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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">litosphere</journal-id><journal-title-group><journal-title xml:lang="ru">Литосфера</journal-title><trans-title-group xml:lang="en"><trans-title>LITHOSPHERE (Russia)</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1681-9004</issn><issn pub-type="epub">2500-302X</issn><publisher><publisher-name>A.N. Zavaritsky Institute of Geology and Geochemistry</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.24930/2500-302X-2024-24-3-526-546</article-id><article-id custom-type="elpub" pub-id-type="custom">litosphere-2099</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Статьи</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>Articles</subject></subj-group></article-categories><title-group><article-title>Минералы палладия и платины в рудах Au-Pd месторождения Чудное (Приполярный Урал, Россия)</article-title><trans-title-group xml:lang="en"><trans-title>Palladium and platinum minerals in Au-Pd ores of the Chudnoe deposit (Subpolar Urals, Russia)</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Онищенко</surname><given-names>C. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Onishchenko</surname><given-names>S. A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>167982, г. Сыктывкар, ул. Первомайская, 54</p></bio><bio xml:lang="en"><p>54 Pervomaiskaya st., Syktyvkar 167982</p></bio><email xlink:type="simple">mine222@ya.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Кузнецов</surname><given-names>С. К.</given-names></name><name name-style="western" xml:lang="en"><surname>Kuznetsov</surname><given-names>S. K.</given-names></name></name-alternatives><bio xml:lang="ru"><p>167982, г. Сыктывкар, ул. Первомайская, 54</p></bio><bio xml:lang="en"><p>54 Pervomaiskaya st., Syktyvkar 167982</p></bio><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Институт геологии ФИЦ Коми НЦ УрО РАН</institution><country>Россия</country></aff><aff xml:lang="en"><institution>N.P. Yushkin Institute of Geology, FRC Komi SC UB RAS</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2024</year></pub-date><pub-date pub-type="epub"><day>08</day><month>07</month><year>2024</year></pub-date><volume>24</volume><issue>3</issue><fpage>526</fpage><lpage>546</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Онищенко C.А., Кузнецов С.К., 2024</copyright-statement><copyright-year>2024</copyright-year><copyright-holder xml:lang="ru">Онищенко C.А., Кузнецов С.К.</copyright-holder><copyright-holder xml:lang="en">Onishchenko S.A., Kuznetsov S.K.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://www.lithosphere.ru/jour/article/view/2099">https://www.lithosphere.ru/jour/article/view/2099</self-uri><abstract><p>Объект исследований. Минералы палладия и платины, локализованные преимущественно в прожилках хромсодержащей слюды (фуксите) в риолитах. Цель исследований. Уточнение особенностей локализации минералов платиновой группы, их видового разнообразия, определение состава минералов, взаимоотношений между минералами благородных металлов, установление последовательности образования. Методы. Изучались полированные шлифы из образцов руд и монтированных в эпоксидной смоле концентратов тяжелых минералов с использованием оптического и электронного микроскопов. Состав минералов определялся на сканирующем электронном микроскопе с энергодисперсионным спектрометром. Результаты. Основные Pd минералы месторождения – изомертиит/псевдомертиит и мертиит, второстепенные – атенеит и неназванный минерал платиновой группы Pd6BiSe, платиновый минерал – сперрилит. Изомертиит/псевдомертиит образует срастания с золотом любого состава и строения, а мертиит встречается только с относительно маломедистым золотом гомогенного строения, в связи с чем для значительных участков рудных зон характерно наличие одного из арсеноантимонидов палладия. В отдельных участках руд установлено замещение изомертиита/псевдомертиита мертиитом. Выводы. Формирование фукситовых прожилков и содержащихся в них самородного золота, палладиевых минералов и сперрилита связано с одной стадией минералообразования. Cr, Au, Pd и Pt в рудах составляют единую геохимическую ассоциацию, что свидетельствует об общем источнике этих элементов, в качестве которого наиболее вероятны производные базитгипербазитового магматизма.