litosphereЛитосфераLITHOSPHERE (Russia)1681-90042500-302XA.N. Zavaritsky Institute of Geology and Geochemistry10.24930/2500-302X-2024-24-3-547-565litosphere-2100Research ArticleСтатьиArticlesИспользование состава циркона и апатита при прогнозировании Cu-Mo-Au-порфирового оруденения в Пекинском и Тессемском массивах Таймыро-Североземельской складчатой областиUtilizing compositions of zircon and apatite for prospecting of Cu-Mo-Auporphyry mineralization in the Pekinsky and Tessemsky granitoid massifs of the Taimyr-Severozemelskaya folded areaБерзинC. В.BerzinS. V.

199034, г. Санкт-Петербург, Университетская наб., 7/9

7/9 Universitetskaya emb., St.Petersburg 199034

sbersin@ya.ruПетровС. В.PetrovS. V.

199034, г. Санкт-Петербург, Университетская наб., 7/9

7/9 Universitetskaya emb., St.Petersburg 199034

КонопелькоД. Л.KonopelkoD. L.

199034, г. Санкт-Петербург, Университетская наб., 7/9

7/9 Universitetskaya emb., St.Petersburg 199034

КураповМ. Ю.KurapovM. Yu.

199034, г. Санкт-Петербург, Университетская наб., 7/9

7/9 Universitetskaya emb., St.Petersburg 199034

ГоловинаТ. А.GolovinaT. A.

198216, г. Санкт-Петербург, пр-т Народного Ополчения, 2, лит. А

2A Narodnogo Opolcheniya st., St.Petersburg 198216

ЧерненкоН. Я.ChernenkoN. Ya.

660043, г. Красноярск, ул. Дмитрия Мартынова, 43 

43 Dmitry Martynov st., Krasnoyarsk 660043

ЧервяковскийВ. С.ChervyakovskiyV. S.

620110, г. Екатеринбург, ул. Академика Вонсовского, 15

15 Academician Vonsovsky st., Ekaterinburg 620110

Санкт-Петербургский государственный университетРоссияSt. Petersburg State UniversityRussian FederationАО “Полиметалл УК”РоссияAO “Polymetal UK”Russian FederationООО “Полярная экспедиционная компания”РоссияLLC “Polar Forwarding Company”Russian FederationИнститут геологии и геохимии им. академика А.Н. Заварицкого УрО РАНРоссияA.N. Zavaritsky Institute of Geology and Geochemistry, UB RASRussian Federation202408072024243547565Copyright © Берзин C.В., Петров С.В., Конопелько Д.Л., Курапов М.Ю., Головина Т.А., Черненко Н.Я., Червяковский В.С., 20242024Берзин C.В., Петров С.В., Конопелько Д.Л., Курапов М.Ю., Головина Т.А., Черненко Н.Я., Червяковский В.С.Berzin S.V., Petrov S.V., Konopelko D.L., Kurapov M.Y., Golovina T.A., Chernenko N.Y., Chervyakovskiy V.S.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.lithosphere.ru/jour/article/view/2100

Объект исследования. Тессемский массив гранитоидов расположен в Северо-Таймырской тектонической зоне в окружении кембрийских пород. Пекинский массив гранитоидов находится в пределах Центрально-Таймырский зоны в окружении метаморфизованных протерозойских пород. Цель. Разработка методики использования состава акцессорных минералов гранитоидов для определения перспектив развития связанного с ними Cu-Mo-Auпорфирового оруденения на примере Пекинского и Тессемского массивов п-ова Таймыр. Материалы и методы исследования. Изучены акцессорные цирконы и апатиты из двух проб гранитоидов Пекинского массива (П1, П2) и двух проб гранитоидов Тессемского массива (Т2, Т3). Состав минералов исследован с помощью EPMA Cameca SX100. Содержание элементов в минералах определено методом LA-ICP-MS при помощи NexION 300S с приставкой NWR 213. Результаты. Составы пород обоих массивов попадают в поля адакитов на классификационных диаграммах. Бóльшая часть цирконов из Пекинского и Тессемского массивов сформировались при температуре <738°С в достаточно окисленной магме с ΔFMQ = 0.6–2.6, что является благоприятным признаком для выявления Cu-Mo-Au-порфирового оруденения. Цирконы характеризуются повышенными отношениями (Eu/Eu*)/Y и  (Ce/Nd)n/Y, что также является благоприятным, хотя и не очень надежным признаком для выявления порфирового оруденения. Значения отношений Eu/Eu* и Sr/Y в апатитах из Тессемского массива выше, чем в апатитах из Пекинского массива. Оценки фугитивности кислорода (logfO2), рассчитанные по Mn в апатитах для четырех проб, совпадают в пределах погрешности. Выводы. Рассмотрены особенности использования состава акцессорных минералов (циркон, апатит) для определения перспективности развития связанного с гранитоидами Cu-Mo-Au-порфирового оруденения. На основе анализа состава циркона и апатита показано, что данные минералы-индикаторы могут использоваться для ранжирования массивов гранитоидов по степени их потенциальной рудоносности. На примере изучения двух гранитных интрузий п-ова Таймыр удалось показать, что Тессемский массив является более перспективным для обнаружения связанного Cu-Mo-Au-порфирового оруденения, чем Пекинский массив.

