litosphereЛитосфераLITHOSPHERE (Russia)1681-90042500-302XA.N. Zavaritsky Institute of Geology and Geochemistry10.24930/1681-9004-2024-24-2-300-325litosphere-2062Research ArticleСтатьиArticlesВариации изотопного состава меди и цинка в платиноидно-медно-никелевых рудах Норильской провинции (Россия)Copper and zinc isotopic variations in Ni-Cu-PGE ores of the Noril’sk Province (Russia)МаличК. Н.MalitchK. N.

620110, г. Екатеринбург, ул. Академика Вонсовского, 15

Kreshimir N. Malitch

15 Academician Vonsovsky st., Ekaterinburg 620110

dunite@yandex.ruБаданинаИ. Ю.BadaninaI. Yu.

620110, г. Екатеринбург, ул. Академика Вонсовского, 15

Inna Yu. Badanina

15 Academician Vonsovsky st., Ekaterinburg 620110

СолошенкоН. Г.SoloshenkoN. G.

620110, г. Екатеринбург, ул. Академика Вонсовского, 15

Nataliya G. Soloshenko

15 Academician Vonsovsky st., Ekaterinburg 620110

СлуженикинС. Ф.SluzhenikinS. F.

119017, г. Москва, пер. Старомонетный, 35

Sergey F. Sluzhenikin

35 Staromonetny lane, Moscow 119017

Институт геологии и геохимии им. академика А.Н. Заварицкого УрО РАНРоссияA.N. Zavaritsky Institute of Geology and Geochemistry, UB RASRussian FederationИнститут геологии рудных месторождений, петрографии, минералогии и геохимии РАНРоссияInstitute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry, RASRussian Federation202406052024242300325Copyright © Малич К.Н., Баданина И.Ю., Солошенко Н.Г., Служеникин С.Ф., 20242024Малич К.Н., Баданина И.Ю., Солошенко Н.Г., Служеникин С.Ф.Malitch K.N., Badanina I.Y., Soloshenko N.G., Sluzhenikin S.F.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.lithosphere.ru/jour/article/view/2062

Объект исследования. Минеральные ассоциации сульфидов из массивных и вкрапленных сульфидных платиноидно-медно-никелевых (ЭПГ-Cu-Ni) и малосульфидных платиноидных руд Норильской провинции, вмещающей богатейшие комплексные месторождения платиноидов, никеля и меди. Цель. Изучение вариаций изотопного состава Cu и Zn в сульфидах промышленно-рудоносных (Хараелахского и Норильск-1), рудоносных (Зуб-Маркшейдерского и Вологочанского) и слаборудоносных (Нижнеталнахского и Нижненорильского) интрузивов в целях выявления источников рудного вещества и совершенствования подходов при прогнозировании месторождений стратегических видов минерального сырья. Методы. Химический состав сульфидов изучен с помощью рентгеноспектрального микроанализа (микроанализаторы CAMECA SX 100 и JXA-8200 JEOL). Аналитическая методика определения δ65Cu и δ66Zn включала в себя растворение образцов в смеси кислот HCl и HNO3, селективное хроматографическое выделение Cu и Zn из раствора с последующим определением изотопных отношений 65Cu/63Cu и 66Zn/64Zn на масс-спектрометре Neptune Plus. Результаты. Проанализированные образцы характеризуются минеральными ассоциациями сульфидов, состоящими главным образом из халькопирита, пирротина, пентландита, троилита, кубанита и галенита. Сульфидные ЭПГ-Cu-Ni руды месторождений Октябрьское и Норильск-1, ассоциирующие с промышленно-рудоносными интрузивами (Хараелах и Норильск-1), демонстрируют дискретные диапазоны значений δ65Cu от –2.42 до –1.40 и от –0.33 до 0.60‰ соответственно, которые отличаются от значений δ65Cu для сульфидов из других месторождений и рудопроявлений Норильской провинции (данные по 36 анализам). При этом изотопный состав меди для сульфидных минералов массивных и вкрапленных руд Хараелахского интрузива обладает сходными “изотопно-легкими” характеристиками. Наиболее выраженный сдвиг в сторону “изотопнотяжелой” меди установлен в горизонте малосульфидных руд интрузива Норильск-1 (δ65Cu = 0.51–0.60‰). Изотопный состав Zn (δ66Zn) для изученных образцов сульфидов промышленно-рудоносных, рудоносных и слаборудоносных интрузивов, за исключением одного образца (0.73 ± 0.14‰), характеризуется сходными “изотопнолегкими” значениями (–0.65 … –0.03‰). Выводы. Выявленные вариации изотопного состава Cu и Zn в изученных сульфидных ассоциациях из всех типов руд отражают их первичную характеристику; тем не менее для Октябрьского ЭПГ-Cu-Ni месторождения, характеризующегося наиболее “изотопно-легким” составом меди (δ65Cu = –1.9 ± 0.34‰), нельзя исключить возможность ассимиляции внешнего источника Cu при формировании сульфидных ЭПГ-Cu-Ni руд. Сопряженный характер изотопных параметров Cu и Zn оказался слабоинформативным прогнозным индикатором обнаружения богатых сульфидных руд, прежде всего, из-за сходства изотопного состава Zn в рудном веществе из различно рудоносных интрузивов Норильской провинции.