</p></abstract><trans-abstract xml:lang="en"><p>Research subject. Minerals of palladium, platinum, and native gold, localized mainly in the veins of chromium-containing mica (fuchsite) in rhyolites. Aim. Clarification of the localization features of platinum group minerals, their species diversity, determination of the composition of minerals, relationships between precious metal minerals, establishment of the sequence of formation. Methods. Polished sections from ore samples and concentrates of heavy minerals mounted in epoxy resin were studied using optical and electron microscopes. The composition of minerals was determined using a scanning electron microscope with an energy dispersive spectrometer. Results. The main Pd minerals of the deposit are isomertieite/pseudomertieite and mertieite, the minor ones are ateneite and the unnamed Pd6BiSe mineral, and the platinum mineral is sperrylite. Isomertieite/pseudomertieite forms intergrowths with gold of any composition and structure, while mertieite occurs only with relatively low-copper gold of a homogeneous structure; therefore, significant areas of ore zones are characterized by the presence of one of the palladium arsenoantimonides. In some areas of ores, the replacement of isomertieite/pseudomertieite by mertieite wass established. Conclusions. The formation of fuchsite veinlets and the native gold, palladium minerals, and sperrylite contained therein is associated with one stage of mineral formation. Cr, Au, Pd, and Pt in ores form a single geochemical association, which indicates a common source of these elements. This source is most likely to be derivatives of basite-hyperbasite magmatism.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>Cu-Pd-содержащее золото</kwd><kwd>изомертиит</kwd><kwd>псевдомертиит (мертиит-I)</kwd><kwd>мертиит (мертиит-II)</kwd><kwd>атенеит</kwd><kwd>сперрилит</kwd><kwd>падмаит</kwd><kwd>неназванные минералы платиновой группы Pd6BiSe и Pd3Bi2Se2</kwd><kwd>самородный палладий</kwd><kwd>соболевскит</kwd><kwd>оксиды Pd</kwd></kwd-group><kwd-group xml:lang="en"><kwd>Cu-Pd-containing gold</kwd><kwd>isomertieite</kwd><kwd>pseudomertieite (mertieite-I)</kwd><kwd>mertieite (mertieite-II)</kwd><kwd>atheneite</kwd><kwd>sperrylite</kwd><kwd>padmaite</kwd><kwd>unnamed Pd6BiSe mineral</kwd><kwd>unnamed Pd3Bi2Se2 mineral</kwd><kwd>native palladium</kwd><kwd>sobolevskite</kwd><kwd>Pd oxides</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Аникина Е.В., Алексеев А.В. (2010) Минералого-геохимическая характеристика золото-палладиевого оруденения в Волковском габбро-диоритовом массиве (Платиноносный пояс Урала). Литосфера, (5), 75-100.</mixed-citation><mixed-citation xml:lang="en">Anikina E.V., Alekseev A.V. (2010) Mineral-geochemical characteristic of gold-palladium mineralization in the Volkov gabbro massif (Platinifirous Urals Belt). Lithosphere (Russia), (5), 75-100. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Билибина Т.В., Мельников Е.К., Савицкий А.В. (1991) О новом типе месторождений комплексных руд в Южной Карелии. Геология рудн. месторождений, 33(6), 3-14.</mixed-citation><mixed-citation xml:lang="en">Bilibina T.V., Mel’nikov E.K., Savitskii A.V. (1991) A new type of deposits of composite ores in southern Karelia. Geol. Rudn. Mestorozhd., 33(6), 3-14. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Борисов А.В. (2005) Геолого-генетические особенности Au-Pd-REE рудопроявлений хребта Малдынырд (Приполярный Урал). Дисс. … канд. геол.-мин. наук. М.: МГУ, 27 с.</mixed-citation><mixed-citation xml:lang="en">Bindi L. (2010) Atheneite, [Pd2][As0.75Hg0.25], from Itabira, Minas Gerais, Brazil: Crystal structure and revision of the chemical formula. Canad. Miner., 48, 1149-1155. https://doi.org/10.3749/canmin.48.5.1149</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Галанкина О.Л., Гавриленко В.В., Гайдамако И.М. (1998) Новые данные о минералогии гидротермального золото-платиноидного оруденения Приполярного Урала. Зап. ВМО, (3), 72-78.</mixed-citation><mixed-citation xml:lang="en">Borisov A.V. (2005) Geological and genetic features of the Au–Pd–REE ore occurrences of the Maldynyrd ridge (Subpolar Urals). Cand. geol. and min. sci. diss. Moscow, 27 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Калинин Ю.А., Боровиков А.А., Maacha L., Zuhair M., Пальянова Г.А., Житова Л.М. (2022) Au-Pd минерализация и рудообразующие флюиды месторождения Блейда Фар Вест (Анти-Атлас, Марокко). Литосфера, 22(5), 644-666. https://doi.org/10.24930/1681-9004-2022-22-5-644-666</mixed-citation><mixed-citation xml:lang="en">Cabral A.R., Lehmann B., Kwitko-Ribeiro R., Cravo Costa C.H. (2002) Palladium and Platinum Minerals from the Serra Pelada Au-Pd-Pt Deposit, Carajas Mineral Province, Northern Brazil. Canad. Miner., 40(5), 1451-1463.