Research subject. The Tessemsky granite massif is located in the North Taimyr tectonic zone, surrounded by Cambrian rocks. The Pekinsky granite massif is located within the Central Taimyr zone, surrounded by metamorphosed Proterozoic rocks. Aim. To develop a methodology for using the composition of accessory granitoid minerals when prospecting  Cu-Mo-Au-porphyry mineralization on the example of the Pekinsky and Tessemsky granitoid massifs of the Taimyr Peninsula. Materials and methods. Accessory zircon and apatite contained in two granitoid samples from the Pekinsky massif (P1, P2) and two granitoid samples from the Tessemsky massif (T2, T3) were studied. Their mineral composition was examined using an EPMA Cameca SX100 instrument. The element content in minerals was determined by LA-ICPMS using an NexION 300S instrument equipped with an NWR 213 attachment. Results. Most of the zircons from the Pekinsky and Tessemsky massifs were formed at T < 738°C in oxidized magma with ΔFMQ of 0.6–2.6, which is a favorable sign for the identification of Cu-Mo-Au-porphyry mineralization. Zircons are characterized by elevated (Eu/Eu*)Y and  (Ce/Nd)n/Y ratios, which is also a favorable, though not a strongly reliable, sign for identifying porphyry mineralization. The Eu/Eu* and Sr/Y ratios in the apatites from the Tessemsky massif are higher than those in the apatites from the Pekinsky massif. The rock compositions of both massifs fall within the fields of adakites on the classification diagrams. The estimates of oxygen fugacity (logfO2) calculated from Mn in apatites for four samples agree well within the error limits.  Conclusion. Specific features of using the composition of accessory minerals (zircon and apatite) for prospecting the  Cu-Mo-Au-porphyry mineralization associated with granitoids were considered. Accessory indicator minerals can be used to rank granitoid massifs in order to assess their ore content. The example of two granite intrusions of the Taimyr Peninsula made it was possible to show that the Tessemsky massif is more promising for the discovery of associated Cu-Mo-Auporphyry mineralization than the Pekinsky massif.

