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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">litosphere</journal-id><journal-title-group><journal-title xml:lang="ru">Литосфера</journal-title><trans-title-group xml:lang="en"><trans-title>LITHOSPHERE (Russia)</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1681-9004</issn><issn pub-type="epub">2500-302X</issn><publisher><publisher-name>A.N. Zavaritsky Institute of Geology and Geochemistry</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.24930/1681-9004-2025-25-6-1298-1323</article-id><article-id custom-type="edn" pub-id-type="custom">PLPJHJ</article-id><article-id custom-type="elpub" pub-id-type="custom">litosphere-2415</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Статьи</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>Articles</subject></subj-group></article-categories><title-group><article-title>Минералого-геохимическая зональность и массоперенос между водонасыщенными габбро худолазовского комплекса и песчаниками зилаирской свиты (Восточный Бускун, Южный Урал)</article-title><trans-title-group xml:lang="en"><trans-title>Mineralogical and geochemical zoning and mass transfer between the Khudolaz complex water-saturated gabbro and the Zilair Formation sandstones (Vostochnyi Buskun, Southern Urals)</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Михеев</surname><given-names>Е. И.</given-names></name><name name-style="western" xml:lang="en"><surname>Mikheev</surname><given-names>E. I.</given-names></name></name-alternatives><bio xml:lang="ru"><p>630090; пр-т Академика Коптюга, 3; Новосибирск</p></bio><bio xml:lang="en"><p>Evgeny I. Mikheev</p><p>630090; 3 Academician Koptyug av.; Novosibirsk</p></bio><email xlink:type="simple">mikheev@igm.nsc.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Рахимов</surname><given-names>И. Р.</given-names></name><name name-style="western" xml:lang="en"><surname>Rakhimov</surname><given-names>I. R.</given-names></name></name-alternatives><bio xml:lang="ru"><p>450077; ул. Карла Маркса, 16/2; Уфа; 620110; ул. Академика Вонсовского, 15; Екатеринбург</p></bio><bio xml:lang="en"><p>Ildar R. Rakhimov</p><p>450077; 16/2 Karl Marx st.; Ufa; 620110; 15 Academician Vonsovsky st.; Ekaterinburg</p></bio><xref ref-type="aff" rid="aff-2"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru">Институт геологии и минералогии им. В.С. Соболева СО РАН<country>Россия</country></aff><aff xml:lang="en">V.S. Sobolev Institute of Geology and Mineralogy, SB RAS<country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru">Институт геологии УФИЦ РАН; Институт геологии и геохимии им. академика А.Н. Заварицкого УрО РАН<country>Россия</country></aff><aff xml:lang="en">Institute of Geology, UFRC RAS; A.N. Zavaritsky Institute of Geology and Geochemistry, UB RAS<country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2025</year></pub-date><pub-date pub-type="epub"><day>26</day><month>12</month><year>2025</year></pub-date><volume>25</volume><issue>6</issue><fpage>1298</fpage><lpage>1323</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Михеев Е.И., Рахимов И.Р., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Михеев Е.И., Рахимов И.Р.</copyright-holder><copyright-holder xml:lang="en">Mikheev E.I., Rakhimov I.R.</copyright-holder><license license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://www.lithosphere.ru/jour/article/view/2415">https://www.lithosphere.ru/jour/article/view/2415</self-uri><abstract><sec><title>   Объект исследования</title><p>   Объект исследования. Породы контактового ореола многофазного габброидного массива Восточный Бускун худолазовского дифференцированного комплекса (Южный Урал).</p></sec><sec><title>   Цель</title><p>   Цель. Установить особенности геохимического взаимодействия между магматическим телом и вмещающими вулканогенно-осадочными породами, определить физико-химические условия метаморфизма и метасоматоза, выявить минералого-геохимическую зональность разреза приконтактовой области, оценить металлогенический потенциал роговиков.</p></sec><sec><title>   Материалы и методы</title><p>   Материалы и методы. Минералы пород эндо- и экзоконтакта изучены методами оптической и сканирующей электронной микроскопии, валовый состав пород определен методами РФА и ИСП МС. Температуры контактового метаморфизма определены с помощью биотитового и хлоритового геотермометров.