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Калустов С.В., Ефанова Л.И. (2013) Золоторудное месторождение Чудное на этапе подготовки к промышленному освоению. Горн. журн., (9), 42-44.</mixed-citation><mixed-citation xml:lang="en">Cabri L.J. (2002) The Platinum-Group Minerals. In The Geology, Geochemistry, Mineralogy and mineral beneficiation of platinum-group elements. (Ed. L.J. Cabri). Canadian Institute of Mining, Metallurgy and Petroleum. Spec. V. 54, 13-129.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Кузнецов С.К., Андреичев В.Л. (1998) Возраст золотофукситовой минерализации в риолитах хребта Малдынырд. Золото, платина и алмазы Республики Коми и сопредельных регионов. Мат-лы Всерос. конф. Сыктывкар, 18-19.</mixed-citation><mixed-citation xml:lang="en">Chernikov A.A., Chistyakova N.I., Uvarkina O.M., Dubinchuk V.G., Rassulov V.A., Polekhovsky Yu.S. (2006) Malyshevite PdBiCuS3 – a new mineral from the Srednaya Padma deposit in South Karelia. New Data Miner., 41, 14-17. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Кузнецов С.К., Майорова Т.П., Шайбеков Р.И., Сокерина Н.В., Филиппов В.Н. (2014) Минеральный состав и условия формирования золото-платино-палладиевых проявлений севера Урала и Пай-Хоя. Геология и минерально-сырьевые ресурсы Сибири, S3-1, 81-85.</mixed-citation><mixed-citation xml:lang="en">El Ghorfi M., Oberthur T., Melcher F., Luders V., El Boukhari A., Maacha L., Ziadi R., Baoutoul H. (2006) Goldpalladium mineralization at Bleida Far West, Bou Azzer-El Graara Inlier, Anti-Atlas, Morocco. Miner. Depos., 41, 549-564. https://doi.org/10.1007/s00126-006-0077-3</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Кузнецов С.К., Онищенко С.А. (2018) Золотоносность локальных участков метасоматического изменения риолитов месторождения Чудное (Приполярный Урал). Вестн. ИГ Коми НЦ УрО РАН, (12), 39-45. https://doi.org/10.19110/2221-1381-2018-12-39-45</mixed-citation><mixed-citation xml:lang="en">Galankina O.L., Gavrilenko V.V., Gaidamako I.M. (1998) New data on mineralogy of the hydrothermal gold-PGE mineralization at the Polar Urals. Zapiski VMO, (3), 72- 78. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Кулешевич Л.В., Голубев А.И. (2012) Благородные металлы в щелочных метасоматитах Средней Падмы, Карелия. Руды и металлы, (1), 17-25.</mixed-citation><mixed-citation xml:lang="en">Kalinin Yu.A., Borovikov A.A., Maacha L., Zuhair M., Palyanova G.A., Zhitova L.M. (2022) Au-Pd mineralization and ore-forming fluids of the Bleïda Far West deposit (Anti-Atlas, Morocco). Lithosphere (Russia), 22(5), 644-666. (In Russ.) https://doi.org/10.24930/1681-9004-2022-22-5-644-666</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Моралев Г.В., Борисов А.В., Суренков С.В., Тарбаев М.Б., Пономарчук В.А. (2005) Первые 39Ar/40Ar датировки слюд Au-Pd-РЗЭ проявления Чудное (Приполярный Урал). Докл. АН, 400(2), 243-246.</mixed-citation><mixed-citation xml:lang="en">Kalustov S.V., Efanova L.I. (2013) The Chudnoe gold deposit at the stage of preparation for commercial exploration. Gornyi Zhurnal, (9), 42-44. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Мурзин В.В., Пальянова Г.А., Аникина Е.В., Молошаг В.П. (2021) Минералогия благородных металлов (Au, Ag, Pd, Pt) Волковского Cu-Fe-Ti-V месторождения (Средний Урал). Литосфера, 21(5), 643-659. https://doi.org/10.24930/1681-9004-2021-21-5-643-659</mixed-citation><mixed-citation xml:lang="en">Karimova O.V., Grokhovskaya T.L., Zolotarev A.A., Gurzhiy V.V. (2016) Crystal structure refinements of isomertieite, Pd11Sb2As2, and tornroosite, Pd11As2Te2. Canad. Miner., 54, 511-517. https://doi.org/10.3749/canmin.1500039</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Онищенко С.А., Кузнецов С.К. (2019) Палладийзолотосульфидная минерализация в андезитах на месторождении Чудное (Приполярный Урал). Вестн. Ин-та геол. Коми НЦ УрО РАН, (6), 20-27. https://doi.org/10.19110/2221-1381-2019-6-20-27</mixed-citation><mixed-citation xml:lang="en">Karimova O.V., Mezhueva A.A., Zgurskiy N.A., Zolotarev A.A., Chareev D.A. (2022) The crystal structure of Pd8As3, a synthetic analogue of stillwaterite. Miner. Mag., 86(3), 492-499. https://doi.org/10.1180/mgm.2022.57</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Онищенко С.А., Кузнецов С.