порфировое оруденениегранитТаймырцирконапатитporphyry mineralizationgraniteTaimyrzirconapatiteИсследование выполнено за счет гранта Российского научного фонда (проект 23-27-00283). https://rscf.ru/ project/23-27-00283/The study was supported by a grant from the Russian Science Foundation (project 23-27-00283). https://rscf.ru/project/23-27-00283/ReferencesВерниковский В.А. (1996) Геодинамическая эволюция Таймырской складчатой области. Новосибирск: СО РАН, НИЦ ОИГГМ, 202 с.Augland L.E., Ryabov V.V., Vernikovsky V.A., Planke S., Polozov A.G., Callegaro S., Jerram D.A., Svensen H.H. (2019) The main pulse of the Siberian Traps expanded in size and composition. Sci. Rep., 9(1), 1-12. https://doi.org/10.1038/s41598-019-54023-2Верниковский В.А. Сальникова Е.Б., Котов А.Б., Пономарчук В.А., Ковач В.П., Травин А.В., Яковлева С.З., Березная Н.Г. (1998) Возраст постколлизионных гранитоидов Северного Таймыра: U-Pb, Sm-Nd, Rb-Sr- и Ar-Ar-данные. Докл. АН, 363(3), 375-378.Ballard J.R., Palin J.M., Campbell I.H. (2002) Relative oxidation states of magmas inferred from Ce(IV)/Ce(III) in zircon: Application to porphyry copper deposits of northern Chile. Contrib. Mineral. Petrol., 144, 347-364.Зайцева М.В., Пупышев А.А., Щапова Ю.В., Вотяков С.Л. (2016) U-Pb-датирование цирконов с помощью квадрупольного масс-спектрометра с индуктивно связанной плазмой NexION300S и приставки для лазерной абляции NWR213. Аналитика и контроль, 20(4), 294-306. http://dx.doi.org/10.15826/analitika.2016.20.4.006Belousova E.A., Griffin W.L., O’Reilly S.Y., Fisher N.I. (2002) Apatite as an indicator mineral for mineral exploration: Trace-element compositions and their relationship to host rock type. J. Geochem. Explor., 76(1), 45-69. https://doi.org/10.1016/S0375-6742(02)00204-2Зоненшайн Л.П. (1990) Тектоника литосферных плит территории СССР. Ч. II. М.: Недра, 344 с.Belousova E.A., Griffin W.L., O’Reilly S.Y., Fisher N.I. (2002) Igneous zircon: Trace element composition as an indicator of source rock type. Contrib. Mineral. Petrol., 143, 602-622. https://doi.org/10.1007/s00410-002-0364-7Качурина Н.В., Макарьев А.А., Макарьева Е.М., Гавриш А.В., Орлов В.В., Дымов В.А. (2013) Государственная геологическая карта Российской Федерации. М-б 1 : 1 000 000 (третье поколение). Лист Т-45- 48 – Мыс Челюскин. Объяснит. записка. СПб.: Картфабрика ВСЕГЕИ, 562 с.Bromiley G.D. (2021) Do concentrations of Mn, Eu and Ce in apatite reliably record oxygen fugacity in magmas? Lithos, 384-385, 105900. https://doi.org/10.1016/j.lithos.2020.105900Курапов М.Ю., Ершова В.Б., Макарьев А.А., Макарьева Е.М., Худолей А.К., Лучицкая М.В., Прокопьев А.В. (2018) Каменноугольный магматизм Северного Таймыра: результаты изотопно-геохимических исследований и геодинамические следствия. Геотектоника, (2), 76-90.Cao M., Li G., Qin K., Seitmuratova E.Y., Liu Y. (2012) Major and trace element characteristics of apatites in granitoids from C. Kazakhstan: Implications for petrogenesis and mineralization. Resour. Geol., 62, 63-83.Погребицкий Ю.Э. (1971) Палеотектонический анализ Таймырской складчатой системы. М.: Недра, 284 с.Cassini V., Moyen J.-F., Cellier G., de Freitas B., Juliani C., Laurent O. (2022) Towards the fertility trend: Unraveling the economic potential of igneous suites through whole-rock and zircon geochemistry (example from the Tapajós mineral Province, Northern Brazil). Ore Geol. Rev., 142, 104643.Проскурнин В.Ф., Листков А.Г., Гавриш А.В., Ванюнин Н.В. (2002) Металлогенический анализ и перспективы промышленного освоения Таймыро-Североземельской золотоносной провинции. Недра Таймыра. Вып. 5. СПб.: ВСЕГЕИ, 10-42.Cooke D.R., Agnew P., Hollings P., Baker M., Chang Z., Wilkinson J.J., White N.C., Zhang L., Thompson J., Gemmell J.B., Fox N., Chen H., Wilkinson C.C. (2017) Porphyry Indicator Minerals (PIMS) and Porphyry Vectoring and Fertility Tools (PVFTS) – Indicators of Mineralization Styles and Recorders of Hypogene Geochemical Dispersion Halos. Proceedings of Exploration 17: Sixth Decennial International Conference on Mineral Exploration, 457-470.Проскурнин В.Ф., Петров О.В., Романов А.П., Курбатов И.И., Гавриш А.В., Проскурнина М.А. (2021) Центрально-Арктический золотосодержащий медномолибден-порфировый пояс. Региональная геология и металлогения, 85, 31-49.Ershova V.B., Anfinson O., Prokopiev A.V., Khudoley A.K., Stockli D.F., Faleide J.I., Gaina C., Malyshev N.A. (2018) Detrital zircon (U-Th)/He ages from Paleozoic strata of the Severnaya Zemlya Archipelago: Deciphering multiple episodes of Paleozoic tectonic evolution within the Russian High Arctic. J. Geodynam., 119, 210-220. https://doi.org/10.1016/j.jog.2018.02.007Проскурнина М.А., Проскурнин В.Ф., Ремизов Д.Н., Ларионов А.Н. (2019) Кольцевые интрузивы Беспамятнинского ареала: проявления шошонит-латитового магматизма на Северном Таймыре. Регион. геол. и металлогения, 79, 5-22.Ershova V.B., Prokopiev A.V., Khudoley A.K., Andersen T., Kullerud K., Kolchanov D.A. (2020) U–Pb age and Hf isotope geochemistry of detrital zircons from cambrian sandstones of the severnaya Zemlya archipelago and Northern Taimyr (Russian high arctic). Minerals, 10(1), 36. https://doi.org/10.3390/min10010036Урванцев Н.