Research subject. Mineral assemblages of sulfides from massive and disseminated sulfide nickel-copper-platinum-group element (Ni-Cu-PGE) and low-sulfide PGE ores of the Noril’sk Province, which hosts the richest complex deposits of platinum-group metals, nickel, and copper. Aim. In order to identify sources of ore material and explore new forecasting approaches for Ni-Cu-PGE deposits, we study the Cu- and Zn isotopic compositions of sulfides from economic Kharaelakh and Noril’sk-1 intrusions containing unique and large sulphide Ni-Cu-PGE deposits (Oktyabr’sk and Noril’sk-1, respectively), subeconmic Zub-Marksheider and Vologochan intrusions containing small- to medium-size Ni-Cu-PGE deposits, and non-economic Nizhny Talnakh and Nizhny Noril’sk intrusions containing low grade disseminated Ni-Cu mineralization. Results. The analyzed samples are characterized by sulfide mineral assemblages, which contain mainly chalcopyrite, pyrrhotite, pentlandite, troilite, cubanite, and galena. Sulfide Ni-Cu-PGE ores of the Oktyabr’sk and Noril’sk-1 deposits, associated with economic intrusions (i.e., Kharaelakh and Noril’sk-1), demonstrate distinct δ65Cu values from –2.42 to –1.40‰ and from –0.33 to 0.60‰, respectively, which differ from the δ65Cu values for sulfides from other Ni-Cu-PGE deposits and ore occurrences of the Noril’sk Province (data comprise 36 analyses). We note that the Cu-isotopic composition for sulfide minerals of massive and disseminated ores from the Kharaelakh intrusion has similar “isotope-light” characteristics. The most pronounced shift towards “isotope-heavy” copper was found in the horizon of low-sulfide PGE ores of the Noril’sk-1 intrusion (δ65Cu = 0.51–0.60‰). The isotopic composition of Zn (δ66Zn) for the studied sulfide samples from economic, subeconomic, and non-economic intrusions, with the exception of one sample (0.73 ± 0.14‰), is characterized by similar “isotope-light” values (from –0.65 to –0.03‰). Conclusions. The revealed variations in the Cu- and Zn-isotopic composition in the studied sulfide assemblages from all types of ores reflect their primary characteristics; however, for the unique Oktyabr’sk Ni-Cu-PGE deposit, characterized by the most “isotopically light” composition of copper (δ65Cu = –1.9 ± 0.34‰), the possibility of assimilation of an external source of Cu during the formation of sulfide Ni-Cu-PGE ores cannot be excluded. The combined use of Cu and Zn isotopic parameters proved to be a weakly informative predictive indicator for the detection of high-grade sulfide ores, primarily due to the similarity of the Zn isotopic composition of the ore material in all investigated intrusions of the Noril’sk Province.