</p></sec><sec><title>   Результаты</title><p>   Результаты. В строении массива Восточный Бускун установлено несколько типов габброидов. Контактовый ореол массива сложен тремя главными типами пород, отвечающими взаимодействию между такситовыми лейкогаббро массива и вмещающей вулканогенно-терригенной толщей: гиперстеновые и клинопироксеновые роговики, непосредственно контактирующие с породами массива, и chl ± ms ± bt роговики, слагающие бóльшую часть экзоконтакта. Клинопироксеновые роговики, по сравнению с более удаленными от контакта роговиками, испытали привнос Ca, Sr, вынос Ti, Fe, Mg, Li, Rb, Ba. Особенности минерального и химического состава гиперстеновых роговиков отвечают основным магматическим породам и показывают сходство с беербахитами. Убогая рудная минерализация в породах эндо- и экзоконтакта представлена ильменитом, сульфидами меди и железа, в том числе платиносодержащим пирротином в хлорит-слюдяных роговиках.</p></sec><sec><title>   Выводы</title><p>   Выводы. Массив Восточный Бускун формировался как минимум в три петрогенетические фазы, что отразилось на многоэтапности метаморфического и метасоматического изменения вмещающих пород. Формирование контактового ореола связано с внедрением флюидонасыщенных такситовых оливин-роговообманковых лейкогаббро второй фазы, непосредственно контактирующих с вмещающей вулканогенно-осадочной толщей. Формирование приконтактовой области происходило в два этапа: высокотемпературный этап (526–616 °C) с образованием пегматоидных обособлений в габбро, гиперстеновых, клинопироксеновых и биотитсодержащих роговиков; низкотемпературный этап (253–458 °C), с которым связано внедрение долеритовых даек и пропилитовых кварц-хлорит-альбитовых жил, а также замещение биотита хлоритом. Наличие хлористых апатита и амфибола указывает на участие в метасоматозе хлорсодержащего флюида, а особенности массопереноса рудных элементов свидетельствуют об отсутствии сульфидных рудных тел под зоной контакта в составе массива Восточный Бускун.</p></sec></abstract><trans-abstract xml:lang="en"><sec><title>   Research subject</title><p>   Research subject. The contact aureole rocks of the Vostochnyi Buskun multiphase gabbroic intrusion of the Khudołaz differentiated complex (Southern Urals).</p></sec><sec><title>   Aim</title><p>   Aim. To study geochemical interactions between the magmatic body and host volcanogenic-sedimentary rocks, to determine the physicochemical conditions of metamorphism and metasomatism, to identify mineralogical and geochemical zoning of the contact aureole, and to assess the metallogenic potential of the rocks.</p></sec><sec><title>   Materials and methods</title><p>   Materials and methods. Minerals were studied by optical and scanning electron microscopy; the bulk composition of rocks was determined by XRF and ICP–MS. Contact metamorphism temperatures were determined using biotite and chlorite geothermometers.</p></sec><sec><title>   Results</title><p>   Results. Several types of gabbroids in the Vostochnyi Buskun massif have been identified. The contact aureole of the massif is composed of three main types of rocks, corresponding to the interaction between taxitic leucogabbro and host volcanogenic-terrigenous rocks: hypersthene and clinopyroxene hornfelses in direct contact with the intrusion rocks, and chl ± ms ± bt hornfelses, forming the greater part of the exocontact. Clinopyroxene metasomatites, in comparison with more distant from the contact hornfelses, are characterized by an addition of Ca and Sr, and removal of Ti, Fe, Mg, Li, Rb, and Ba. The mineral and chemical composition of hypersthene hornfelses correspond to mafic igneous rocks and show similarities with beerbachites. Poor ore mineralization in the contact aureole rocks is represented by ilmenite, copper, and iron sulfides, including platinum-bearing pyrrhotite in chlorite-mica hornfelses.</p></sec><sec><title>   Conclusion</title><p>   Conclusion. The Vostochnyi Buskun massif was formed via at least three petrogenetic phases, which resulted in the multi-stage metamorphic and metasomatic alteration of host rocks. The contact aureole formation is associated with injection of second-phase fluid-saturated taxitic olivine-hornblende leucogabbro, which were in direct contact with the host volcanogenic-sedimentary strata. The contact aureole formed in two stages: (1) a high-temperature stage (526–616 °C) accompanied by pegmatoid segregations in gabbro, hypersthene, clinopyroxene, and biotite-bearing hornfelses; and (2) a low-temperature stage (253–458 °C), which is associated with dolerite dikes and propylitic quartz-chlorite-albite veins, as well as chlorite replacing biotite. The presence of chlorine-containing apatite and amphibole indicate the participation of chlorine-bearing fluid in metasomatism, while the features of the mass transfer of ore elements indicate the absence of sulfide ore bodies under the Vostochnyi Buskun massif contact zone.