Н. (1949) Таймырская складчатая зона. Бюлл. Норильского комбината, 4-12.Ershova V.B., Prokopiev A.V., Khudoley A.K., Proskurnin V.F., Andersen T., Kullerud K., Stepunina M.A., Kolchanov D.A. (2017) New U-Pb isotopic data for detrital zircons from metasedimentary sequences of northwestern Taimyr. Dokl. Earth Sci., 474, 613-616. https://doi.org/10.1134/S1028334X17060022Augland L.E., Ryabov V.V., Vernikovsky V.A., Planke S., Polozov A.G., Callegaro S., Jerram D.A., Svensen H.H. (2019) The main pulse of the Siberian Traps expanded in size and composition. Sci. Rep., 9(1), 1-12. https://doi.org/10.1038/s41598-019-54023-2Ershova V.B., Prokopiev A.V., Khudoley A.K., Sobolev N.N., Petrov E.O. (2015a) Detrital zircon ages and provenance of the Upper Paleozoic successions of Kotel’ny Island (New Siberian Islands archipelago). Lithosphere, 7(1), 40-45. https://doi.org/10.1130/L387.1Ballard J.R., Palin J.M., Campbell I.H. (2002) Relative oxidation states of magmas inferred from Ce(IV)/Ce(III) in zircon: Application to porphyry copper deposits of northern Chile. Contrib. Mineral. Petrol., 144, 347-364Ershova V.B., Prokopiev A.V., Nikishin V.A., Khudoley A.K., Malyshev N.A., Nikishin A.M. (2015b) New data on Upper Carboniferous-Lower Permian deposits of Bol’shevik Island, Severnaya Zemlya Archipelago. Polar Res., 34, 1-8. https://doi.org/10.3402/polar. v34.24558Belousova E.A., Griffin W.L., O’Reilly S.Y., Fisher N.I. (2002) Apatite as an indicator mineral for mineral exploration: Trace-element compositions and their relationship to host rock type. J. Geochem. Explor., 76(1), 45-69. https://doi.org/10.1016/S0375-6742(02)00204-2Harlov D.E. (2015) Apatite: A fingerprint for metasomatic processes. Elements, 11(3), 171-176. https://doi. org/10.2113/gselements.11.3.171Belousova E.A., Griffin W.L., O’Reilly S.Y., Fisher N.I. (2002) Igneous zircon: Trace element composition as an indicator of source rock type. Contrib. Mineral. Petrol., 143, 602-622. https://doi.org/10.1007/s00410-002-0364-7Hedenquist J.W. (2014) Variable Characteristics of Ore Deposits in the Epithermal Environment: Causes, and Exploration Implications. Acta Geol. Sinica, 88(s2), 736- 737.Bromiley G.D. (2021) Do concentrations of Mn, Eu and Ce in apatite reliably record oxygen fugacity in magmas? Lithos, 384-385, 105900. https://doi.org/10.1016/j.lithos.2020.105900Hoskin P.W.O. (2005) Trace-element composition of hydrothermal zircon and the alteration of hadean zircon from the Jack Hills, Australia. Geochim. Cosmochim. Acta, 69, 637-648.Cao M., Li G., Qin K., Seitmuratova E.Y., Liu Y. (2012) Major and trace element characteristics of apatites in granitoids from C. Kazakhstan: Implications for petrogenesis and mineralization. Resour. Geol., 62, 63-83.Hoskin P.W.O., Schaltegger U. (2003) The composition of zircon and igneous and metamorphic petrogenesis. Rev. Mineral. Geochem., 53(1), 27-62. https://doi. org/10.2113/0530027Cassini V., Moyen J.-F., Cellier G., de Freitas B., Juliani C., Laurent O. (2022) Towards the fertility trend: Unraveling the economic potential of igneous suites through whole-rock and zircon geochemistry (example from the Tapajós mineral Province, Northern Brazil). Ore Geol. Rev., 142, 104643.Imai A. (2004) Variation of Cl and SO3 contents of microphenocrystic apatite in intermediate to silicic igneous rocks of Cenozoic Japanese island arcs: Implications for porphyry Cumetallogenesis in theWestern Pacific Island arcs. Resour. Geol., 54, 357-372.Cooke D.R., Agnew P., Hollings P., Baker M., Chang Z., Wilkinson J.J., White N.C., Zhang L., Thompson J., Gemmell J.B., Fox N., Chen H., Wilkinson C.C. (2017) Porphyry Indicator Minerals (PIMS) and Porphyry Vectoring and Fertility Tools (PVFTS) – Indicators of Mineralization Styles and Recorders of Hypogene Geochemical Dispersion Halos. Proceedings of Exploration 17: Sixth Decennial International Conference on Mineral Exploration, 457-470.Kachurina N.V., Makar’ev A.A., Makar’eva E.M., Gavrish A.V., Orlov V.V., Dymov V.A. (2013) State Geological Map of the Russian Federation. Scale 1 : 1 000 000 (third generation). Sheet T-45-48 – Cape Chelyuskin. Explanatory letter. St.Petersburg, VSEGEI Mapping Factory, 562 p. (In Russ.)Ershova V.B., Anfinson O., Prokopiev A.V., Khudoley A.K., Stockli D.F., Faleide J.I., Gaina C., Malyshev N.A. (2018) Detrital zircon (U-Th)/He ages from Paleozoic strata of the Severnaya Zemlya Archipelago: Deciphering multiple episodes of Paleozoic tectonic evolution within the Russian High Arctic. J. Geodynam., 119, 210-220. https://doi.org/10.1016/j.jog.2018.02.007Khudoley A.K., Verzhbitsky V.E., Zastrozhnov D.A., O’Sullivan P., Ershova V.B., Proskurnin V.F., Tuchkova M.I., Rogov M.A., Kyser T.K., Malyshev S.V., Schneider G.V. (2018) Late Paleozoic – Mesozoic tectonic evolution of the Eastern Taimyr-Severnaya Zemlya Fold and Thrust Belt and adjoining Yenisey-Khatanga Depression. J. Geodynam., 119, 221-241. https://doi.org/10.1016/j.jog.2018.02.002Ershova V.B., Prokopiev A.V., Khudoley A.K., Andersen T., Kullerud K., Kolchanov D.A. (2020) U–Pb age and Hf isotope geochemistry of detrital zircons from cambrian sandstones of the severnaya Zemlya archipelago and Northern Taimyr (Russian high arctic). Minerals, 10(1), 36. https://doi.org/10.3390/min10010036Kong D.X. (2022) Tracing the effects of fO2, pressure and H2O on the ore-forming magmas: Perspective from zircon REE composition. J. Asian Earth Sci., 237, 105354. https://doi.org/10.1016/j.jseaes.2022.105354Ershova V.B., Prokopiev A.V., Khudoley A.K., Proskurnin V.F., Andersen T., Kullerud K., Stepunina M.A., Kolchanov D.A. (2017) New U-Pb isotopic data for detrital zircons from metasedimentary sequences of northwestern Taimyr. Dokl. Earth Sci., 474, 613-616. https://doi.org/10.1134/S1028334X17060022Konopelko D., Seltmann R., Dolgopolova A., Safonova I., Glorie S., De Grave J., Sun M. (2021) Adakite-like granitoids of Songkultau: A relic of juvenile Cambrian arc in Kyrgyz Tien Shan. Geosci. Front., 12, 