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Bulan gold-sulfide-quartz ore deposit of the Makarovsky ore cluster (Western Sayan, Russia): Mineralogical and geochemical features, formation conditions, and fluid sources

https://doi.org/10.24930/2500-302X-2025-25-3-619-632

EDN: FORYQE

Abstract

Research subject. Mineralogical and geochemical features and formation conditions of the Bulan gold-sulfide-quartz ore occurrence of the Makarov ore cluster in the Western Sayan.

Methods. A Linkam TMS-600 thermostage and Olympus BX 51 optical microscope were used to determine temperatures, compositions, and fluid salinities in inclusions of mineral- forming fluid in quartz of gold-sulfide-quartz veins (SUSU, Miass, analyst Natalia N. Ankusheva). The chemical composition of gold was determined by SEM Hitachi TM-1000 (TuvIENR SB RAS, Kyzyl, analyst Renat V. Kuzhuget).

Results. The conducted mineralogical and geochemical studies determined that gold formation at the Bulan ore field was single-stage in the form of gold-sulfide-quartz veins and veins with pyrite, chalcopyrite, arsenopyrite, pyrrhotite, as well as rare isolations of galena, fahlore, gold, and electrum. The results of fluid inclusion study from gold-sulfide-quartz veins showed that they were formed in the temperature range 170–230°C due to a weakly to moderately saline (3.5–6.8 wt % NaCl eq.) magmatic fluid of the K-Na-Mg±Fe-chloride composition. The stable range of fluid salinity and the narrow range of δ18O indicate a single magmatic source and insignificant influence of host rocks and meteoric waters. Conclusions. According to mineralogical and geochemical features and PT parameters, the Bulan ore occurrence is similar to low-sulfide deposits of gold-sulfide-quartz berezite-listvenite formation.

About the Authors

N. N. Ankusheva
SU FRC MG UB RAS
Russian Federation

Ilmensky Reserve, Miass, Chelyabinsk Region 456317



R. V. Kuzhuget
Tuvinian Institute for Exploration of Natural Resources, SB RAS
Russian Federation

117a Internatsionalnaya st., Kyzyl 667007



М. М. Balanay
Tuvinian Institute for Exploration of Natural Resources, SB RAS
Russian Federation

117a Internatsionalnaya st., Kyzyl 667007



References

1. Afifi A.M., Kelly W.C., Essene E.J. (1988) Phase relations among tellurides, sulphides and oxides: I. Thermochemical data and calculated equilibria. Econ. Geol., 83, 377-404.

2. Artem’ev D.S. (2018) Ore content of hydrothermal-metasomatic formations of the May Ore Field (Chukotka Autonomous Okrug). Abstract. diss. ... Cand. Geol. Sci. St.Petersburg, 20 p.

3. Barton P.B., Skinner B.J. (1979) Sulfide mineral stabilities. Geochemistry of Hydrothermal Ore Deposits. (Ed H.L. Barnes). N.Y., Sley & Sons, 278-403.

4. Belogub E.V., Melekestseva I.Yu., Novoselov K.A., Zabotina M.V., Tret’yakov G.A., Zaykov V.V., Yuminov A.M. Listvenite-related gold deposits of the South Urals (Russia): a review. Ore Geol. Rev., 85, 247-270.

5. Berzin N.A., Coleman R.G., Dobretsov N.L., Zonenshain L.P., Xiao Xuchang, Chang E.Z. (1994) Geodynamic map of the western part of Paleoasian Ocean. Russ. Geol. Geophys., 35, 5-22.

6. Berzin N.A., Kungurtsev L.V. (1996) Geodynamic interpretation of Altai-Sayan geological complexes. Russ. Geol. Geophys., 37, 56-73.

7. Bodnar R.J., Vityk M.O. (1994) Interpretation of microthermometric data for H2O–NaCl fluid inclusions. Fluid Inclusions in Minerals: Methods and Applications. (Eds B. De Vivo, M.L. Frezzotti). Blacksburg, Virginia Tech, 117-130.

8. Borisenko A.S. (1982) Analysis of the salt composition of solutions of gas-liquid inclusions in minerals by cryometry. The use of thermobarogeochemistry methods in the search and study of ore deposits. (Ed. N.P. Laverov). Moscow, Nedra Publ., 37-46.

9. Bowers T.S. (1991) The deposition of gold and other metals. Pressure-induced fluid immiscibility and associated stable isotope signatures. Geochim. Cosmochim. Acta, 55, 2417-2434. https://doi.org/10.1016/0016-7037(91)90363-A

10. Davis D.W., Lowenstein T.K., Spenser R.J. (1990) Melting behavior of fluid inclusions in laboratory-grown halite crystals in the systems NaCl-H2O, NaCl-KCl-H2O, NaCl-MgCl2-H2O, and CaCl2-NaCl-H2O. Geochim. Cosmochim. Acta, 54, 591-601.

11. Hoefs J. (2009) Stable Isotope Geochemistry. Berlin; Heidelberg, Springer, 281 s.

12. Kornev T.Ya., Еkhanin A.G., Vlasov A.P. (2018) Geology and gold content of the Kurtushibinsky greenstone belt (Western Sayan). Krasnoyarsk, GPKK KNIIGiMS Publ., 244 p.