</p></sec></trans-abstract><kwd-group xml:lang="ru"><kwd>Южный Урал</kwd><kwd>водонасыщенные габбро</kwd><kwd>массив Восточный Бускун</kwd><kwd>контактовый метаморфизм</kwd><kwd>метасоматоз</kwd><kwd>роговик</kwd><kwd>беербахит</kwd></kwd-group><kwd-group xml:lang="en"><kwd>Southern Urals</kwd><kwd>Vostochnyi Buskun massif</kwd><kwd>water-saturated gabbro</kwd><kwd>contact metamorphism</kwd><kwd>metasomatism</kwd><kwd>hornfels</kwd><kwd>beerbachite</kwd></kwd-group><funding-group xml:lang="ru"><funding-statement>Исследование выполнено за счет гранта Российского научного фонда № 22-77-10049, https://rscf.ru/project/22-77-10049 и за счет государственных заданий ИГМ СО РАН (№ госрегистрации 122041400044-2) и ИГГ УрО РАН (№ госрегистрации 123011800009-9)</funding-statement></funding-group><funding-group xml:lang="en"><funding-statement>The research was supported by the Russian Science Foundation grant No. 22-77-10049, https://rscf.ru/project/22-77-10049 and by the state assignments of the Institute of Geology and Mineralogy SB RAS (state registration No. 122041400044-2) and the Institute of Geology and Geochemistry UB RAS (state registration No. 123011800009-9)</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Бучковский Э.С., Перминов Г.М., Калташов А.П., Караваев И.Н. (1971ф) Оценка никеленосности основных интрузий Худолазовского комплекса. Отчет о результатах работ, проведенных Худолазовской геолого-поисковой партией в северной части Баймакского и южной части Абзелиловского районов БАССР. Уфа: ГосГеолФонд. Т. 1. Инв. № 8235.</mixed-citation><mixed-citation xml:lang="en">Barton M.D., Ilchik R.P., Marikos M.A. (1991) Ch. 7. Metasomatism. Contact metamorphism. (Eds D.M. Kerrick). Berlin, Boston: De Gruyter, 321-350. doi: 10.1515/9781501509612-010</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Бучковский Э.С., Перминов Г.М., Крестинин Б.А., Караваев И.Н., Петров Ю.Н. (1974ф) Оценка никеленосности основных интрузий Худолазовского комплекса. Отчет по объекту “Худолазовская синклиналь. Поиски масштаба 1:50 000 сульфидных медно-никелевых руд” : в 8 т. Уфа: ГосГеолФонд. Т. 1, 240 с. Инв. № 9028.</mixed-citation><mixed-citation xml:lang="en">Boynton W.V. (1984) Cosmochemistry of Rare Earth Elements: meteorite studies. (Ed. P. Henderson). Rare Earth Element Geochemistry. N. Y.: Elsevier, 63-114. doi: 10.1016/B978-0-444-42148-7.50008-3</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Врублевская Т.Т., Цыганков А.А., Орсоев Д.А. (2003) Контактово-реакционные процессы в Нюрундуканском ультрамафит-мафитовом массиве (Северное Прибайкалье). Геология и геофизика, 44(3), 207-223.</mixed-citation><mixed-citation xml:lang="en">Bucher K. (2023) Petrogenesis of Metamorphic Rocks. Springer, 467 p. doi: 10.1007/978-3-031-12595-9</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Горячев Н.А. (2003) Происхождение золото-кварцевых жильных поясов Севера Пацифики. Магадан: СВКНИИ ДВО РАН, 143 с.</mixed-citation><mixed-citation xml:lang="en">Buchkovskii E.S., Perminov G.M., Kaltashov A.P., Karavaev I.N. (1971f) Evaluation of nickel-bearing capacity of basic intrusions of the Khudolazovsky complex. Report on the results of work carried out by the Khudolazovsky geological prospecting party in the northern part of the Baimaksky and southern part of the Abzelilovsky districts of the Bashkir ASSR. Ufa, GosGeol-Fond. V. 1. Inv. No. 8235. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Захарова А.А. (1982ф) Петрология и металлогения раннекаменноугольной габбро-плагиогранитной формации на восточном склоне Ю. Урала (худолазовский комплекс). Научный отчет по теме “Условия формирования и метаморфизм магматогенных комплексов Южного Урала” : в 3 т. Уфа: ИГ БФ АН СССР. Т. 1, 429 с. Инв. № 10913.</mixed-citation><mixed-citation xml:lang="en">Buchkovskii E.S., Perminov G.M., Krestinin B.A., Karavaev I.N., Petrov Yu.N. (1974f) Evaluation of nickel-bearing capacity of basic intrusions of the Khudolazovsky complex. Report on the object “Khudolazovskaya syncline. Prospecting for 1:50 000 scale sulfide copper-nickel ores” : in 8 volumes. Ufa, GosGeolFond. V. 1, 240 p.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Знаменский С.Е. (2009) Структурные условия формирования коллизионных месторождений золота восточного склона Южного Урала. Уфа: Гилем, 348 с.