147-160. https://doi.org/10.1016/j.gsf.2020.08.006Ershova V.B., Prokopiev A.V., Khudoley A.K., Sobolev N.N., Petrov E.O. (2015a) Detrital zircon ages and provenance of the Upper Paleozoic successions of Kotel’ny Island (New Siberian Islands archipelago). Lithosphere, 7(1), 40-45. https://doi.org/10.1130/L387.1Kurapov M.Y., Ershova V.B., Khudoley A.K., Luchitskaya M.V., Makariev A.A., Makarieva E.M., Vishnevskaya I.A. (2020а) Late Palaeozoic magmatism of Northern Taimyr: New insights into the tectonic evolution of the Russian High Arctic. Int. Geol. Rev., (9), 1-23. https://doi.org/10.1080/00206814.2020.1818300Ershova V.B., Prokopiev A.V., Nikishin V.A., Khudoley A.K., Malyshev N.A., Nikishin A.M. (2015b) New data on Upper Carboniferous-Lower Permian deposits of Bol’shevik Island, Severnaya Zemlya Archipelago. Polar Res., 34, 1-8. https://doi.org/10.3402/polar.v34.24558Kurapov M.Y., Ershova V.B., Khudoley A.K., Makariev A.A., Makarieva E.M. (2020b) The first evidence of Late Ordovician magmatism of the October Revolution Island (Severnaya Zemlya archipelago, Russian High Arctic): Geochronology, geochemistry and geodynamic settings. Norweg. J. Geol., 100(1). https://doi.org/10.17850/njg100-3-4Harlov D.E. (2015) Apatite: A fingerprint for metasomatic processes. Elements, 11(3), 171-176. https://doi.org/10.2113/gselements.11.3.171Kurapov M.Y., Ershova V.B., Makariev A.A., Makarieva E.V., Khudoley A.K., Luchitskaya M.V., Prokopiev A.V. (2018) Carboniferous granitoid magmatism of Northern Taimyr: Results of isotopic-geochemical study and geodynamic interpretation. Geotectonics, 52(2), 225- 239. https://doi.org/10.1134/S001685211802004Hedenquist J.W. (2014) Variable Characteristics of Ore Deposits in the Epithermal Environment: Causes, and Exploration Implications. Acta Geol. Sinica, 88(s2), 736-737.Loader M.A., Nathwani Ch.L., Wilkinson J.J., Armstrong R.N. (2022) Controls on the magnitude of Ce anomalies in zircon. Geochim. Cosmochim. Acta, 328, 242-257. https://doi.org/10.1016/j.gca.2022.03.024Hoskin P.W.O. (2005) Trace-element composition of hydrothermal zircon and the alteration of hadean zircon from the Jack Hills, Australia. Geochim. Cosmochim. Acta, 69, 637-648.Loader M.A., Wilkinson J.J., Armstrong R.N. (2017) The effect of titanite crystallisation on Eu and Ce anomalies in zircon and its implications for the assessment of porphyry Cu deposit fertility. Earth Planet. Sci. Lett., 472, 107- 119. https://doi.org/10.1016/j.epsl.2017.05.010Hoskin P.W.O., Schaltegger U. (2003) The composi tion of zircon and igneous and metamorphic petrogenesis. Rev. Mineral. Geochem., 53(1), 27-62. https://doi.org/10.2113/0530027Lorenz H., Gee D.G., Whitehouse M.J. (2007) New geochronological data on Palaeozoic igneous activity and deformation in the Severnaya Zemlya Archipelago, Russia, and implications for the development of the Eurasian Arctic margin. Geol. Mag., 144(1), 105-125. https://doi.org/10.1017/S001675680600272XImai A. (2004) Variation of Cl and SO3 contents of microphenocrystic apatite in intermediate to silicic igneous rocks of Cenozoic Japanese island arcs: Implications for porphyry Cumetallogenesis in theWestern Pacific Island arcs. Resour. Geol., 54, 357-372.Lorenz H., Männik P., Gee D.G., Proskurnin V.F. (2008) Geology of the Severnaya Zemlya Archipelago and the North Kara Terrane in the Russian high Arctic. Int. J. Earth Sci., 97(3), 519-547. https://doi.org/10.1007/s00531-007-0182-2Khudoley A.K., Verzhbitsky V.E., Zastrozhnov D.A., O’Sullivan P., Ershova V.B., Proskurnin V.F., Tuchkova M.I., Rogov M.A., Kyser T.K., Malyshev S.V., Schneider G.V. (2018) Late Paleozoic – Mesozoic tectonic evolution of the Eastern Taimyr-Severnaya Zemlya Fold and Thrust Belt and adjoining Yenisey-Khatanga Depression. J. Geodynam., 119, 221-241. https://doi.org/10.1016/j.jog.2018.02.002Loucks R.R., Fiorentini M.L., Henríquez G.J. (2020) New magmatic oxybarometer using trace elements in zircon. J. Petrol., 61(3), egaa034.Kong D.X. (2022) Tracing the effects of fO2, pressure and H2O on the ore-forming magmas: Perspective from zircon REE composition. J. Asian Earth Sci., 237, 105354. https://doi.org/10.1016/j.jseaes.2022.105354Lu Y.-J., Loucks R.R., Fiorentini M., McCuaig T.C., Evans N.J., Yang Z.-M., Hou Z.-Q., Kirkland C.L., Parra-Avila L.A., Kobussen A. (2016) Zircon compositions as a pathfinder for porphyry Cu ± Mo ± Au Deposits. Soc. Econom. Geol. Spec. Publ., 19, 329-347.Konopelko D., Seltmann R., Dolgopolova A., Safonova I., Glorie S., De Grave J., Sun M. (2021) Adakite-like granitoids of Songkultau: A relic of juvenile Cambrian arc in Kyrgyz Tien Shan. Geosci. Front., 12, 147-160. https://doi.org/10.1016/j.gsf.2020.08.006Mao M., Rukhlov A.S., Rowins S.M., Spence J., Coogan L.A. (2016) Apatite trace element compositions: A robust newtool for mineral exploration. Econom. Geol., 111, 1187-1222. https://doi.org/10.2113/econgeo.111.5.1187Kurapov M.Y., Ershova V.B., Khudoley A.K., Luchitskaya M.V., Makariev A.A., Makarieva E.M., Vishnevskaya I.A. (2020а) Late Palaeozoic magmatism of Northern Taimyr: New insights into the tectonic evolution of the Russian High Arctic. Int. Geol. Rev., (9), 1-23. https://doi.org/10.1080/00206814.2020.1818300Metelkin D.V., Vernikovsky V.A., Kazansky A.Y., Bogolepova O.K., Gubanov A.P. (2005) Paleozoic history of the Kara microcontinent and its relation to Siberia and Baltica: Paleomagnetism, paleogeography and tectonics. Tectonophysics, 398(3-4), 225-243. https://doi.org/10.1016/j.tecto.2005.02.008Kurapov M.Y., Ershova V.B., Khudoley A.K., Makariev A.A., Makarieva