К. (2022) Распад твердого раствора в системе Au-Ag-Cu в богатой золотом области. Геохимия, 67(7), 639-654. https://doi.org/10.31857/S0016752522060061</mixed-citation><mixed-citation xml:lang="en">Karimova O.V., Zolotarev A.A., Evstigneeva T.L., Johanson B.S. (2018) Mertieite-II, Pd8Sb2.5As0.5, crystal-structure refinement and formula revision. Miner. Mag., 82, 247-257. https://doi.org/10.1180/minmag.2017.081.052</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Онищенко С.А., Кузнецов С.К. (2023) Самородное золото Au-Pd месторождения Чудное (Приполярный Урал, Россия). Геология и геофизика, 64(2), 233-254. https://doi.org/10.15372/GiG2022122</mixed-citation><mixed-citation xml:lang="en">Karimova O.V., Zolotarev A.A., Johanson B.S., Evstigneeva T.L. (2020) The crystal structure of arsenopalladinite, Pd8As2.5Sb0.5, and its relation to mertieite-II, Pd8Sb2.5As0.5. Miner. Mag., 84, 746-752. https://doi.org/10.1180/mgm.2020.65</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Онищенко С.А., Кузнецов С.К., Тропников Е.М. (2022) Минеральные фазы системы Pd–Bi–Se в рудах AuPd-месторождения Чудное (Приполярный Урал, Россия). Докл. РАН. Науки о Земле, 504(1), 41-45. https://doi.org/10.31857/S2686739722050115</mixed-citation><mixed-citation xml:lang="en">Kuznetsov S.K., Andreichev V.L. (1998) The age of gold– fuchsite mineralization in rhyolites of the Maldynyrd Ridge. Gold, Platinum, and Diamonds of the Komi Republic and Adjacent Regions. Proceedings of the AllRussian Conference. Syktyvkar, 18-19. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Онищенко С.А., Онищенко Л.В., Ефанова Л.И., Артеева Т.А. (2014) Золоторудное месторождение Чудное на Приполярном Урале. Геология и минеральные ресурсы Eвропейского Cеверо-Востока России. Матлы XVI съезда Республики Коми. Т. III. Сыктывкар: ИГ Коми НЦ УрО РАН, 172-175.</mixed-citation><mixed-citation xml:lang="en">Kuznetsov S.K., Maiorova T.P., Shaibekov R.I., Sokerina N.V., Filippov V.N. (2014) Mineral composition and conditions for the formation of gold-platinum-palladium occurrences in the north of the Urals and Pai-Khoi. Geologiya i Mineral’nye Resyrsy Sibiri, S3-1, 81-85. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Онищенко С.А., Сокерина Н.В., Кузнецов С.К., Исаенко С.И., Тропников Е.М. (2024) Стадийность формирования кварц-альбит-алланит-фукситовых прожилков на Au-Pd-месторождении Чудное (Приполярный Урал). Вестн. геонаук. 349(1), 4-15. https://doi.org/10.19110/geov.2024.1.1</mixed-citation><mixed-citation xml:lang="en">Kuznetsov S.K., Onishchenko S.A. (2018) Gold content of local areas of metasomatic alteration of rhyolites of the Chudnoe deposit (Subpolar Urals). Vestnik IG Ko mi NTs UrO RAN, (12), 39-45. (In Russ.) https://doi.org/10.19110/2221-1381-2018-12-39-45</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Пеков И.В., Чуканов Н.В., Румянцева Е.В., Кабалов Ю.К., Шнайдер Ю., Леденева Н.В. (2000) Хромселадонит KCrMg[Si4O10](OH)2 – новый минерал из группы слюд. Зап. ВМО, 129(1), 38-44.</mixed-citation><mixed-citation xml:lang="en">Kuleshevich L.V., Golubev A.I. (2012) Noble metals in alkaline metasomatites at Srednyia Padma, Karelia. Rudy i Metally, (1), 17-25. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Полеховский Ю.С., Волошин А.В., Тарасова И.П., Никитин С.А., Пахомовский Я.А., Меньшиков Ю.П., Крецер Ю.Л., Колычева Т.И. (1991а) Падмаит PdBiSe – новый селенид палладия и висмута из метасоматитов южной Карелии. Зап. ВМО, (3), 85-88.</mixed-citation><mixed-citation xml:lang="en">Menez J., Botelho N.F. (2017) Ore characterization and textural relationships among gold, selenides, platinumgroup minerals and uraninite at the granite-related Buraco do Ouro gold mine, Cavalcante, Central Brazil. Miner. Mag., 81(3), 463-475. https://doi.org/10.1180/minmag.2016.080.101</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Полеховский Ю.С., Волошин А.В., Тарасова И.П., Пахомовский Я.А., Крецер Ю.Л. (1991б) Новый тип палладийсодержащей минерализации в метасоматитах Карелии. Изв. АН СССР. Сер. геол., (7), 86-95.</mixed-citation><mixed-citation xml:lang="en">Miyawaki R., Hatert F., Pasero M., Mills S.J. (2022) CNMNC Newsletter 69. Eur. J. Mineral., 34, 463-468. https://doi.org/10.5194/ejm-34-463-2022</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Полеховский Ю.С., Тарасова И.П., Нестеров А.Р., Пахомовский Я.А., Бахчисарайцев А.Ю. (1997) Судовиковит PtSe2 – новый селенид платины из метасоматитов Южной Карелии. Докл. АН, 354(1), 82-85.