</mixed-citation><mixed-citation xml:lang="en">Chashchin V.V. (2007) Mineral assemblages and genesis of hornfelses in the outer contact zone of the Khibina Massif, Kola Peninsula, Russia. Geochem. Int., 45(1), 15-31 (translated from Geokhimiya, (1), 19-37). doi: 10.1134/S0016702907010028</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Классификация и номенклатура метаморфических горных пород. (1992) (Ред. Н.Л. Добрецов, О.А. Богатиков, О.М. Розен). Новосибирск: ОИГГМ, 205 с.</mixed-citation><mixed-citation xml:lang="en">Classification and nomenclature of metamorphic rocks. Reference manual. (1992) (Eds N.L. Dobretsov, O.A. Bogatikov, O.M. Rosen). Novosibirsk, OIGGM Publ., 205 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Кокшина Л.В. (2013) Постдиагенетические преобразования петрокластических граувакк (на примере среднего палеозоя Южного Урала и юга Западной Сибири). Автореф. … дисс. канд. геол.-мин. наук. Екатеринбург, 23 с.</mixed-citation><mixed-citation xml:lang="en">Crerar D.A., Susak N.J., Borcsik M., Schwartz S. (1978) Solubility of the buffer assemblage pyrite + pyrrhotite + magnetite in NaCl solutions from 200 to 350 °C. Geochim. Cosmochim. Acta, 42(9), 1427-1437. doi: 10.1016/0016-7037(78)90048-0</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Малюкова Н.Н. (2018) Распределение редкоземельной минерализации по типам руд на разведочных горизонтах месторождения Кутессай-II. Междунар. науч.-исслед. журн., 6-1(72), 97-104. doi: 10.23670/IRJ.2018.72.6.019</mixed-citation><mixed-citation xml:lang="en">Dasgupta S., Bhowmik S.K. (2021) Types of Metamorphism. Encyclopedia of Geology, 2&lt;sup&gt;nd&lt;/sup&gt; ed. (Eds D. Alderton, S.A. Ellias). London, Academic Press, 354-365. doi: 10.1016/B978-0-08-102908-4.00114-4</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Михеев Е.И., Рахимов И.Р., Шапаренко Е.О., Сорока Е.И. (2025) Метасоматоз и РЗЭ-минерализация осадочных пород зилаирской свиты в зоне экзоконтакта габбрового массива худолазовского комплекса (Чебаркульская площадь, Южный Урал). Изв. Томского политехн. ун-та. Инжиниринг георесурсов, 336(1), 123-138. doi: 10.18799/24131830/2025/1/4584</mixed-citation><mixed-citation xml:lang="en">Fazliakhmetov A.M. (2021) Frasnian greywackes of the Khudolaz Syncline. Message 3. Brief description of geochemistry. Geol. Vestnik, (2), 83-105. (In Russ.) doi: 10.31084/2619-0087/2021-2-7</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Монтин С.А., Левина Н.Б., Батрак И.Е. и др. (2015) Государственная геологическая карта Российской Федерации. М-б 1:200 000. Изд-е второе. Сер. Южно-Уральская. Лист N-40-XXIX – Сибай. Объяснит. записка. М.: МФ ВСЕГЕИ, 218 с. + 14 вкл. (МПР России, Федеральное агентство по недропользованию, Управление по недропользованию по Челябинской области, ФГУНПП “Аэрогеология”).</mixed-citation><mixed-citation xml:lang="en">Frolova T.I., Burikova I.A. (1997) Magmatic formations of modern geotectonic settings: Tutorial. Moscow, MGU Publ., 320 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Рахимов И.Р., Анкушева Н.Н., Холоднов В.В. (2020) Co-Pd-Ag и Th-REE минерализация вмещающих пород экзоконтактовой зоны массива Ташлы-Тау Худолазовского комплекса (Южный Урал): условия образования и источники вещества. Изв. Томского политехн. ун-та. Инжиниринг георесурсов, 331(8), 77-91. doi: 10.18799/24131830/2020/7/2770</mixed-citation><mixed-citation xml:lang="en">Goryachev N.A. (1998) Geology of Mesozoic Gold Quartz Vein Belts in Northeastern Asia. Magadan, SVKNII DVO RAN Publ., 210 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Рахимов И.Р., Васильев А.М., Самигуллин А.А. (2024) Условия образования золоторудного проявления Билян-Тау (Худолазовская мульда, Южный Урал). Вестник Воронежск. гос. ун-та. Сер.: Геол., (3), 21-31. doi: 10.17308/geology/1609-0691/2024/3/21-31</mixed-citation><mixed-citation xml:lang="en">Kelemen P.B., Hanghøj K., Greene A.R. (2014) One View of the Geochemistry of Subduction-Related Magmatic Arcs, with an Emphasis on Primitive Andesite and Lower Crust. Treatise on Geochemistry (Second Ed.). (Eds H.D. Holland, K.K. Turekian). Elsevier, 749-806. doi: 10.1016/B978-0-08-095975-7.00323-5</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Ревердатто В.В. (1970) Фации контактового метаморфизма. (Ред. В.С. Соболев). М.: Недра, 272 с.</mixed-citation><mixed-citation xml:lang="en">Kitsault Molybdenum Project. British Columbia, Canada. NI 43-101 Technical Report on Feasibility Study. (2010) (Prepared by: G. Christie, G. Kulla, R. Ulansky, T. Lipiec, P. Healy, M. Levy, B. Borntraeger). Project No.: 165003, 208 p.