E.M. (2020b) The first evidence of Late Ordovician magmatism of the October Revolution Island (Severnaya Zemlya archipelago, Russian High Arctic): Geochronology, geochemistry and geodynamic settings. Norweg. J. Geol., 100(1). https://doi.org/10.17850/njg100-3-4Metelkin D.V., Vernikovsky V.A., Matushkin N.Y. (2015) Arctida between Rodinia and Pangea. Precambr. Res., 259, 114-129. https://doi.org/10.1016/j.precamres.2014.09.013Loader M.A., Nathwani Ch.L., Wilkinson J.J., Armstrong R.N. (2022) Controls on the magnitude of Ce anomalies in zircon. Geochim. Cosmochim. Acta, 328, 242-257. https://doi.org/10.1016/j.gca.2022.03.024Miles A.J., Graham C.M., Hawkesworth C.J., Gillespie M.R., Hinton R.W., Bromiley G.D. (2014) Apatite: A new redox proxy for silicic magmas. Geochim. Cosmochim. Acta, 132, 101-119.Loader M.A., Wilkinson J.J., Armstrong R.N. (2017) The effect of titanite crystallisation on Eu and Ce anomalies in zircon and its implications for the assessment of porphyry Cu deposit fertility. Earth Planet. Sci. Lett., 472, 107- 119. https://doi.org/10.1016/j.epsl.2017.05.010Müntener O., Kelemen P.B., Grove T.L. (2001) The role of H2O during crystallization of primitive arc magmas under uppermost mantle conditions and genesis of igneous pyroxenites: An experimental study. Contrib. Mineral. Petrol., 141, 643-658. https://doi.org/10.1007/s004100100266Lorenz H., Gee D.G., Whitehouse M.J. (2007) New geochronological data on Palaeozoic igneous activity and deformation in the Severnaya Zemlya Archipelago, Russia, and implications for the development of the Eurasian Arctic margin. Geol. Mag., 144(1), 105-125. https://doi.org/10.1017/S001675680600272XNathwani C.L., Loader M.A., Wilkinson J.J., Buret Y., Sievwright R.H., Hollings P. (2020) Multi-stage arc magma evolution recorded by apatite in volcanic rocks. Geology, 48(4), 323-327. https://doi.org/10.1130/G46998.1Lorenz H., Männik P., Gee D.G., Proskurnin V.F. (2008) Geology of the Severnaya Zemlya Archipelago and the North Kara Terrane in the Russian high Arctic. Int. J. Earth Sci., 97(3), 519-547. https://doi.org/10.1007/s00531-007-0182-2Pan L.C., Hu R.Z., Bi X.W., Wang Y., Yan J. (2020) Evaluating magmatic fertility of Paleo-Tethyan granitoids in eastern Tibet using apatite chemical composition and Nd isotope. Ore Geol. Rev., 127, 103757.Loucks R.R., Fiorentini M.L., Henríquez G.J. (2020) New magmatic oxybarometer using trace elements in zircon. J. Petrol., 61(3), egaa034.Pan L.C., Hu R.Z., Wang X.S., Bi X.W., Zhu J.J., Li C. (2016) Apatite trace element and halogen compositions as petrogenetic–metallogenic indicators: Examples from four granite plutons in the Sanjiang region, SW China. Lithos, 254, 118-130.Lu Y.-J., Loucks R.R., Fiorentini M., McCuaig T.C., Evans N.J., Yang Z.-M., Hou Z.-Q., Kirkland C.L., Parra-Avila L.A., Kobussen A. (2016) Zircon compositions as a pathfinder for porphyry Cu ± Mo ± Au Deposits. Soc. Econom. Geol. Spec. Publ., 19, 329-347.Pearce J.A., Harris N.B.W., Tindle A.G. (1984) Trace element discrimination diagrams for the tectonic interpretation of granitic rocks. J. Petrol., 25, 956-983. https://doi.org/10.2113/10.1093/petrology/25.4.956Mao M., Rukhlov A.S., Rowins S.M., Spence J., Coogan L.A. (2016) Apatite trace element compositions: A robust newtool for mineral exploration. Econom. Geol., 111, 1187-1222. https://doi.org/10.2113/econgeo.111.5.1187Pease V.L., Kuzmichev A.B., Danukalova M.K. (2014) The new Siberian Islands and evidence for the continuation of the Uralides, Arctic Russia. J. Geol. Soc., 172, 1-4. https://doi.org/10.1144/jgs2014-064Metelkin D.V., Vernikovsky V.A., Kazansky A.Y., Bogolepova O.K., Gubanov A.P. (2005) Paleozoic history of the Kara microcontinent and its relation to Siberia and Baltica: Paleomagnetism, paleogeography and tectonics. Tectonophysics, 398(3-4), 225-243. https://doi.org/10.1016/j.tecto.2005.02.008Pease V.L., Scott R.A. (2009) Crustal affinities in the Arctic Uralides, northern Russia: Significance of detrital zircon ages from Neoproterozoic and Palaeozoic sediments in Novaya Zemlya and Taimyr. J. Geol. Soc., 166(3), 517- 527. https://doi.org/10.1144/0016-76492008-093Metelkin D.V., Vernikovsky V.A., Matushkin N.Y. (2015) Arctida between Rodinia and Pangea. Precambr. Res., 259, 114-129. https://doi.org/10.1016/j.precamres.2014.09.013Petrov O.V., Khanchuk A.I., Ivanov V.V., Shatov V.V., Seltmann R., Dolgopolova A.V., Alenicheva A.A., Molchanov A.V., Terekhov A.V., Leontev V.I., Belyatsky B.V., Rodionov N.V., Sergeev S.A. (2021) Porphyry indicator zircons (PIZ) and geochronology of magmatic rocks from the Malmyzh and Pony Cu-Au porphyry ore fields (Russian Far East). Ore Geol. Rev., 139, 104491.Miles A.J., Graham C.M., Hawkesworth C.J., Gillespie M.R., Hinton R.W., Bromiley G.D. (2014) Apatite: A new redox proxy for silicic magmas. Geochim. Cosmochim. Acta, 132, 101-119.Pizarro H., Campos E., Bouzari F., Rousse S., Bissig T., Gregoire M., Riquelme R. (2020) Porphyry indicator zircons (PIZs): Application to exploration of porphyry copper deposits. Ore Geol. Rev., 126, 1-18.Müntener O., Kelemen P.B., Grove T.L. (2001) The role of H2O during crystallization of primitive arc magmas under uppermost mantle conditions and genesis of igneous pyroxenites: An experimental study. Contrib. Mineral. Petrol., 141, 643-658. https://doi.org/10.1007/s004100100266Pogrebitskii Yu.E. (1971) Paleotectonic analysis of the Taimyr fold system. Moscow, Nedra Publ., 284 p. (In Russ.)Nathwani C.L., Loader M.A., Wilkinson J.J., Buret Y., Sievwright R.H., Hollings P. (2020) Multi-stage arc magma evolution