сульфидные ЭПГ-Cu-Ni рудымалосульфидные платиноидные рудыCu-Zn изотопные системыисточники веществаусловия образованияНорильская провинцияsulfide Ni-Cu-PGE oreslow-sulfide PGE oresCu-Zn isotope systemssource of ore materialformation conditionsNoril’sk ProvinceИсследование выполнено при поддержке Министерства науки и высшего образования Российской Федерации в рамках государственного задания ИГГ УрО РАН (№№ госрегистрации 122022600107-1 и 123011800012-9) при использовании оборудования ЦКП “Геоаналитик” ИГГ УрО РАН (соглашение № 075-15-2021-680). Авторы признательны Н.С. Чебыкину и Т.Г. Окуневой за помощь при проведении минералого-геохимических исследований и анонимным рецензентам за конструктивные замечания, которые способствовали улучшению рукописи.This investigation was supported by Ministry of Science and Higher Education of the Russian Federation and was carried out as part of the state assignment of IGG UB RAS (No. 122022600107-1 and 123011800012-9) using the re-equipment and comprehensive development of the “Geoanalitik” shared research facilities of IGG UB RAS (Agreement No. 075-15- 2021-680). The authors are grateful to N.S. Chebykin and T.G. Okuneva for assistance during mineralogical and geochemical studies and anonymous reviewers for their constructive comments that led to improvement of the manuscript.ReferencesБогатиков О.А., Коваленко В.И., Шарков Е.В. (2010) Магматизм, тектоника, геодинамика Земли: связь во времени и в пространстве. М.: Наука, 605 с.Albarède F. (2004) The stable isotope geochemistry of copper and zinc. Rev. Mineral. Geochem., 55, 409-427.Генкин А.Д., Дистлер В.В., Гладышев Г.Д., Филимонова А.А., Евстигнеева Т.Л., Коваленкер В.А., Лапутина И.П., Смирнов А.В., Гроховская Т.Л. (1981) Сульфидные медно-никелевые руды норильских месторождений. М.: Наука, 234 с.Albarede F. (2009) Volatile accretion history of the terrestrial planets and dynamic implications. Nature, 461, 1227-1233.Годлевский М.Н. (1959) Траппы и рудоносные интрузии Норильского района. М.: Гостехметиздат, 68 с.Arndt N.T., Czamanske G.K., Walker R.J., Chauvel C., Fedorenko V.A. (2003) Geochemistry and origin of the intrusive hosts of the Noril’sk-Talnakh Cu-Ni-PGE sulfide deposits. Econ. Geol., 98, 495-515.Гриненко Л.Н. (1990) Источники вещества и условия формирования сульфидных медно-никелевых руд по изотопно-геохимическим данным. Геология медноникелевых месторождений СССР. Л.: Наука, 57-66.Asael D., Matthews A., Bar-Matthews M., Halicz L. (2007) Copper isotope fractionation in sedimentary copper mineralization (Timna Valley, Israel). Chem. Geol., 243, 238-254.Дистлер В.В., Гроховская Т.Л., Евстигнеева Т.Л., Служеникин С.Ф., Филимонова А.А., Дюжиков О.А., Лапутина И.П. (1988) Петрология сульфидного магматического рудообразования. М.: Наука, 232 с.Asael D., Matthews A., Bar-Matthews M., Harlavan Y., Segal I. (2012) Tracking redox controls and sources of sedimentary mineralization using copper and lead isotopes. Chem. Geol., 310-311, 23-35.Добрецов Н.Л. (1997) Пермо-триасовый магматизм и осадконакопление в Евразии как отражение суперплюма. Докл. РАН, 354(2), 220-223.Asael D., Matthews A., Butler I., Rickard A.D., Bar-Matthews M., Halicz L. (2006) 65Cu/63Cu fractionation during copper sulphide formation from iron sulphides in aqueous solution. Geochim. Cosmochim. Acta, 70(18S), A23.Добрецов Н.Л., Борисенко А.С., Изох А.Э., Жмодик С.М. (2010) Термохимическая модель пермотриасовых мантийных плюмов Евразии как основа для выявления закономерностей формирования и прогноза медно-никелевых, благородно- и редкометалльных месторождений. Геология и геофизика, 51(9), 1159-1187.Asael D., Matthews A., Oszczepalski S., Bar-Matthews M., Halicz L. (2009) Fluid speciation controls of low temperature copper isotope fractionation applied to the Kupferschiefer and Timna ore deposits. Chem. Geol., 262, 147-158.Додин Д.А. (2002) Металлогения Таймыро-Норильского района. СПб.: Наука, 822 с.Barnes S.J., Malitch K.N., Yudovskaya M.A. (2020) Introduction to a Special Issue on the Norilsk-Talnakh Ni-Cuplatinum group element deposits. Econ. Geol., 115(6), 1157-1172.Дюжиков О.А., Дистлер В.В., Струнин Б.М., Мкртычян А.К., Шерман М.Л., Служеникин С.Ф., Лурье А.М. (1988) Геология и рудоносность Норильского района. М.: Наука, 279 с.Ben Othman D., Luck J.M., Bodinier J.L., Arndt N.T., Albarède F. (2006) Cu-Zn isotopic variations in the Earth’s mantle. Geochim. Cosmochim. Acta, 70(18S), A46.Зенько Т.Е. (1983) Механизм формирования норильских расслоенных рудоносных интрузивов. Изв. АН СССР. Сер. геол., (11), 21-39.Bogatikov O.A., Kovalenko V.I., Sharkov E.V. (2010) Magmatism, tectonics, geodynamics of the Earth: connections in time and space. Mosсow, Nauka Publ., 605 p. (In Russ.)