</mixed-citation><mixed-citation xml:lang="en">Moralev G.V., Borisov A.V., Surenkov S.V., Tarbaev M.B., Ponomarchuk V.A. (2005). First 39Ar–40Ar datings on micas from the Chudnoe Au–Pd–REE occurrence, NearPolar Urals. Dokl. Earth Sci., 400(2), 109-112 (translated from Dokl. Akad. Nauk, 400(2), 243-246).</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Пыстин А.М., Потапов И.Л., Пыстина Ю.И., Генералов В.И., Онищенко С.А., Филиппов В.Н., Шлома А.А., Терешко В.В. (2011) Малосульфидное платинометалльное оруденение на Полярном Урале. Екатеринбург: Изд-во УрО РАН, 150 с.</mixed-citation><mixed-citation xml:lang="en">Murzin V.V., Chudnenko K.V., Palyanova G.A., Varlamov D.A., Naumov E.A., Pirajno F. (2018) Physicochemical model for the genesis of Cu-Ag-Au-Hg solid solutions and intermetallics in the rodingites of the Zolotaya Gora gold deposit (Urals, Russia). Ore Geol. Rev., 93, 81-97. https://doi.org/10.1016/j.oregeorev.2017.12.018</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Рудашевский Н.С., Рудашевский В.Н., Ниелсен Т.Ф.Д. (2015) Интерметаллиды и сплавы меди и палладия в золото-палладиевых рудах Скаергардского массива (Гренландия). Зап. РМО, 144(1), 30-53.</mixed-citation><mixed-citation xml:lang="en">Murzin V.V., Palyanova G.A., Anikina E.V., Moloshag V.P. (2021) Mineralogy of noble metals (Au, Ag, Pd, Pt) in Volkovskoe Cu-Fe-Ti-V deposit (Middle Urals, Russia). Lithosphere (Russia), 21(5), 643-659. (In Russ.) https://doi.org/10.24930/1681-9004-2021-21-5-643-659</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Сазонов В.Н., Огородников В.Н., Коротеев В.А., Поленов Ю.А. (2001) Месторождения золота Урала. Екатеринбург: УГГГА, 622 с.</mixed-citation><mixed-citation xml:lang="en">Murzin V., Palyanova G., Mayorova T., Beliaeva T. (2022) The Gold-Palladium Ozernoe Occurrence (Polar Urals, Russia): Mineralogy, Conditions of Formation, Sources of Ore Matter and Fluid. Minerals, 12, 765. https://doi.org/10.3390/min12060765</mixed-citation></citation-alternatives></ref><ref id="cit26"><label>26</label><citation-alternatives><mixed-citation xml:lang="ru">Спиридонов Э.М., Кулагов Э.А., Куликова И.М. (2004) Ассоциации минералов палладия, платины и золота в рудах Норильского месторождения. Геология рудн. месторождений, 46(2), 175-192.</mixed-citation><mixed-citation xml:lang="en">Nielsen T.F.D., Keiding J.K., Andersen J.C.Ø., Holness M.B., Keiding J.K., Rudashevsky N.S., Rudashevsky V.N., Salmonsen L.P., Tegner C., Veksler I.V. (2015) The Skaergaard PGE and gold deposit: The result of in situ fractionation, sulphide saturation, and magma chamber-scale precious metal redistribution by immiscible Fe-rich melt. J. Petrol., 56(8), 1643-1676. https://doi.org/10.1093/petrology/egv049</mixed-citation></citation-alternatives></ref><ref id="cit27"><label>27</label><citation-alternatives><mixed-citation xml:lang="ru">Спиридонов Э.М., Кулагов Э.А., Серова А.А., Куликова И.М., Коротаева Н.Н., Середа Е.В., Тушенцова И.Н., Беляков С.Н., Жуков Н.Н. (2015) Генетическая минералогия Pd, Pt, Au, Ag, Rh в Норильских сульфидных рудах. Геология рудн. месторождений, 57(5), 445-476. https://doi.org/10.7868/S0016777015050068</mixed-citation><mixed-citation xml:lang="en">Olivo G.R., Gauthier M., Bardoux M., Leao de Sa E., Fonseca J.T.F., Santana F.C. (1995) Palladium-bearing gold deposit hosted by Proterozoic lake superior-type ironformation at the Caue iron mine, Itabira District, southern Sao Francisco Craton, Brazil: Ggeologic and structural controls. Econ. Geol., 90, 118-134. https://doi.org/10.2113/gsecongeo.90.1.118</mixed-citation></citation-alternatives></ref><ref id="cit28"><label>28</label><citation-alternatives><mixed-citation xml:lang="ru">Тарбаев М.Б., Кузнецов С.К., Моралев Г.В., Соболева А.А., Лапутина И.П. (1996) Новый золотопалладиевый тип минерализации в Кожимском районе Приполярного Урала (Россия). Геология рудн. месторождений, 38(1), 15-30.</mixed-citation><mixed-citation xml:lang="en">Olivo G.R., Gauthier M., Williams-Jones A.E., Levesque M. (2001) The Au-Pd mineralization at the Conceição iron mine, Itabira District, southern Sao Francisco Craton, Brazil: An example of a jacutinga-type deposit. Econ. Geol., 96, 61-74. https://doi.org/10.2113/gsecongeo.96.1.61</mixed-citation></citation-alternatives></ref><ref id="cit29"><label>29</label><citation-alternatives><mixed-citation xml:lang="ru">Черников А.А., Чистякова Н.И., Уваркина О.М., Дубинчук В.Г., Рассулов В.А., Полеховский Ю.С. (2006) Малышевит PdBiCuS3 – новый минерал из месторождения Средняя Падма в Южной Карелии. Новые данные о минералах, (41), 14-17.