13. Kuzhuget R.V., Ankusheva N.N., Redina A.A., Prokop’ev I.R., Butanaev Yu.V., Ondar Kh.Kh (2019) Gold composition and PTX formation conditions of the Tardan-2 gold-sulphide-quartz ore manifestation in beresites (Eastern Tuva). Geologiya i Mineral’nye Resursy Sibiri, 4, 89-104. (In Russ.)

14. Kuzhuget R.V., Ankusheva N.N., Redina A.A., Prokop’ev I.R., Ponomarchuk A.V. (2021) Khaak-Sair gold-sulfidequartz ore occurrence (Western Tuva): dating, PT parameters, fluid composition, and isotopes of S, O and C. Izvestiya Tomskogo Politekhnicheskogo Universitetа. Inginiring Georesursov, 332(12), 148-163. (In Russ.)

15. LeFort D., Hanley J., Guillong M. (2011) Subepithermal AuPd mineralization associated with an alkalic porphyry Cu–Au deposit, Mount Milligan, Quesnel Terrane, British Columbia, Canada. Econ. Geol., 106, 781-808.

16. Li Y., Liu J. (2006) Calculation of sulfur isotope fractionation in sulfides. Geochim. Cosmochim. Acta, 70, 1789- 1795.

17. Melekestseva I.Yu., Zaikov V.V., Tret’yakov G.A., Filippova K.A., Kotlyarov V.A. (2019) Geological structure and mineralogy of the Mechnikovskoye gold deposit, Southern Urals. Litosphere (Russia), 19(1), 111-138.

18. Ohmoto H. (1986) Stable isotope geochemistry of ore deposits. In: Stable Isotopes in High Temperature Geological Processes. Rev. Mineral. Geochem., 16, 491-560.

19. Ohmoto H., Rye R.O. (1979) Isotopes of Sulfur and Carbon. Geochemistry of Hydrothermal Ore Deposits. N. Y., Wiley, 509-567.

20. Popov G.G., Popov B.G., Muratshin H.H., Miziryak D.G. (2017) Petrochemical characterization of igneous rocks and hydrothermal-metasomatic formations of the Kedrovskoye gold ore field. Razvedka i Okhrana Nedr, 9, 27-32.

21. Redder E. (1978) Fluid inclusions in minerals. V. 1. Moscow, Mir Publ., 360 p. (In Russ.)

22. Rudnev S.N., Serov P.A., Kiseleva V.Yu. (2015) Vendian – Early Paleozoic granitoid magmatism in Eastern Tuva. Russ. Geol. Geophys., 56(9), 1232-1255.

23. Semenov M.I., Zorina A.N., Kolyamkin V.M., Kachevskii L.K., Krotova T.A., Aleksandrovskii Yu.S. (2019) State Geological Map of the Russian Federation scale 1:200 000. Ed. 2nd Edition. Zapadno-Sayanskaya. Sheet N-46-XXXIV (Turan). He’ll explain. note / Ministry of Natural Resources of Russia, Rosnedra, FSBI VSEGEI, JSC Sibirskoe PGO. SPb.: VSEGEI, 188 p., ill. 13. (In Russ.)

24. Spiridonov E.M. (2010) Review of gold mineralogy in major types of Au mineralization, in: Gold of the Kola Peninsula and Adjacent Regions. Proceedings of the Russian (with Non-Russian Participants) Conference Dedicated to the 80th Anniversary of the Kola Scientific Center (Russian Academy of Sciences). Apatity, K&M Publ., 143-171. (In Russ.)

25. Van den Kerkhof A.M., Hein U.F. (2001) Fluid inclusion petrography. Lithos, 55(1) 27-White N.C., Hedenquist J.W. (1995) Epithermal gold deposits: styles, characteristics, and exploration. Soc. Econ. Geol. Newslett., 23, 9-13.

26. Wilkinson J.J. (2001) Fluid inclusions in hydrothermal ore deposits. Lithos, 55, 229-272.

27. Yarmolyuk V.V., Kovalenko V.I. (2003) Deep Geodynamics and Mantle Plumes: their role in the formation of the Central Asian fold belt. Petrology, 11(6), 504-531.

28. Zabotina M.V., Ankusheva N.N., Shanina S.N., Kotlyarov V.A. (2018) Conditions of formation of the Ganeevsky gold deposit, Uchalinsky ore district: mineralogical thermometry and the study of fluid inclusions. Mineralogiya, 4, 55-67. (In Russ.)

29. Zhang L.-G., Liu J.-X., Zhou H.B., Chen Z.-S. (1989) Oxygen isotope fractionation in the quartz-water-salt system. Econ. Geol., 89, 1643-1650.

30. Zheng Y.F. (1999) Oxygen isotope fractionation in carbonate and sulfate minerals. Geochem. J., 33, 109-126.


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For citations:


Ankusheva N.N., Kuzhuget R.V., Balanay М.М. Bulan gold-sulfide-quartz ore deposit of the Makarovsky ore cluster (Western Sayan, Russia): Mineralogical and geochemical features, formation conditions, and fluid sources. LITHOSPHERE (Russia). 2025;25(3):619-632. (In Russ.) https://doi.org/10.24930/2500-302X-2025-25-3-619-632. EDN: FORYQE

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