Золотухин В.В., Рябов В.В., Васильев Ю.Р., Шатков В.А. (1975) Петрология Талнахской рудоносной дифференцированной трапповой интрузии. Новосибирск: Наука, 432 с.Chen H., Savage P., Teng F.Z., Helz R.T., Moynier F. (2013) Zinc isotope fractionation during magmatic differentiation and the isotopic composition of the bulk Earth. Earth Planet. Sci. Lett., 369-370, 34-42.Зотов И.А. (1979) Генезис трапповых интрузивов и метаморфических образований Талнаха. М.: Наука, 155 с.Czamanske G.K., Zen’ko T.E., Fedorenko V.A., Calk L.C., Budahn J.R., Bullock J.H. Jr., Fries T.L., King B.S., Siems D.F. (1995) Petrography and geochemical characterization of ore-bearing intrusions of the Noril’sk type, Siberia; with discussion of their origin. Res. Geol., Spec. Iss., 18, 1-48.Лихачев А.П. (2006) Платино-медно-никелевые и платиновые месторождения. М.: Эслан, 496 с.Distler V.V., Grokhovskaya T.L., Evstigneeva T.L., Sluzhenikin S.F., Filimonova A.A., Dyuzhikov O.A., Laputina I.P. (1988) Petrology of magmatic sulphide ore formation. Moscow, Nauka Publ., 232 p. (In Russ.)Лихачев А.П. (2020) Опоискованность Норильского района и возможности открытия в нем новых Pt-Cu-Ni месторождений. Отеч. геология, (2), 3-16.Dobretsov N.L. (1997) Permo-Triassic magmatism and sedimentation in Eurasia as expression of a mantle superplume. Dokl. Earth Sci., 354(4), 497-500 (translated from Doklady RAN, 354(2), 220-223).Люлько В.А., Федоренко В.А., Дистлер В.В., Служеникин С.Ф., Кунилов В.Е., Стехин А.И., Рябикин В.А., Симонов О.Н., Зенько Т.Е. (1994) Геология и рудные месторождения Норильского района. Путеводитель VII Международного платинового симпозиума. (Ред. В.В. Дистлер, В.Е. Кунилов). М.: Московский контакт, 43 с.Dobretsov N.L., Borisenko A.S., Izokh A.E., Zhmodik S.M. (2010) Thermochemical model of Permo-Triassic mantle plumes of Eurasia as a basis for identifying patterns of formation and forecasting copper-nickel, noble and rare metal deposits. Geol. Geophys., 51(9), 1159-1187. (In Russ.)Ляхницкая И.В., Туганова Е.В. (1977) Региональные и локальные закономерности размещения медноникелевых сульфидных месторождений. Л.: Недра, 77 с.Dodin D.A. (2002) Metallogeny of the Taimyr-Noril’sk region. St.Petersburg, Nauka Publ., 822 p. (In Russ.)Малич К.Н., Баданина И.Ю., Туганова Е.В. (2010) Магматическая эволюция ультрамафит-мафитовых интрузивов Норильской провинции (Россия): вещественные и геохронологические данные. Литосфера, (5), 37-63.Dyuzhikov O.A., Distler V.V., Strunin B.M., Mkrtychyan A.K., Sherman M.L., Sluzhenikin S.F., Lur’e A.M. (1988) Geology and ore content of the Noril’sk region. Moscow, Nauka Publ., 279 p. (In Russ.)Малич К.Н., Баданина И.Ю., Туганова Е.В. (2018) Рудоносные ультрамафит-мафитовые интрузивы Полярной Сибири: возраст, условия образования, критерии прогноза. Екатеринбург: ИГГ УрО РАН, 287 с.Exploration criteria for Noril’sk-type sulphide ores. (1978) (Ed. V.S. Sobolev). Novosibirsk, Nauka Publ., 167 p. (In Russ.)Металлогеническая карта северо-запада Сибирской платформы. М-б 1 : 500 000. (1987) (Гл. ред. Н.С. Малич). Карта на 16 л. Объяснит. записка. Л.: Картограф. фабрика ВСЕГЕИ, 149 с.Gagnevin D., Boyee A.J., Barrie C.D., Menuge J.F., Blakeman R.J. (2012) Zn, Fe and S isotope fractionation in a large hydrothermal system. Geochim. Cosmochim. Acta, 88, 183-198.Поисковые критерии сульфидных руд норильского типа. (1978) (Ред. В.С. Соболев). Новосибирск: Наука, 167 с.Genkin A.D., Distler V.V., Gladyshev G.D., Filimonova A.A., Evstigneeva T.L., Kovalenker V.A., Laputina I.P., Smirnov A.V., Grokhovskaya T.L. (1981) Sulphide copper-nickel ores of the Noril’sk deposits. Mos-cow, Nauka Publ., 234 p. (In Russ.)Пушкарев Ю.Д. (1997) Два типа взаимодействия корового и мантийного вещества и новый подход к проблемам глубинного рудообразования. Докл. АН, 335(4), 524-526.Godlevskii M.N. (1959) Traps and ore-bearing intrusions of the Noril’sk region. Moscow, Gostekhmetizdat Publ., 68 p. (In Russ.)Радько В.А. (1991) Модель динамической дифференциации интрузивных траппов северо-запада Сибирской платформы. Геология и геофизика, 32(11), 19-27.Graham S., Pearson N., Jackson S., Griffin W., O’Reilly S.Y. (2004) Tracing Cu and Fe from source to porphyry: in situ determination of Cu and Fe isotope ratios in sulfides from the Grasberg Cu-Au deposit. Chem. Geol., 207, 147-169.Радько В.А. (2016) Фации интрузивного и эффузивного магматизма Норильского района. СПб.: Картограф. фабрика ВСЕГЕИ, 226 с.Grinenko L.N. (1985) Sources of sulfur of the nickeliferous and barren gabbro-dolerite intrusions of the northwest Siberian platform. Int. Geol. Rev., 28, 695-708.