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Ревердатто В.В., Лиханов И.И., Полянский О.П., Шеплев В.С., Колобов В.Ю. (2017) Природа и модели метаморфизма. (Отв. ред. Н.В. Соболев). Новосибирск: Изд-во СО РАН, 331 с.</mixed-citation><mixed-citation xml:lang="en">Kokshina L.V. (2013) Postdiagenetic transformations of petroclastic graywackes (on the example of the Middle Paleozoic of the Southern Urals and the south of Western Siberia). Abstr. of Cand. Geol.-Min. Sci. Ekaterinburg, 23 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Салихов Д.Н., Пшеничный Г.Н. (1984) Магматизм и оруденение зоны ранней консолидации Магнитогорской эвгеосинклинали. Уфа: БФАН СССР, 112 с.</mixed-citation><mixed-citation xml:lang="en">Lanari P., Wagner T., Vidal O. (2014) A thermodynamic model for di-trioctahedral chlorite from experimental and natural data in the system MgO–FeO–Al&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;3&lt;/sub&gt;–SiO&lt;sub&gt;2&lt;/sub&gt;–H&lt;sub&gt;2&lt;/sub&gt;O: applications to P–T sections and geothermometry. Contrib. Mineral. Petrol., 167, 968. doi: 10.1007/s00410-014-0968-8</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Семёнов И.В., Яковлева О.М. (1994) Роговики юго-восточного обрамления габбрового массива горы Кумба – апогаббровые бластокатаклазиты или экзоконтактовые аповулканогенные образования? Тр. ИГГ УрО РАН, вып. 141, 29-34.</mixed-citation><mixed-citation xml:lang="en">Liu Y., Brenan J. (2015) Partitioning of platinum-group elements (PGE) and chalcogens (Se, Te, As, Sb, Bi) between monosulfide-solid solution (MSS), intermediate solid solution (ISS) and sulfide liquid at controlled fO&lt;sub&gt;2&lt;/sub&gt;–fS&lt;sub&gt;2&lt;/sub&gt; conditions. Geochim. Cosmochim. Acta, 159, 139-161. doi: 10.1016/j.gca.2015.03.021</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Серавкин И.Б., Знаменский С.Е., Косарев А.М. (2001) Разрывная тектоника и рудоносность Башкирского Зауралья. Уфа: Полиграфкомбинат, 318 с.</mixed-citation><mixed-citation xml:lang="en">Lu Z.Y., Jeffrey M.I., Zhu Y., Lawson F. (2000) Studies of pentlandite leaching in mixed oxygenated acidic chloride-sulfate solutions. Hydrometallurgy, 56(1), 63-74. doi: 10.1016/S0304-386X(00)00067-0</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Скляров Е.В., Лавренчук А.В., Федоровский В.С., Гладкочуб Д.П., Донская Т.В., Котов А.Б., Мазукабзов А.М., Старикова А.Е. (2020) Региональный и контактовый метаморфизм и автометаморфизм Ольхонского террейна, Западное Прибайкалье. Петрология, 28(1), 55-71. doi: 10.31857/S0869590320010057</mixed-citation><mixed-citation xml:lang="en">Malyukova N.N. (2018) Rare-earth mineralization distribution by ore types at exploration horizons of Kutessai-II deposit. Mezhdunar. Nauchno-Issledov. Zhurnal, 6-1(72), 97-104. (In Russ.) doi: 10.23670/IRJ.2018.72.6.019</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Фазлиахметов А.М. (2021) Франские граувакки Худолазовской мульды. Сообщение 3. Краткая геохимическая характеристика. Геол. вестник, (2), 83-105. doi: 10.31084/2619-0087/2021-2-7</mixed-citation><mixed-citation xml:lang="en">Mikheev E.I., Rakhimov I.R., Shaparenko E.O., Soroka E.I. (2025) Metasomatism and REE mineralization of the Zilair Formation sedimentary rocks in the Khudolaz complex gabbro massif exocontact zone (Chebarkul area, Southern Urals). Izv. Tomsk. Politekhn. Universiteta. Inginiring Georesursov, 336(1), 123-138. (In Russ.) doi: /10.18799/24131830/2025/1/4584</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Фролова Т.И., Бурикова И.А. (1997) Магматические формации современных геотектонических обстановок. М.: Изд-во МГУ, 320 с.</mixed-citation><mixed-citation xml:lang="en">Montin S.A., Levina N.B., Batrak I.E. et al. (2015) State Geological Map of the Russian Federation. Scale 1:200,000. Second edition. South Ural Series. Sheet N-40-XXIX – Sibay. Explanatory note. Moscow, MF VSEGEI Publ., 218 p. + 14 incl. (Ministry of Natural Resources of Russia, Federal Agency for Subsoil Use, Subsoil Use Administration for the Chelyabinsk Region, FSUE “Aerogeology”). (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Цабадзе Дж.Э., Гуфранов Р.А., Александров Ю.А., Цабадзе Г.А., Жариков В.Г., Марченко Т.А., Кавыева М.Х. (1984ф) Геологическое строение Сибайского рудного района. Отчет по геологическому доизучению м-ба 1:50 000 Сибайской площади (планшеты N-40-106-В-в, г; N-40-118-А; N-40-118-В; N-40-130-А-а, б) за 1980–1984 гг. в 5 т. Уфа. Т. 1, 271 с. Инв. № 11504.