dioxidewater systems in lithogenesis. Report 1. Sedimentogenesis and diagenesis. Litologiia i polez. iskopaemye, (5), 491-508. (In Russ.)
19. Kuleshov V.N. (2013) Manganese rocks and ores: isotope geochemistry, origin and evolution of ore formation. Moscow, Nauchnyi Mir Publ., 508 p. (In Russ.)
20. Kuleshov V.N., Aref’ev M.P., Pokrovskii B.G. (2019) Isotope features (δ13С, δ18О) of continental carbonates from the Permian-Triassic boundary deposits of the northeastern Russian plate: paleoclimatic and biotic causes, chemostratigraphy. Litologiia i polez. iskopaemye, (6), 568-591. (In Russ.)
21. Maidl’ T.V., Beznosov P.A. (2011). Carbon and oxygen isotope composition and the distribution of strontium in the Lower Famennian section of Izhma river (South Timan). Vestn. IG Komi NTs UrO RAN, (4), 4-8. (In Russ.)
22. Maidl’ T.V., Kotik I.S. (2017) Lithological and geochemical characteristics of the Silurian isotope event Mulde expression in the section of the Padymeityvis (Chernov’s swell). Geodynamics, matter, and ore genesis in the East European Platform and its folded framework. Proc. AllRuss. Sci. Conf. Syktyvkar, IG Komi NTS UrO RAN, 105-107. (In Russ.)
23. Maidl’ T.V., Zhemchugova V.A., Naumchev IU.V. (2018) Geochemical background for the identification of the pre-Frasnian unconformity in the Devonian section of the Timan-Pechora sedimentary basin. Vestn. IG Komi NTs UrO RAN, (9), 30-38. (In Russ.) https://doi.org/10.19110/2221-1381-2018-9-30-38
24. Makhnach A.A. (2000) Stage analysis of lithogenesis. Minsk, BGU, 255 p. ((In Russ.)
25. Malysheva E.O., Sukhanov N.V. (1986) Specifics of the carbon and oxygen isotopic composition of sandstones carbonate cements in the Pechora oil and gas basin. Tez. dokl. The All-Union Geological Symposium on Isotope Geochemistry. Moscow, GEOKhI, 230-231. (In Russ.)
26. Malysheva E.O., Vol’fovich E.M., Gorbunova S.A., Nikiforova O.G., Nikishin V.A. (2020) Depositional environments of Late Paleozoic and Mesozoic sediments of the Russian sector of the Barents Sea based on sedimentological studies. Neftianoe khoziaistvo, (4), 10-16. (In Russ.) https://doi.org/10.24887/0028-2448-2020-4-10-16
27. Malysheva E.O., Zhemchugova V.A., Maidl T.V., Malyshev N.A., Ryabinkina N.N. (1998). Regional unconformities and chronostratigraphy of Paleosoic deposites of Pechora basin. Tr. IG Komi NTs UrO RAN, vyp. 97: Geology of fossil fuels of the European North, 71-84. (In Russ.)
28. Matveeva N.A. (2023) Isotopic composition and formation of the Famenian carbonatoliths of the Central Khoreyversky swell (Khoreyverskaya depression, Pechora Plate). Vestn. geonauk, (11), 37-47. (In Russ.) https://doi.org/10.19110/geov.2023.11.4
29. McCreat J.M. (1950) On the Isotopic Chemistry of Carbonates and a Paleotemperature Scale. J. Chem. Phys., 18(6), 849-857. http://doi.org/10.1063/1.1747785
30. Prishchepa O.M., Bogatskii V.I., Makarevich V.N., Chumakova O.V., Nikonov N.I., Kuranov A.V., Bogdanov M.M. (2011) New view on the tectonic and oil and gas geological zoning of the Timan-Pechora oil and gas province. Neftegazovaia geologiia. Teoriia i praktika, 6(4), 1-33. (In Russ.)
31. Qie W.K., Zhang X.H., Du Y.S., Zhang Y. (2011) Lower Carboniferous carbon isotope stratigraphy in South China: Implications for the Late Paleozoic glaciation. Sci. China Earth Sci. 54, 84-92.
32. Rejmers A.N., Alekseev A.S., Ermakova Yu.V. (2013) Late Carboniferous – Late Permian climatic fluctuations and biotic events. Byul. MOIP. Otd. Geol., 88(1), 41-48. (In Russ.)
33. Rozian’skii K., Gonf’iantini R. (1990) Isotopes in climatological research. Bull. MAGATE, (4), 10-16. (In Russ.)
34. Saltzman M.R., Thomas E. (2012) Carbon Isotope Stratigraphy. The Geologic Time Scale. Amsterdam, Elsevier, 207-232. https://doi.org/10.1016/B978-0-444-59425-9.00011-1
35. Silaev V.I., Khazov A.F. (2003) Isotopic disproportionation of carbonate carbon in the processes of hypergenicexogenous rearrangement of the Earth’s crust matter. Syktyvkar, Geoprint Publ., 41 p. (In Russ.)
36. Swart P.K. (2015) The geochemistry of carbonate diagenesis: The past, present and future. Sedimentology, (62), 1233-1304. https://doi.org/10.1111/sed.12205
37. Teis R.V., Naidin D.P. (1973) Paleothermometry and oxygen isotopic composition of organogenic carbonates. Moscow, Nauka Publ., 256 p. (In Russ.)
38. Teplov E.L., Kostygova P.K., Larionova Z.V., Beda I.Iu., Dovzhikova E.G., Kuranova T.I., Nikonov N.I., Petrenko E.L., Sрabanova G.A. (2011) Natural reservoirs within oil and gas complexes of Timan-Pechora province. Saint Petersburg, Renome Publ., 286 p. (In Russ.)
39. Yudovich Ya.E. (1988) Anomalous lightening of organic carbon in ancient black shales. Goriuchie Slantsy, 5(2), 147-151. (In Russ.)
40. Yudovich Ya.E., Belyaev A.A., Ketris M.P. (1998) Geochemistry and ore genesis of the black shales of the Pai Khoi. Saint Petersburg, Nauka Publ., 366 p. (In Russ.)
41. Yudovich Ya.E., Ketris M.P. (2010) Carbon isotope ratios in the stratosphere and biosphere: four scenarios. Biosfera, 2(2), 231-246. (In Russ.)
42. Yudovich Ya.E., Sukhanov N.V. (1984) Isotopically anomalous carbonates in Paleozoic black shales of Pai Khoi. Dokl. AN SSSR, 275(2), 445-449. (In Russ.)
43. Zhao Z., Wang J., Wan P. (2017) Carbon and oxygen isotope variation and its implication for marine sequence: A case study of Ordovician in Tarim basin. Petrol. Res., (2), 281-290. https://doi.org/10.1016/j.ptlrs.2017.02.002
44. Zhuravlev A.V. (2023) Carbon isotopic composition of Early Famenian conodonts and carbonates of the Izhma Formation (Southern Timan). Neftegazovaia geologiia. Teoriia i praktika, 18(3), 1-19. (In Russ.) https://doi.org/10.17353/2070-5379/35_2023
Review
For citations:
Malysheva E.O., Gorbunova S.A., Doronina M.S., Ulyanov G.V. Carbon and oxygen isotopic composition of Paleozoic carbonate deposits of the Pechora Sea. LITHOSPHERE (Russia). 2026;26(1):100-121. (In Russ.) https://doi.org/10.24930/2500-302X-2026-26-1-100-121. EDN: LIVVWN
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