Ржевский В.Ф., Габлина И.Ф., Василовская Л.В., Лурье А.М. (1988) Генетические особенности Гравийского месторождения меди. Литология и полез. ископаемые, (2), 86-97.Grinenko L.N. (1990) Substanse sources and conditions of formation of sulphide copper-nickel ores deduced from isotope-geochemical data. Geology of copper-nickel deposits of the USSR. Leningrad, Nauka Publ., 57-66. (In Russ.)Ржевский В.Ф., Мирошников А.Е., Душаткин А.Б., Шклярик Г.К. (1980) Меденосность верхнедокембрийских отложений Игарского района. Процессы осадочного и вулканогенно-осадочного накопления цветных металлов (Сибирь и Дальний Восток). (Ред. Ю.П. Казанский, Л.Ф. Наркелюн). Новосибирск: Наука, 81-84.Isotope Geology of the Norilsk deposits. (2019) (Ed. O. Petrov). Cham, Springer Nature, 306 p.Рябов В.В., Шевко А.Я., Гора М.П. (2000) Магматические образования Норильского района. Т. 1. Петрология траппов. Новосибирск: Нонапрель, 408 с.John S.G., Rouxel O.J., Craddock P.R., Engwall A.M., Boyle E.A. (2008) Zinc stable isotopes in seafloor hydrothermal vent fluids and chimneys. Earth Planet. Sci. Lett., 269, 17-28.Служеникин С.Ф. (2000) Малосульфидное платиновое оруденение в дифференцированных базит-гипербазитовых интрузивах Норильского района. Автореф. дисс. … канд. геол.-мин. наук. М.: ИГЕМ РАН, 26 с.Kelley K.D., Wilkinson J.J., Chapman J.B., Crowther H.L., Weiss D.J. (2009) Zinc isotopes in sphalerite from base metal deposits in the Red Dog district, northern Alaska. Econ. Geol., 104, 767-773.Служеникин С.Ф., Дистлер В.В., Дюжиков О.А., Кравцов В.Ф., Кунилов В.Е., Лапутина И.П., Туровцев Д.М. (1994) Малосульфидное платиновое оруденение в норильских дифференцированных интрузивах. Геология рудн. месторождений, 36(3), 195-217.Krivolutskaya N.A. (2016) Siberian traps and Pt-Cu-Ni deposits in the Noril’sk Area. Cham, Springer International Publishing Switzerland, 364 p.Служеникин С.Ф., Малич К.Н., Туровцев Д.М., Григорьева А.В., Баданина И.Ю. (2020) Зубовский тип дифференцированных базит-гипербазитовых интрузивов Норильского района: петрогеохимические характеристики и рудоносность. Петрология, 28(5), 511-544.Larson P.B., Maher K., Ramos F.C., Chang Z.S., Gaspar M., Meinert L.D. (2003) Copper isotope ratios in magmatic and hydrothermal ore-forming environments. Chem. Geol., 201(3-4), 337-350.Служеникин С.Ф., Малич К.Н., Юдовская М.А., Туровцев Д.М., Анциферова Т.Н., Михалев С.К., Баданина И.Ю., Солошенко Н.Г. (2023) Нижнеталнахский тип интрузивов в Норильском рудном районе. Петрология, 31(5), 482-509.Li C., Ripley E.M., Naldrett A.J. (2003) Compositional variations of olivine and sulfur isotopes in the Noril’sk and Talnakh intrusions, Siberia: implications for ore-forming processes in dynamic magma conduits. Econ. Geol., 98, 69-86.Спиридонов Э.М. (2010) Рудно-магматические системы Норильского рудного поля. Геология и геофизика, 51(9), 1356-1378.Li W.-Q., Jackson S.E., Pearson N.J., Alard O., Chappell B.W. (2009) The Cu isotopic signature of granites from the Lachlan Fold Belt, SE Australia. Chem. Geol., 258, 38-49.Туганова Е.В. (1991) Петролого-геодинамическая модель образования сульфидных Си-Ni месторождений. Геология и геофизика, 32(6), 3-11.Likhachev A.P. (2006) Ni-Cu-PGE and PGE deposits. Mos-cow, Eslan Publ., 496 p. (In Russ.)Туганова Е.В. (2000) Формационные типы, генезис и закономерности размещения сульфидных платиноидно-медно-никелевых месторождений. СПб.: ВСЕГЕИ, 102 с.Likhachev A.P. (2020) Search coverage of the Noril’sk region and the possibility of discovering new Pt-Cu-Ni deposits. Otechestvennaya Geologiya, (2), 3-16. (In Russ.)Albarède F. (2004) The stable isotope geochemistry of copper and zinc. Rev. Mineral. Geochem., 55, 409-427.Liu S.-A., Huang J., Liu J., Wörner G., Yang W., Tang Y.-J., Chen Y., Tang L., Zheng J., Li S. (2015) Copper isotopic composition of the silicate Earth. Earth Planet. Sci. Lett., 427, 95-103.Albarede F. (2009) Volatile accretion history of the terrestrial planets and dynamic implications. Nature, 461, 1227-1233.Luck J.-M., Ben Othman D., Albarède F. (2005) Zn and Cu isotopic variations in chondrites and iron meteorites: early solar nebula reservoirs and parent-body processes. Geochim. Cosmochim. Acta, 69, 5351-5363.Arndt N.T., Czamanske G.K., Walker R.J., Chauvel C., Fedorenko V.A. (2003) Geochemistry and origin of the intrusive hosts of the Noril’sk-Talnakh Cu-Ni-PGE sulfide deposits. Econ. Geol., 98, 495-515.Luck J.