</mixed-citation><mixed-citation xml:lang="en">Rakhimov I.R., Ankusheva N.N., Kholodnov V.V. (2020) Co-Pd-Ag and Th-REE mineralization of host rocks from the exocontact zone of Tashly-Tau massif, Khudolaz complex (South Urals): ore sources and fluid inclusions data. Izv. Tomsk. Politekhn. Universiteta. Inginiring Georesursov, 331(8), 77-91. (In Russ.) doi: 10.18799/24131830/2020/7/2770</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Чащин В.В. (2007) Минеральные парагенезисы и условия образования роговиков зоны экзоконтакта Хибинского щелочного плутона (Кольский полуостров, Россия). Геохимия, (1), 19-37.</mixed-citation><mixed-citation xml:lang="en">Rakhimov I.R., Ankusheva N.N., Samigullin A.A., Shanina S.N. (2023) Origin and Evolution of Ore-Forming Fluids at the Small-Sized Gold Deposits in the Khudolaz Area, Southern Urals. Minerals, 13(6), 781. doi: 10.3390/min13060781</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Юдович Я.Э., Кетрис М.П. (2000) Основы литохимии. СПб.: Наука, 479 с.</mixed-citation><mixed-citation xml:lang="en">Rakhimov I.R., Vasil’ev A.M., Samigullin A.A. (2024) Formation of the Bilyan-Tau gold ore occurrence (Khudolaz trough, Southern Urals). Proceedings of Voronezh State University. Ser.: Geology, (3), 21-31. (In Russ.) doi: 10.17308/geology/1609-0691/2024/3/21-31</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Barton M.D., Ilchik R.P., Marikos M.A. (1991) Ch. 7. Metasomatism. Contact metamorphism. (Eds D.M. Kerrick). Berlin, Boston: De Gruyter, 321-350. doi: 10.1515/9781501509612-010</mixed-citation><mixed-citation xml:lang="en">Rakhimov I.R., Vishnevskiy A.V., Saveliev D.E. (2021) Geochemical evolution of PGE-sulfide mineralization of the Khudolaz differentiated complex in the South Urals: The role of R-factor and hydrothermal alteration. Ore Geol. Rev., 104411. doi: 10.1016/j.oregeorev.2021.104411</mixed-citation></citation-alternatives></ref><ref id="cit26"><label>26</label><citation-alternatives><mixed-citation xml:lang="ru">Boynton W.V. (1984) Cosmochemistry of Rare Earth Elements: meteorite studies. (Ed. P. Henderson). Rare Earth Element Geochemistry, N. Y.: Elsevier, 63-114. doi: 10.1016/B978-0-444-42148-7.50008-3</mixed-citation><mixed-citation xml:lang="en">Reverdatto V.V. (1970) Facies of contact metamorphism. (Ed. V.S. Sobolev). Moscow, Nedra Publ., 272 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit27"><label>27</label><citation-alternatives><mixed-citation xml:lang="ru">Bucher K. (2023) Petrogenesis of Metamorphic Rocks. Sprin ger, 467 p. doi: 10.1007/978-3-031-12595-9</mixed-citation><mixed-citation xml:lang="en">Reverdatto V.V., Likhanov I.I., Polyanskii O.P., Sheplev V.S., Kolobov V.Yu. (2017) The nature and models of metamorphism. (Ed. N.V. Sobolev). Novosibirsk, Publishing House of the Siberian Branch of the Russian Academy of Sciences, 331 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit28"><label>28</label><citation-alternatives><mixed-citation xml:lang="ru">Crerar D.A., Susak N.J., Borcsik M., Schwartz S. (1978) Solubility of the buffer assemblage pyrite + pyrrhotite + magnetite in NaCl solutions from 200 to 350 °C. Geochim. Cosmochim. Acta, 42(9), 1427-1437. doi: 10.1016/0016-7037(78)90048-0</mixed-citation><mixed-citation xml:lang="en">Salikhov D.N., Pshenichnyi G.N. (1984) Magmatism and mineralization of the early consolidation zone of the Magnitogorsk eugeosyncline. Ufa, BFAN SSSR Publ., 112 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit29"><label>29</label><citation-alternatives><mixed-citation xml:lang="ru">Dasgupta S., Bhowmik S.K. (2021) Types of Metamorphism. Encyclopedia of Geology, 2&lt;sup&gt;nd&lt;/sup&gt; ed. (Eds D. Alderton, S.A. Ellias). L.: Academic Press, 354-365. doi: 10.1016/B978-0-08-102908-4.00114-4</mixed-citation><mixed-citation xml:lang="en">Semenov I.V., Yakovleva O.M. (1994) Hornfelses of the southeastern framing of the gabbro massif of Mount Kumba – apo-gabbro blastocataclasites or exocontact apo-volcanogenic formations? Tr. IGG UB RAS, vyp. 141, 29-34. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit30"><label>30</label><citation-alternatives><mixed-citation xml:lang="ru">Kelemen P.B., Hanghøj K., Greene A.R. (2014) One View of the Geochemistry of Subduction-Related Magmatic Arcs, with an Emphasis on Primitive Andesite and Lower Crust. Treatise on Geochemistry (Second Ed.). (Eds H.D. Holland, K.K. Turekian). Elsevier, 749-806. doi: 10.1016/B978-0-08-095975-7.00323-5</mixed-citation><mixed-citation xml:lang="en">Seravkin I.B., Znamenskii S.E., Kosarev A.M. (2001) Fracture tectonics and ore content of the Bashkir Trans-Urals. Ufa, Poligrafkombinat Publ., 318 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit31"><label>31</label><citation-alternatives><mixed-citation xml:lang="ru">Kitsault Molybdenum Project. British Columbia, Canada. NI 43-101 Technical Report on Feasibility Study. (2010) (Prepared by: G. Christie, G. Kulla, R. Ulansky, T. Lipiec, P. Healy, M. Levy, B. Borntraeger). Project No.: 165003, 208 p.