</mixed-citation><mixed-citation xml:lang="en">Onishchenko S.A., Kuznetsov S.K. (2022) Exsolution in the Au–Ag–Cu System in a Gold-Rich Area. Geochem. Int., 60(7), 657-671 (translated from Geochimiya, 67(7), 639-654). https://doi.org/10.1134/S0016702922060064</mixed-citation></citation-alternatives></ref><ref id="cit30"><label>30</label><citation-alternatives><mixed-citation xml:lang="ru">Шумилов И.Х., Остащенко Б.А. (2000) Минералоготехнологические особенности Au-Pd-TR оруденения на Приполярном Урале. Сыктывкар: Геопринт, 104 с.</mixed-citation><mixed-citation xml:lang="en">Onishchenko S.A., Kuznetsov S.K. (2023) Native Gold of the Chudnoe Gold–Palladium Deposit (Subpolar Urals, Russia). Russ. Geol. Geophys., 64(2), 192-209 (translated from Geologya i Geofizika, 64(2), 233-254). https://doi.org/10.2113/RGG20214452</mixed-citation></citation-alternatives></ref><ref id="cit31"><label>31</label><citation-alternatives><mixed-citation xml:lang="ru">Bindi L. (2010) Atheneite, [Pd2][As0.75Hg0.25], from Itabira, Minas Gerais, Brazil: Crystal structure and revision of the chemical formula. Canad. Miner., 48, 1149-1155. https://doi.org/10.3749/canmin.48.5.1149</mixed-citation><mixed-citation xml:lang="en">Onishchenko S.A., Kuznetsov S.K. (2019) Palladium-goldsulphide mineralization in andesites at Chudnoe deposit (Subpolar Urals). Vestnik IG Komi NTs UrO RAN, (6), 20-27. (In Russ.) https://doi.org/10.19110/2221-1381-2019-6-20-27</mixed-citation></citation-alternatives></ref><ref id="cit32"><label>32</label><citation-alternatives><mixed-citation xml:lang="ru">Cabral A.R., Lehmann B., Kwitko-Ribeiro R., Cravo Costa C.H. (2002) Palladium and Platinum Minerals from the Serra Pelada Au–Pd–Pt Deposit, Carajas Mineral Province, Northern Brazil. Canad. Miner., 40(5), 1451-1463.</mixed-citation><mixed-citation xml:lang="en">Onishchenko S.A., Kuznetsov S.K., Tropnikov E.M. (2022) Mineral Phases of the Pd–Bi–Se System in the Ores at the Chudnoe Au–Pd Deposit (Subpolar Urals, Russia). Dokl. Earth Sci., 504(1), 266-270 (translated from Dokl. Akad. Nauk, 504(1), 41-45). https://doi.org/10.1134/ S1028334X22050117</mixed-citation></citation-alternatives></ref><ref id="cit33"><label>33</label><citation-alternatives><mixed-citation xml:lang="ru">Cabri L.J. (2002) The Platinum-Group Minerals. In The Geology, Geochemistry, Mineralogy and mineral beneficiation of platinum-group elements. (Ed. L.J. Cabri). Canadian Institute of Mining, Metallurgy and Petroleum. Spec. V. 54, 13-129.</mixed-citation><mixed-citation xml:lang="en">Onishchenko S.A., Onishchenko L.V., Efanova L.I., Arteeva T.A. (2014) The Chudnoe gold deposit in the Subpolar Urals. Geology and Mineral Resources of the European Northeastern Russia. Proceedings of the 16th Komi Republic Meeting. V. 3. Syktyvkar, IG Komi NTs UrO RAN Publ., 172-175. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit34"><label>34</label><citation-alternatives><mixed-citation xml:lang="ru">El Ghorfi M., Oberthur T., Melcher F., Luders V., El Boukhari A., Maacha L., Ziadi R., Baoutoul H. (2006) Goldpalladium mineralization at Bleida Far West, Bou Azzer-El Graara Inlier, Anti-Atlas, Morocco. Miner. Depos., 41, 549-564. https://doi.org/10.1007/s00126-006-0077-3</mixed-citation><mixed-citation xml:lang="en">Onishchenko S.A., Sokerina N.V., Kuznetsov S.K., Isaenko S.I., Tropnikov E.M. (2024) Stages of formation of quartz-albite-allanite-fuchsite veins at the Chudnoe AuPd deposit (Subpolar Urals). Vestnik of Geosciences 349(1), 4-15. (In Russ.). https://doi.org/10.19110/geov.2024.1.1</mixed-citation></citation-alternatives></ref><ref id="cit35"><label>35</label><citation-alternatives><mixed-citation xml:lang="ru">Karimova O.V., Grokhovskaya T.L., Zolotarev A.A., Gurzhiy V.V. (2016) Crystal structure refinements of isomertieite, Pd11Sb2As2, and tornroosite, Pd11As2Te2. Canad. Miner., 54, 511-517. https://doi.org/10.3749/canmin.1500039</mixed-citation><mixed-citation xml:lang="en">Orth K., Meffre S., Davidson G. (2014) Age and paragenesis of mineralisation at Coronation Hill uranium deposit, Northern Territory, Australia. Miner. Depos., 49(5), 595- 623. https://doi.org/10.1007/s00126-013-0501-4</mixed-citation></citation-alternatives></ref><ref id="cit36"><label>36</label><citation-alternatives><mixed-citation xml:lang="ru">Karimova O.V., Mezhueva A.A., Zgurskiy N.A., Zolotarev A.A., Chareev D.A. (2022) The crystal structure of Pd8As3, a synthetic analogue