-M., Ben Othman D., Barrat J.A., Albarède F. (2003) Coupled 63Cu and 16O excesses in chondrites. Geochim. Cosmochim. Acta, 67, 143-151.Asael D., Matthews A., Bar-Matthews M., Halicz L. (2007) Copper isotope fractionation in sedimentary copper mineralization (Timna Valley, Israel). Chem. Geol., 243, 238-254.Lyakhnitskaya I.V., Tuganova E.V. (1977) Regional and local regularities of distribution of Cu-Ni sulphide deposits. Leningrad, Nedra Publ., 77 p. (In Russ.)Asael D., Matthews A., Bar-Matthews M., Harlavan Y., Segal I. (2012) Tracking redox controls and sources of sedimentary mineralization using copper and lead isotopes. Chem. Geol., 310-311, 23-35.Lyul’ko V.A., Fedorenko V.A., Distler V.V., Sluzhenikin S.F., Kunilov V.E., Stekhin A.I., Ryabikin V.A., Simonov O.N., Zen’ko T.E. (1994) Geology and ore deposits of the Noril’sk region: Guidebook of the VII International Platinum Symposium. Moscow–Noril’sk. Mos-cow, Moskovskii Kontakt Publ., 43 p. (In Russ.)Asael D., Matthews A., Butler I., Rickard A.D., Bar-Matthews M., Halicz L. (2006) 65Cu/63Cu fractionation during copper sulphide formation from iron sulphides in aqueous solution. Geochim. Cosmochim. Acta, 70(18S), A23.Maher K.C., Larson P.B. (2007) Variation in copper isotope ratios and controls on fractionation in hypogene skarn mineralization at Coroccohuayco and Tintaya, Peru. Econ. Geol., 102, 225-237.Asael D., Matthews A., Oszczepalski S., Bar-Matthews M., Halicz L. (2009) Fluid speciation controls of low temperature copper isotope fractionation applied to the Kupferschiefer and Timna ore deposits. Chem. Geol., 262, 147-158.Malitch K.N. (2021) Forecasting criteria for sulphide PGE-copper-nickel deposits of the Noril’sk province. Lithosphere (Russia), 21(5), 660-682.Barnes S.J., Malitch K.N., Yudovskaya M.A. (2020) Introduction to a Special Issue on the Norilsk-Talnakh Ni-Cuplatinum group element deposits. Econ. Geol., 115(6), 1157-1172.Malitch K.N., Badanina I.Yu., Tuganova E.V. (2010) Magmatic evolution of ultramafic-mafic intrusions of the Noril’sk province (Russia): compositional and geochronological data. Lithosphere (Russia), (5), 37-63. (In Russ.)Ben Othman D., Luck J.M., Bodinier J.L., Arndt N.T., Albarède F. (2006) Cu-Zn isotopic variations in the Earth’s mantle. Geochim. Cosmochim. Acta, 70(18S), A46.Malitch K.N., Badanina I.Yu., Tuganova E.V. (2018) Ore-bearing ultramafic-mafic intrusions of Polar Siberia: age, origin and prediction criteria. Ekaterinburg, IGG UB RAS, 287 p. (In Russ.)Chen H., Savage P., Teng F.Z., Helz R.T., Moynier F. (2013) Zinc isotope fractionation during magmatic differentiation and the isotopic composition of the bulk Earth. Earth Planet. Sci. Lett., 369-370, 34-42.Malitch K.N., Belousova E.A., Griffin W.L., Badanina I.Yu. (2013) Hafnium-neodymium constraints on source heterogeneity of the economic ultramafic-mafic Noril’sk-1 intrusion (Russia). Lithos, 164-167, 36-46.Czamanske G.K., Zen’ko T.E., Fedorenko V.A., Calk L.C., Budahn J.R., Bullock J.H. Jr., Fries T.L., King B.S., Siems D.F. (1995) Petrography and geochemical characterization of ore-bearing intrusions of the Noril’sk type, Siberia; with discussion of their origin. Res. Geol., Spec. Iss., 18, 1-48.Malitch K.N., Belousova E.A., Griffin W.L., Badanina I.Yu., Latypov R.M., Sluzhenikin S.F. (2018) New insights on the origin of ultramafic-mafic intrusions and associated Ni-Cu-PGE sulphide deposits of the Noril’sk and Taimyr provinces, Russia: Evidence from radiogenic- and stable-isotope data. Processes and ore deposits of ultramaficmafic magmas through space and time. (Eds S. Mondal, W.L. Griffin). 1st ed. Amsterdam, Elsevier, 197-238.Gagnevin D., Boyee A.J., Barrie C.D., Menuge J.F., Blakeman R.J. (2012) Zn, Fe and S isotope fractionation in a large hydrothermal system. Geochim. Cosmochim. Acta, 88, 183-198.Malitch K.N., Belousova E.A., Griffin W.L., Badanina I.Yu., Pearson N.J., Presnyakov S.L., Tuganova E.V. (2010) Magmatic evolution of the ultramafic-mafic Kharaelakh intrusion (Siberian craton, Russia): Insights from trace-element, U-Pb and Hf-isotope data on zircon. Contrib. Mineral. Petrol., 159, 753-768.Graham S., Pearson N., Jackson S., Griffin W., O’Reilly S.Y. (2004) Tracing Cu and Fe from source to porphyry: in situ determination of Cu and Fe isotope ratios in sulfides from the Grasberg Cu-Au deposit. Chem. Geol., 207, 147-169.Malitch K.N., Latypov R.M. (2011) Re-Os and S-isotope constraints on age and source heterogeneity of Ni-Cu-PGE sulfide ores: a case study at the Talnakh ore junction (Russia). Canad. Miner., 49(6), 1653-1677.Grinenko L.N. (1985) Sources of sulfur of the nickeliferous and barren gabbro-dolerite intrusions of the northwest Siberian platform. Int. Geol. Rev., 28, 695-708.Malitch K.N., Latypov R.M., Badanina I.Yu., Sluzhenikin S.F. (2014) Insights into ore genesis of Ni-Cu-PGE sulfide deposits of the Noril’sk province (Russia): Evidence from copper and sulfur isotopes. Lithos, 204, 172-187.Isotope Geology of the Norilsk deposits. (2019) (Ed. O. Petrov). Cham, Springer Nature, 306 p.Maréchal C., Albarède F. (2002) Ion-exchange fractionation of copper and zinc isotopes. Geochim. Cosmochim. Acta, 66, 1499-1509.John S.G., Rouxel O.J., Craddock P.R., Engwall A.M., Boyle E.A. (2008) Zinc stable isotopes in seafloor hydrothermal vent fluids and chimneys. Earth Planet. Sci. Lett., 269, 17-28.Maréchal C.N., Télouk P., Albarède F. (1999) Precise analysis of copper and zinc isotopic compositions by plasma-source mass spectrometry. Chem. Geol., 156, 251-273.Kelley K.D., Wilkinson J.J., Chapman J.B., Crowther H.L., Weiss D.J. (2009) Zinc isotopes in sphalerite from base metal deposits in the Red Dog district, northern Alaska. Econ. Geol., 104, 767-773.Markl G., Lahaye Y., Schwinn G. (2006) Copper isotopes asmonitors of redox processes in hydrothermal mineralization. Geochim. Cosmochim. Acta, 70, 4215-4228.Krivolutskaya N.A. (2016) Siberian traps and Pt-Cu-Ni deposits in the Noril’sk Area. Cham, Springer International Publishing Switzerland, 364 p.Mason T.F.D., Weiss D.J., Chapman J.B., Wilkinson A.J., Tessalina V.G., Spiro A., Horstwood A.S.A., Spratt O., Coles A.J. (2005) Zn and Cu isotopic variability in the Alexandrinka volcanic-hosted massive sulphide (VHMS) ore deposit, Urals, Russia. Chem. Geol., 221, 170-187.Larson P.B., Maher K., Ramos F.C., Chang Z.S., Gaspar M., Meinert L.D. (2003) Copper isotope ratios in magmatic and hydrothermal ore-forming environments. Chem. Geol., 201(3-4), 337-350.Mathur R., Ruiz J., Casselman M.J., Megaw P., van Egmond R. (2012) Use of Cu isotopes to distinguish primary and secondary Cu mineralization in the Canariaco Norte porphyry copper deposit, Northern Peru. Mineral. Depos., 47, 755-762.Li C., Ripley E.M., Naldrett A.J. (2003) Compositional variations of olivine and sulfur isotopes in the Noril’sk and Talnakh intrusions, Siberia: implications for ore-forming processes in dynamic magma conduits. Econ. Geol., 98, 69-86.Mathur R., Ruiz J., Titley S., Liermann L., Buss H., Brantley S. (2005) Cu isotopic fractionation in the supergene environment with and without bacteria. Geochim. Cosmochim. Acta, 69(22), 5233-5246.Li W.-Q., Jackson S.E., Pearson N.J., Alard O., Chappell B.W. (2009) The Cu isotopic signature of granites from the Lachlan Fold Belt, SE Australia. Chem. Geol., 258, 38-49.Mathur R., Titley S., Barra F., Brantley S., Wilson M., Phillips A., Munizaga F., Maksaev V., Vervoort J., Hart G. (2009) Exploration potential of Cu isotope fractionation in porphyry copper deposits. J. Geochem. Explor., 102, 1-6.Liu S.-A., Huang J., Liu J., Wörner G., Yang W., Tang Y.-J., Chen Y., Tang L., Zheng J., Li S. (2015) Copper isotopic composition of the silicate Earth. Earth Planet. Sci. Lett., 427, 95-103.Metallogenic map of the north-western Siberian Platform. Scale 1 : 500 000. (1987) (Ed. N.S. Malitch). 16 sheets. Explanatory note. Leningrad, Cartographic Factory VSEGEI Publ., 149 p. (In Russ.)Luck J.-M., Ben Othman D., Albarède F. (2005) Zn and Cu isotopic variations in chondrites and iron meteorites: early solar nebula reservoirs and parent-body processes. Geochim. Cosmochim. Acta, 69, 5351-5363.Naldrett A.J. (2004) Magmatic sulfide deposits: Geology, geochemistry and exploration. Heidelberg, Berlin, Springer Verlag, 728 p.Luck J.-M., Ben Othman D., Barrat J.A., Albarède F. (2003) Coupled 63Cu and 16O excesses in chondrites. Geochim. Cosmochim. Acta, 67, 143-151.Naldrett A.J., Fedorenko V.A., Lightfoot P.C., Kunilov V.I., Gorbachev N.S., Doherty W., Johan Z. (1995) Ni-Cu-PGE deposits of Noril’sk region, Siberia: Their formation in conduits for flood basalt volcanism. Trans. Inst. Min. Metall., 104, B18-B36.Maher K.C., Larson P.B. (2007) Variation in copper isotope ratios and controls on fractionation in hypogene skarn mineralization at Coroccohuayco and Tintaya, Peru. Econ. Geol., 102, 225-237.Okuneva T.G., Karpova S.V., Streletskaya M.V., Soloshenko N.G., Kiseleva D.V. (2022) The method for Cu and Zn isotope ratio determination by MC-ICP-MS using the AG-MP-1 resin. Geodynam. Tectonophys., 13(2s), 0615. https://doi.org/10.5800/GT-2022-13-2s-0615Malitch K.N. (2021) Forecasting criteria for sulphide PGE-copper-nickel deposits of the Noril’sk province. Lithosphere (Russia), 21(5), 660-682.Pirajno F. (2007) Mantle plumes, associated intraplate tectono-magmatic processes and ore systems. Episodes, 30(1), 6-19.Malitch K.N., Belousova E.A., Griffin W.L., Badanina I.Yu. (2013) Hafnium-neodymium constraints on source heterogeneity of the economic ultramafic-mafic Noril’sk-1 intrusion (Russia). Lithos, 164-167, 36-46.Pushkarev Yu.D. (1999) The nature of super large ore deposits: a concept of crust-mantle interaction within the mantle. Mineral Deposits: Processes to Processing. Balkema, Rotterdam, 1291-1294.Malitch K.N., Belousova E.A., Griffin W.L., Badanina I.Yu., Latypov R.M., Sluzhenikin S.F. (2018) New insights on the origin of ultramafic-mafic intrusions and associated Ni-Cu-PGE sulphide deposits of the Noril’sk and Taimyr provinces, Russia: Evidence from radiogenic- and stable-isotope data. Processes and ore deposits of ultramaficmafic magmas through space and time. (Eds S. Mondal, W.L. Griffin). 