</mixed-citation><mixed-citation xml:lang="en">Simakov S.K., Dolivo-Dobrovolsky D.V. (2009) PT Quick: the Program for Estimation of Equilibrium Parameters for Mineral Assemblages Using Methods of Classical Geothermobarometry.</mixed-citation></citation-alternatives></ref><ref id="cit32"><label>32</label><citation-alternatives><mixed-citation xml:lang="ru">Lanari P., Wagner T., Vidal O. (2014) A thermodynamic model for di-trioctahedral chlorite from experimental and natural data in the system MgO–FeO–Al&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;3&lt;/sub&gt;–SiO&lt;sub&gt;2&lt;/sub&gt;–H&lt;sub&gt;2&lt;/sub&gt;O: applications to P–T sections and geothermometry. Contrib. Mineral. Petrol., 167, 968. doi: 10.1007/s00410-014-0968-8</mixed-citation><mixed-citation xml:lang="en">Sklyarov E.V., Kargopolov S.A., Lavrenchuk A.V., Pushkarev E.V., Semenova D.V. (2023) Geology, Petrology, and Mineralogy of Hornfels-like Rocks (Beerbachite) in the Early Paleozoic Olkhon Collisional Orogen (West Baikal Area, Russia). Minerals, 13(11), 1370. doi: 10.3390/min13111370</mixed-citation></citation-alternatives></ref><ref id="cit33"><label>33</label><citation-alternatives><mixed-citation xml:lang="ru">Liu Y., Brenan J. (2015) Partitioning of platinum-group elements (PGE) and chalcogens (Se, Te, As, Sb, Bi) between monosulfide-solid solution (MSS), intermediate solid solution (ISS) and sulfide liquid at controlled fO&lt;sub&gt;2&lt;/sub&gt;–fS&lt;sub&gt;2&lt;/sub&gt; conditions. Geochim. Cosmochim. Acta, 159, 139-161. doi: 10.1016/j.gca.2015.03.021</mixed-citation><mixed-citation xml:lang="en">Sklyarov E.V., Lavrenchuk A.V., Fedorovsky V.S., Gladkochub D.P., Donskaya T.V., Kotov A.B., Mazukabzov A.M., Starikova A.E. (2020) Regional, Contact Metamorphism, and Autometamorphism of the Olkhon Terrane (West Baikal Area). Petrology, 28, 47-61 (translated from Petrologiya, 28(1), 55-71). doi: 10.1134/S0869591120010051</mixed-citation></citation-alternatives></ref><ref id="cit34"><label>34</label><citation-alternatives><mixed-citation xml:lang="ru">Lu Z.Y., Jeffrey M.I., Zhu Y., Lawson F. (2000) Studies of pentlandite leaching in mixed oxygenated acidic chloride-sulfate solutions. Hydrometallurgy, 56(1), 63-74. doi: 10.1016/S0304-386X(00)00067-0</mixed-citation><mixed-citation xml:lang="en">Sun S., McDonough W.F. (1989) Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes. Geol. Soc., Lond., Spec. Publ., 42, 313-345. doi: 10.1144/GSL.SP.1989.042.01.19</mixed-citation></citation-alternatives></ref><ref id="cit35"><label>35</label><citation-alternatives><mixed-citation xml:lang="ru">Rakhimov I.R., Ankusheva N.N., Samigullin A.A., Shanina S.N. (2023) Origin and Evolution of Ore-Forming Fluids at the Small-Sized Gold Deposits in the Khudolaz Area, Southern Urals. Minerals, 13(6), 781. doi: 10.3390/min13060781</mixed-citation><mixed-citation xml:lang="en">Taylor S.R., McLennan S.M. (1985) The continental crust: its composition and evolution. Oxford, UK; Blackwell, 349 p. doi: 10.1002/gj.3350210116</mixed-citation></citation-alternatives></ref><ref id="cit36"><label>36</label><citation-alternatives><mixed-citation xml:lang="ru">Rakhimov I.R., Vishnevskiy A.V., Saveliev D.E. (2021) Geochemical evolution of PGE-sulfide mineralization of the Khudolaz differentiated complex in the South Urals: The role of R-factor and hydrothermal alteration. Ore Geol. Rev., 104411. doi: 10.1016/j.oregeorev.2021.104411</mixed-citation><mixed-citation xml:lang="en">Tsabadze Dzh.E., Gufranov R.A., Aleksandrov Yu.A., Tsabadze G.A., Zharikov V.G., Marchenko T.A., Kavyeva M.Kh. (1984f) Geological structure of the Sibay ore region. Report on additional geological study at a scale of 1:50,000 of the Sibay area (tablets N-40-106-B-v, g; N-40-118-A; N-40-118-B; N-40-130-A-a, b) for 1980–1984 in 5 volumes. Ufa, V. 1, 271 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit37"><label>37</label><citation-alternatives><mixed-citation xml:lang="ru">Simakov S.K., Dolivo-Dobrovolsky D.V. (2009) PT Quick: the Program for Estimation of Equilibrium Parameters for Mineral Assemblages Using Methods of Classical Geothermobarometry.