recorded by apatite in volcanic rocks. Geology, 48(4), 323-327. https://doi.org/10.1130/G46998.1Priyatkina N., Collins W.J., Khudoley A.K., Zastrozhnov D.A., Ershova V.B., Chamberlain K., Shatsillo A., Proskurnin V.F. (2017) The Proterozoic evolution of northern Siberian Craton margin: A comparison of U– Pb–Hf signatures from sedimentary units of the Taimyr orogenic belt and the Siberian platform. Int. Geol. Rev., 13(59), 1632-1656.Pan L.C., Hu R.Z., Bi X.W., Wang Y., Yan J. (2020) Evaluating magmatic fertility of Paleo-Tethyan granitoids in eastern Tibet using apatite chemical composition and Nd isotope. Ore Geol. Rev., 127, 103757.Proskurnin V.F., Listkov A.G., Gavrish A.V., Vanyunin N.V. (2002) Metallogenic analysis and prospects for industrial development of the Taimyr-Severozemelskaya goldbearing province. Nedra Taimyra. Iss. 5. St.Petersburg, VSEGEI Publishing House, 10-42. (In Russ.)Pan L.C., Hu R.Z., Wang X.S., Bi X.W., Zhu J.J., Li C. (2016) Apatite trace element and halogen compositions as petrogenetic–metallogenic indicators: Examples from four granite plutons in the Sanjiang region, SW China. Lithos, 254, 118-130.Proskurnin V.F., Petrov O.V., Romanov A.P., Kurbatov I.I., Gavrish A.V., Proskurnina M.A. (2021) Central Arctic gold-bearing copper-molybdenum-porphyric belt. Regional’naya Geologiya i Metallogeniya, 85, 31-49. (In Russ.)Pearce J.A., Harris N.B.W., Tindle A.G. (1984) Trace element discrimination diagrams for the tectonic interpretation of granitic rocks. J. Petrol., 25, 956-983. https://doi.org/10.2113/10.1093/petrology/25.4.956Proskurnina M.A., Proskurnin V.F., Remizov D.N., Larionov A.N. (2019) Ring intrusions of the Bespamyatnaya areal: Manifestations of shoshonite-latite magmatism in Northern Taimyr. Regional’naya Geologiya i Metallogeniya, 79, 5-22. (In Russ.)Pease V.L., Kuzmichev A.B., Danukalova M.K. (2014) The new Siberian Islands and evidence for the continuation of the Uralides, Arctic Russia. J. Geol. Soc., 172, 1-4. https://doi.org/10.1144/jgs2014-064Richards J.P. (2011) High Sr/Y arc magmas and porphyry Cu ± Mo ± Au deposits: Just add water. Econom. Geol. Bull. Soc. Econom. Geol., 106, 1075-1081. https://doi.org/10.2113/econgeo.106.7.1075Pease V.L., Scott R.A. (2009) Crustal affinities in the Arctic Uralides, northern Russia: Significance of detrital zircon ages from Neoproterozoic and Palaeozoic sediments in Novaya Zemlya and Taimyr. J. Geol. Soc., 166(3), 517- 527. https://doi.org/10.1144/0016-76492008-093Richards J., Kerrich R. (2007) Adakite-like rocks: their diverse origins and questionable role in metallogenesis. Econom. Geol., 102(4), 537-576. https://doi.org/10.2113/gsecongeo.102.4.537Petrov O.V., Khanchuk A.I., Ivanov V.V., Shatov V.V., Seltmann R., Dolgopolova A.V., Alenicheva A.A., Molchanov A.V., Terekhov A.V., Leontev V.I., Belyatsky B.V., Rodionov N.V., Sergeev S.A. (2021) Porphyry indicator zircons (PIZ) and geochronology of magmatic rocks from the Malmyzh and Pony Cu-Au porphyry ore fields (Russian Far East). Ore Geol. Rev., 139, 104491.Seedorff E., Dilles J.H., Proffett Jr.J.M., Einaudi M.T., Zurcher L., Stavast W.J.A., Johnson D.A., Barton M.D. (2005) Porphyry deposits: Characteristics and origin of hypogene features. Econom. Geol., 100, 251-298.Pizarro H., Campos E., Bouzari F., Rousse S., Bissig T., Gregoire M., Riquelme R. (2020) Porphyry indicator zircons (PIZs): Application to exploration of porphyry cop per deposits. Ore Geol. Rev., 126, 1-18.Sillitoe R.H. (2014) Geological Criteria for Porphyry Copper Exploration. Acta Geol. Sinica, 88(supp. 2), 597-598.Priyatkina N., Collins W.J., Khudoley A.K., Zastrozhnov D.A., Ershova V. B., Chamberlain K., Shatsillo A., Proskurnin V.F. (2017) The Proterozoic evolution of northern Siberian Craton margin: A comparison of U– Pb–Hf signatures from sedimentary units of the Taimyr orogenic belt and the Siberian platform. Int. Geol. Rev., 13(59), 1632-1656.Sillitoe R.H. (2010) Porphyry Copper Systems. Econom. Geol., 105, 3-41.Richards J.P. (2011) High Sr/Y arc magmas and porphyry Cu ± Mo ± Au deposits: Just add water. Econom. Geol. Bull. Soc. Econom. Geol., 106, 1075-1081. https://doi.org/10.2113/econgeo.106.7.1075Stokes T.N., Bromiley G.D., Potts N.J., Saunders K.E., Miles A.J., EIMF (2019) The effect of melt composition and oxygen fugacity on manganese partitioning between apatite and silicate melt. Chem. Geol., 506, 162-174. https://doi.org/10.1016/j.chemgeo.2018.12.015Richards J., Kerrich R. (2007) Adakite-like rocks: Their diverse origins and questionable role in metallogenesis. Econom. Geol., 102(4), 537-576. https://doi.org/10.2113/gsecongeo.102.4.537Sun S.J., Yang X.Y., Wang G.J., Sun W.D., Zhang H., Li C.Y., Ding X. (2019) In situ elemental and Sr-O isotopic studies on apatite from the Xu-Huai intrusion at the southern margin of the North China Craton: Implications for petrogenesis and metallogeny. Chem. Geol., 510, 200-214.Seedorff E., Dilles J.H., Proffett Jr.J.M., Einaudi M.T., Zurcher L., Stavast W.J.A., Johnson D.A., Barton M.D. (2005) Porphyry deposits: Characteristics and origin of hypogene features. Econom. Geol., 100, 251-298.Sun S.S., McDonough W.F. (1989) Chemical and isotopic systematics of ocean basalts: Implications for mantle composition and processes, in Magmatism in the Ocean Basins. Geol. Soc. Lond. Spec. Publ., 42, 313-345. https://doi.org/10.2113/10.1144/GSL.SP.1989.042.01.19Sillitoe R.H. (2014) Geological Criteria for Porphyry Copper Exploration. Acta Geol. Sinica, 88(supp. 2), 597-598.Sun W., Huang R., Li H., Hu Y., Zhang C., Sun S., Zhang L., Ding X., Li