of stillwaterite. Miner. Mag., 86(3), 492-499. https://doi.org/10.1180/mgm.2022.57</mixed-citation><mixed-citation xml:lang="en">Palyanova G., Murzin V., Borovikov A., Karmanov N., Kuznetsov S. (2021) Native Gold in the Chudnoe AuPd-REE Deposit (Subpolar Urals, Russia): Composition, Minerals in Intergrowth and Genesis. Minerals, 11, 451. https://doi.org/10.3390/min11050451</mixed-citation></citation-alternatives></ref><ref id="cit37"><label>37</label><citation-alternatives><mixed-citation xml:lang="ru">Karimova O.V., Zolotarev A.A., Evstigneeva T.L., Johanson B.S. (2018) Mertieite-II, Pd8Sb2.5As0.5, crystal-structure refinement and formula revision. Miner. Mag., 82, 247-257. https://doi.org/10.1180/minmag.2017.081.052</mixed-citation><mixed-citation xml:lang="en">Pekov I.V., Chukanov N.V., Rumiantseva E.V., Kabalov Yu.K., Schneider Yu., Ledeneva N.V. (2000) Chromceladonite KCrMg[Si4O10](OH)2 – a new mineral of the mica group. Zapiski VMO, 129(1), 38-44. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit38"><label>38</label><citation-alternatives><mixed-citation xml:lang="ru">Karimova O.V., Zolotarev A.A., Johanson B.S., Evstigneeva T.L. (2020) The crystal structure of arsenopalladinite, Pd8As2.5Sb0.5, and its relation to mertieite-II, Pd8Sb2.5As0.5. Miner. Mag., 84, 746-752. https://doi.org/10.1180/mgm.2020.65</mixed-citation><mixed-citation xml:lang="en">Polekhovskii Yu.S., Tarasova I.P., Nesterov A.R., Pakhomovskiy Ya.A., Bakhchisaraitsev A.Yu. (1997) Sudovikovite PtSe2 – a new platinum selenide from Karelia metasomite. Dokl. Akad. Nauk, 354(1), 82-85. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit39"><label>39</label><citation-alternatives><mixed-citation xml:lang="ru">Menez J., Botelho N.F. (2017) Ore characterization and textural relationships among gold, selenides, platinumgroup minerals and uraninite at the granite-related Buraco do Ouro gold mine, Cavalcante, Central Brazil. Miner. Mag., 81(3), 463-475. https://doi.org/10.1180/minmag.2016.080.101</mixed-citation><mixed-citation xml:lang="en">Polekhovskii Yu.S., Voloshin A.V., Tarasova I.P., Nikitin S.A., Pakhomovskii Ya.A., Men’shikov Yu.P., Kretser Yu.L., Kolycheva T.I. (1991a) Padmaite PdBiSe – a new selenide of palladium and bismuth from metasomatites of South Karelia. Zapiski VMO, (3), 85-88. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit40"><label>40</label><citation-alternatives><mixed-citation xml:lang="ru">Miyawaki R., Hatert F., Pasero M., Mills S.J. (2022) CNMNC Newsletter 69. Eur. J. Mineral., 34, 463-468. https://doi.org/10.5194/ejm-34-463-2022</mixed-citation><mixed-citation xml:lang="en">Polekhovskii Yu.S., Voloshin A.V., Tarasova I.P., Pakhomovskii Ya.A., Kretser Yu.L. (1991b) A new type of palladium-containing mineralization in Karelian metasomatites. Izv. AN SSSR. Ser. Geol., (7), 86-95. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit41"><label>41</label><citation-alternatives><mixed-citation xml:lang="ru">Murzin V.V., Chudnenko K.V., Palyanova G.A., Varlamov D.A., Naumov E.A., Pirajno F. (2018) Physicochemical model for the genesis of Cu-Ag-Au-Hg solid solutions and intermetallics in the rodingites of the Zolotaya Gora gold deposit (Urals, Russia). Ore Geol. Rev., 93, 81-97. https://doi.org/10.1016/j.oregeorev.2017.12.018</mixed-citation><mixed-citation xml:lang="en">Pystin A.M., Potapov I.L., Pystina Yu.I., Generalov V.I., Onishchenko S.A., Filippov V.N., Shloma A.A., Tereshko V.V. (2011) Low-sulfide platinum-metal mineralization in the Polar Urals. Ekaterinburg, UrO RAN, 150 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit42"><label>42</label><citation-alternatives><mixed-citation xml:lang="ru">Murzin V., Palyanova G., Mayorova T., Beliaeva T. (2022) The Gold-Palladium Ozernoe Occurrence (Polar Urals, Russia): Mineralogy, Conditions of Formation, Sources of Ore Matter and Fluid. Minerals, 12, 765. https://doi.org/10.3390/min12060765</mixed-citation><mixed-citation xml:lang="en">Rudashevsky N.S., Rudashevsky V.N., Nielsen T.F.D. (2015) Intermetallic compounds, copper-palladium alloys in the Au-Pd ores of the Skaaergaard pluton, Greenland. Geol. Ore Depos., 57(8), 674-690 (translated from Zapiski RMO, 144(1), 30-53). https://doi.org/10.1134/ S1075701515080085</mixed-citation></citation-alternatives></ref><ref id="cit43"><label>43</label><citation-alternatives><mixed-citation xml:lang="ru">Nielsen T.F.D., Keiding J.K., Andersen J.C.