</mixed-citation><mixed-citation xml:lang="en">Vrublevskaya T.T., Tsygankov A.A., Orsoev D.A. (2003) Contact processes in the Nyurundukan ultramaficmafic massif (northern Baikal region). Russ. Geol. Geophys., 44(3), 205-223 (translated from Geol. Geofiz., 44(3), 207-223).</mixed-citation></citation-alternatives></ref><ref id="cit38"><label>38</label><citation-alternatives><mixed-citation xml:lang="ru">Sklyarov E.V., Kargopolov S.A., Lavrenchuk A.V., Pushkarev E.V., Semenova D.V. (2023) Geology, Petrology, and Mineralogy of Hornfels-like Rocks (Beerbachite) in the Early Paleozoic Olkhon Collisional Orogen (West Baikal Area, Russia). Minerals, 13(11), 1370. doi: 10.3390/min13111370</mixed-citation><mixed-citation xml:lang="en">Warr L.N. (2021) IMA–CNMNC approved mineral symbols. Mineral. Mag., 85(3), 291-320. doi: 10.1180/mgm.2021.43</mixed-citation></citation-alternatives></ref><ref id="cit39"><label>39</label><citation-alternatives><mixed-citation xml:lang="ru">Sun S., McDonough W.F. (1989) Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes. Geol. Soc., Lond., Spec. Publ., 42, 313-345. doi: 10.1144/GSL.SP.1989.042.01.19</mixed-citation><mixed-citation xml:lang="en">Winter J.D. (2014) Principles of Igneous and Metamorphic Petrology. 2&lt;sup&gt;nd&lt;/sup&gt; ed. Pearson: London, UK, 745 p.</mixed-citation></citation-alternatives></ref><ref id="cit40"><label>40</label><citation-alternatives><mixed-citation xml:lang="ru">Taylor S.R., McLennan S.M. (1985) The continental crust: its composition and evolution. Oxford, UK; Blackwell, 349 p. doi: 10.1002/gj.3350210116</mixed-citation><mixed-citation xml:lang="en">Wu C.M., Chen H.X. (2015) Revised Ti-in-biotite geothermometer for ilmenite- or rutile-bearing crustal metapelites. Sci. Bull., 60(1), 116-121. doi: 10.1007/s11434-014-0674-y</mixed-citation></citation-alternatives></ref><ref id="cit41"><label>41</label><citation-alternatives><mixed-citation xml:lang="ru">Warr L.N. (2021) IMA–CNMNC approved mineral symbols. Mineral. Mag., 85(3), 291-320. doi: 10.1180/mgm.2021.43</mixed-citation><mixed-citation xml:lang="en">Yudovich Ya.E., Ketris M.P. (2000) Fundamentals of Lithochemistry. St.Petersburg, Nauka Publ., 479 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit42"><label>42</label><citation-alternatives><mixed-citation xml:lang="ru">Winter J.D. (2014) Principles of Igneous and Metamorphic Petrology. 2&lt;sup&gt;nd&lt;/sup&gt; ed. Pearson: London, UK, 745 p.</mixed-citation><mixed-citation xml:lang="en">Zakharova A.A. (1982f) Petrology and metallogeny of the Early Carboniferous gabbro-plagiogranite formation on the eastern slope of the Southern Urals (Khudolazovsky complex). Scientific report on the topic “Conditions of formation and metamorphism of igneous complexes of the Southern Urals” : in 3 volumes. Ufa, IG BF AN SSSR Publ. V. 1, 429 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit43"><label>43</label><citation-alternatives><mixed-citation xml:lang="ru">Wu C.M., Chen H.X. (2015) Revised Ti-in-biotite geothermometer for ilmenite- or rutile-bearing crustal metapelites. Sci. Bull., 60(1), 116-121. doi: 10.1007/s11434-014-0674-y</mixed-citation><mixed-citation xml:lang="en">Zane A., Weiss Z. (1998) A procedure for classifying rock-forming chlorites based on microprobe data. Rendiconti Lincei. Scienze Fisiche e Naturali, 9, 51-56. doi: 10.1007/BF02904455</mixed-citation></citation-alternatives></ref><ref id="cit44"><label>44</label><citation-alternatives><mixed-citation xml:lang="ru">Zane A., Weiss Z. (1998) A procedure for classifying rock-forming chlorites based on microprobe data. Rendiconti Lincei. Scienze Fisiche e Naturali, 9, 51-56. doi: 10.1007/BF02904455</mixed-citation><mixed-citation xml:lang="en">Znamenskii S.E. (2009) Structural conditions for the formation of collisional gold deposits on the eastern slope of the Southern Urals. Ufa, Gilem Publ., 348 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit45"><label>45</label><citation-alternatives><mixed-citation xml:lang="ru">Zou C. (2013) Chapter 8 – Oil and Gas in Metamorphic Re servoirs. Unconventional Petroleum Geology. (Ed. C. Zou). Elsevier, 275-305. doi: 10.1016/B978-0-12-397162-3.00008-6</mixed-citation><mixed-citation xml:lang="en">Zou C. (2013) Chapter 8 – Oil and Gas in Metamorphic Reservoirs. Unconventional Petroleum Geology. (Ed. C. Zou). Elsevier, 275-305. doi: 10.1016/B978-0-12-397162-3.00008-6</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