C., Zartman R.E., Ling M. (2015) Porphyry deposits and oxidized magmas. Ore Geol. Rev., 65(1), 97-131.Sillitoe R.H. (2010) Porphyry Copper Systems. Econom. Geol., 105, 3-41.Urvantsev N.N. (1949) Taimyr fold zone. Beulletin’ Noril’skogo Kombinata, 4-12. (In Russ.)Stokes T.N., Bromiley G.D., Potts N.J., Saunders K.E., Miles A.J., EIMF (2019) The effect of melt composition and oxygen fugacity on manganese partitioning between apatite and silicate melt. Chem. Geol., 506, 162-174. https://doi.org/10.1016/j.chemgeo.2018.12.015Vernikovskii V.A. (1996) Geodynamic evolution of the Taimyr folded region. Novosibirsk, SO RAS NIC OIGGM Publ., 202 p. (In Russ.)Sun S.J., Yang X.Y., Wang G.J., Sun W.D., Zhang H., Li C.Y., Ding X. (2019) In situ elemental and Sr-O isotopic studies on apatite from the Xu-Huai intrusion at the southern margin of the North China Craton: Implications for petrogenesis and metallogeny. Chem. Geol., 510, 200-214.Vernikovskii V.A., Sal’nikova E., Kotov A.B., Ponomarchuk V.A., Kovach V.P., Travin A.V., Yakovleva S.Z., Bereznaya N.G. (1998) Age of post-collisional granitoids of Northern Taimyr: U-Pb, Sm-Nd, Rb-Sr, and ArAr data. Dokl. Akad. Nauk, 363(3), 375-378.Sun S.S., McDonough W.F. (1989) Chemical and isotopic systematics of ocean basalts: Implications for mantle composition and processes, in Magmatism in the Ocean Basins. Geol. Soc. Lond. Spec. Publ., 42, 313-345. https://doi.org/10.2113/10.1144/GSL.SP.1989.042.01.19Vernikovsky V.A., Pease V.L., Vernikovskaya A.E., Romanov A.P., Gee D.G., Travin A.V. (2003) First report of early Triassic A-type granite and syenite intrusions from Taimyr: Product of the northern Eurasian superplume? Lithos, 66(1-2), 23-36. https://doi.org/10.1016/S0024-4937(02)00192-5Sun W., Huang R., Li H., Hu Y., Zhang C., Sun S., Zhang L., Ding X., Li C., Zartman R.E., Ling M. (2015) Porphyry deposits and oxidized magmas. Ore Geol. Rev., 65(1), 97-131.Vernikovsky V.A., Vernikovskaya A.E., Pease V.L., Gee D.G. (2005) Neoproterozoic Orogeny along the margins of Siberia. Geol. Soc. Lond. Mem., 30, 233-248. https://doi.org/10.1144/GSL.MEM.2004.030.01.18Vernikovsky V.A., Pease V.L., Vernikovskaya A.E., Romanov A.P., Gee D.G., Travin A.V. (2003). First report of early Triassic A-type granite and syenite intrusions from Taimyr: Product of the northern Eurasian superplume? Lithos, 66(1-2), 23-36. https://doi.org/10.1016/S0024-4937(02)00192-5Vernikovsky V.A., Vernikovskaya A.E., Proskurnin V.F., Matushkin N.Y., Proskurnina M.A., Kadilnikov P., Larionov A.N., Travin A.V. (2020) Late paleozoic–early mesozoic granite magmatism on the arctic margin of the siberian craton during the kara-siberia oblique collision and plume events. Minerals, 10(6), 571. https://doi.org/10.3390/min10060571Vernikovsky V.A., Vernikovskaya A.E., Pease V.L., Gee D.G. (2005) Neoproterozoic Orogeny along the margins of Siberia. Geol. Soc. Lond. Mem., 30, 233-248. https://doi.org/10.1144/GSL.MEM.2004.030.01.18Wang H., Cai K., Sun M., Xia X.-P., Lai C.-K., Li P., Wan B., Zhang Zh. (2022) Apatite as a magma redox indicator and its application in metallogenic research. Lithos, 422-423, 106749. https://doi.org/10.1016/j.lithos.2022.106749Vernikovsky V.A., Vernikovskaya A.E., Proskurnin V.F., Matushkin N.Y., Proskurnina M.A., Kadilnikov P., Larionov A.N., Travin A.V. (2020). Late paleozoic–early mesozoic granite magmatism on the arctic margin of the siberian craton during the kara-siberia oblique collision and plume events. Minerals, 10(6), 571. https://doi.org/10.3390/min10060571Watson E.B., Wark D.A., Thomas J.B. (2006) Crystallization thermometers for zircon and rutile. Contrib. Mineral. Petrol., 151, 413-433.Wang H., Cai K., Sun M., Xia X.-P., Lai C.-K., Li P., Wan B., Zhang Zh. (2022) Apatite as a magma redox indicator and its application in metallogenic research. Lithos, 422-423, 106749. https://doi.org/10.1016/j.lithos.2022.106749Zafar T., Rehman H.U., Mahar M.A., Alam M., Oyebamiji A., Rehman S.U., Leng C.B. (2020) A critical review on petrogenetic, metallogenic and geodynamic implications of granitic rocks exposed in north and east China: New insights from apatite geochemistry. J. Geodynam., 136, 101723.Watson E.B., Wark D.A., Thomas J.B. (2006) Crystallization thermometers for zircon and rutile. Contrib. Mineral. Petrol., 151, 413-433.Zaitseva M.V., Pupyshev A.A., Shchapova Ju.V., Votyakov S.L. (2016) Dating of zircons using NexION 300S quadrupole mass spectrometer with inductively coupled plasma and NWR 213 attachment for laser ablation. Analitika i Kontrol’, 20(4), 294-306. (In Russ.) http://dx.doi.org/10.15826/analitika.2016.20.4.006Zafar T., Rehman H.U., Mahar M.A., Alam M., Oyebamiji A., Rehman S.U., Leng C.B. (2020) A critical review on petrogenetic, metallogenic and geodynamic implications of granitic rocks exposed in north and east China: New insights from apatite geochemistry. J. Geodynam., 136, 101723.Zhong S., Feng C., Seltmann R., Li D., Qu H. (2018) Can magmatic zircon be distinguished from hydrothermal zircon by trace element composition? The effect of mineral inclusions on zircon trace element composition. Lithos, 314-315, 646-657.Zhong S., Feng C., Seltmann R., Li D., Qu H. (2018) Can magmatic zircon be distinguished from hydrothermal zircon by trace element composition? The effect of mineral inclusions on zircon trace element composition. Lithos, 314-315, 646-657.Zonenshain L.P. (1990) Tectonics of lithospheric plates in the territory of the USSR. Pt II. Moscow, Nedra Publ., 344 p. (In Russ.)

The authors declare that there are no conflicts of interest present.