Ø., Holness M.B., Keiding J.K., Rudashevsky N.S., Rudashevsky V.N., Salmonsen L.P., Tegner C., Veksler I.V. (2015) The Skaergaard PGE and gold deposit: The result of in situ fractionation, sulphide saturation, and magma chamber-scale precious metal redistribution by immiscible Fe-rich melt. J. Petrol., 56(8), 1643-1676. https://doi.org/10.1093/petrology/egv049</mixed-citation><mixed-citation xml:lang="en">Sazonov V.N., Ogorodnikov V.N., Koroteev V.A., Polenov Yu.A. (2001) Gold Deposits of the Urals. Ekaterinburg, UGGGA, 622 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit44"><label>44</label><citation-alternatives><mixed-citation xml:lang="ru">Olivo G.R., Gauthier M., Bardoux M., Leao de Sa E., Fonseca J.T.F., Santana F.C. (1995) Palladium-bearing gold deposit hosted by Proterozoic lake superior-type ironformation at the Caue iron mine, Itabira District, southern Sao Francisco Craton, Brazil: Geologic and structural controls. Econ. Geol., 90, 118-134. https://doi.org/10.2113/gsecongeo.90.1.118</mixed-citation><mixed-citation xml:lang="en">Şener A.K., Grainger C.J., Groves D.I. (2002) Epigenetic gold-platinum-group element deposits: examples from Brazil and Australia. Trans. Inst. Mining Metall., 111(1), 65-73. http://dx.doi.org/10.1179/aes.2002.111.1.65</mixed-citation></citation-alternatives></ref><ref id="cit45"><label>45</label><citation-alternatives><mixed-citation xml:lang="ru">Olivo G.R., Gauthier M., Williams-Jones A.E., Levesque M. (2001) The Au-Pd mineralization at the Conceição iron mine, Itabira District, southern Sao Francisco Craton, Brazil: An example of a jacutinga-type deposit. Econ. Geol., 96, 61-74. https://doi.org/10.2113/gsecongeo.96.1.61</mixed-citation><mixed-citation xml:lang="en">Shumilov I.Kh., Ostashchenko B.A. (2000) Mineral and technological features of Au-Pd-TR mineralization in the Subpolar Urals. Syktyvkar, Geoprint Publ., 104 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit46"><label>46</label><citation-alternatives><mixed-citation xml:lang="ru">Orth K., Meffre S., Davidson G. (2014) Age and paragenesis of mineralisation at Coronation Hill uranium deposit, Northern Territory, Australia. Miner. Depos., 49(5), 595-623. https://doi.org/10.1007/s00126-013-0501-4</mixed-citation><mixed-citation xml:lang="en">Sluzhenikin S.F., Моkhov A.V. (2015) Gold and silver in PGE-Cu-Ni and PGE ores of the Norilʼsk deposits, Russia. Miner. Dep., 50(4), 465-492. https://doi.org/10.1007/s00126-014-0543-2</mixed-citation></citation-alternatives></ref><ref id="cit47"><label>47</label><citation-alternatives><mixed-citation xml:lang="ru">Palyanova G., Murzin V., Borovikov A., Karmanov N., Kuznetsov S. (2021) Native Gold in the Chudnoe AuPd-REE Deposit (Subpolar Urals, Russia): Composition, Minerals in Intergrowth and Genesis. Minerals, 11, 451. https://doi.org/10.3390/min11050451</mixed-citation><mixed-citation xml:lang="en">Spiridonov E.M., Kulagov E.A., Kulikova I.M. (2004) Palladium, platinum, and gold mineral assemblages in ores of the Norilsk deposit. Geol. Ore Depos., 46(2), 150-166 (translated from Geol. Rudn. Mestorozhd., 46(2), 175-192).</mixed-citation></citation-alternatives></ref><ref id="cit48"><label>48</label><citation-alternatives><mixed-citation xml:lang="ru">Şener A.K., Grainger C.J., Groves D.I. (2002) Epigenetic gold-platinum-group element deposits: examples from Brazil and Australia. Trans. Inst. Mining Metall., 111(1), 65-73. http://dx.doi.org/10.1179/aes.2002.111.1.65</mixed-citation><mixed-citation xml:lang="en">Spiridonov E.M., Serova A.A., Korotaeva N.N., Zhukov N.N., Kulagov E.A., Belyakov S.N., Kulikova I.M., Sereda E.V., Tushentsova I.N. (2015) Genetic Pd, Pt, Au, Ag and Rh mineralogy in Norilsk sulfide ores. Geol. Ore Depos., 57(5), 402-432 (translated from Geol. Rudn. Mestorozhd., 57(5), 445-476). https://doi.org/10.1134/S1075701515050062</mixed-citation></citation-alternatives></ref><ref id="cit49"><label>49</label><citation-alternatives><mixed-citation xml:lang="ru">Sluzhenikin S.F., Моkhov A.V. (2015) Gold and silver in PGE-Cu-Ni and PGE ores of the Norilʼsk deposits, Russia. Miner. Depos., 50(4), 465-492. https://doi.org/10.1007/s00126-014-0543-2</mixed-citation><mixed-citation xml:lang="en">Tarbaev M.B., Kuznetsov S.K., Moralev G.V., Soboleva А.А., Laputina I.P. (1996) A new gold-palladium type of mineralization in the Kozhim region of the Circumpolar Urals (Russia). Geol. Ore Depos., 38(1), 11-25 (translated from Geol. Rudn. Mestorozhd., 38(1), 15-30).</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