1st ed. Amsterdam, Elsevier, 197-238.Pushkarev Yu.D. (1997) Two types of interaction of crustal and mantle materials and new approach to problems of deep-seated ore formation. Dokl. RAN, 355(4), 524-526. (In Russ.)Malitch K.N., Belousova E.A., Griffin W.L., Badanina I.Yu., Pearson N.J., Presnyakov S.L., Tuganova E.V. (2010) Magmatic evolution of the ultramafic-mafic Kharaelakh intrusion (Siberian craton, Russia): Insights from trace-element, U-Pb and Hf-isotope data on zircon. Contrib. Mineral. Petrol., 159, 753-768.Rad’ko V.A. (2016) Facies of intrusive and effusive magmatism of the Noril’sk region. St.Petersburg, St.Petersburg Cartographic Factory VSEGEI Publ., 226 p. (In Russ.)Malitch K.N., Latypov R.M. (2011) Re-Os and S-isotope constraints on age and source heterogeneity of Ni-Cu-PGE sulfide ores: a case study at the Talnakh ore junction (Russia). Canad. Miner., 49(6), 1653-1677.Rad’ko V.A. (1991) Model of dynamic differentiation of intrusive traps in the northwestern Siberian platform. Sov. Geol. Geophys., 32, 15-20. (In Russ.)Malitch K.N., Latypov R.M., Badanina I.Yu., Sluzhenikin S.F. (2014) Insights into ore genesis of Ni-Cu-PGE sulfide deposits of the Noril’sk province (Russia): Evidence from copper and sulfur isotopes. Lithos, 204, 172-187.Ripley E.M., Dong S., Li C., Wasylenki L.E. (2015) Cu isotope variations between conduit and sheet-style Ni-Cu-PGE sulfide mineralization in the Midcontinent Rift System, North America. Chem. Geol., 414, 59-68.Maréchal C., Albarède F. (2002) Ion-exchange fractionation of copper and zinc isotopes. Geochim. Cosmochim. Acta, 66, 1499-1509.Ripley E.M., Li C. (2013) Sulfide saturation in mafic magmas: is external sulfur required for magmatic Ni-Cu-(PGE) ore genesis? Econ. Geol., 108, 45-58.Maréchal C.N., Télouk P., Albarède F. (1999) Precise analysis of copper and zinc isotopic compositions by plasma-source mass spectrometry. Chem. Geol., 156, 251-273.Ripley E.M., Li C. (2003) Sulfur isotope exchange and metal enrichment in the formation of magmatic Cu-Ni-(PGE) deposits. Econ. Geol., 98, 635-641.Markl G., Lahaye Y., Schwinn G. (2006) Copper isotopes asmonitors of redox processes in hydrothermal mineralization. Geochim. Cosmochim. Acta, 70, 4215-4228.Ripley E.M., Li C., Moore C.H., Schmitt A.K. (2010) Micro-scale S isotope studies of the Kharaelakh intrusion, Noril’sk region, Siberia: Constraints on the genesis of coexisting anhydrite and sulfide minerals. Geochim. Cosmochim. Acta, 74, 634-644.Mason T.F.D., Weiss D.J., Chapman J.B., Wilkinson A.J., Tessalina V.G., Spiro A., Horstwood A.S.A., Spratt O., Coles A.J. (2005) Zn and Cu isotopic variability in the Alexandrinka volcanic-hosted massive sulphide (VHMS) ore deposit, Urals, Russia. Chem. Geol., 221, 170-187.Ripley E.M., Lightfoot P.C., Li C., Elswick E.R. (2003) Sulfur isotopic studies of continental flood basalts in the Noril’sk region: Implications for the association between lavas and ore-bearing intrusions. Geochim. Cosmochim. Acta, 67, 2805-2817.Mathur R., Ruiz J., Casselman M.J., Megaw P., van Egmond R. (2012) Use of Cu isotopes to distinguish primary and secondary Cu mineralization in the Canariaco Norte porphyry copper deposit, Northern Peru. Mineral. Depos., 47, 755-762.Rosman K.J.R. (1972) A survey of the isotopic and elemental abundance of zinc. Geochim. Cosmochim. Acta, 36(7), 801-819.Mathur R., Ruiz J., Titley S., Liermann L., Buss H., Brantley S. (2005) Cu isotopic fractionation in the supergene environment with and without bacteria. Geochim. Cosmochim. Acta, 69(22), 5233-5246.Rouxel O., Fouquet Y., Ludden J.N. (2004) Copper isotope systematics of the Lucky Strike, Rainbow, and Logatchev seafloor hydrothermal fields on the Mid-Atlantic Ridge. Econ. Geol., 99, 585-600.Mathur R., Titley S., Barra F., Brantley S., Wilson M., Phillips A., Munizaga F., Maksaev V., Vervoort J., Hart G. (2009) Exploration potential of Cu isotope fractionation in porphyry copper deposits. J. Geochem. Explor., 102, 1-6.Ryabov V.V., Shevko A.Yu., Gora M.P. (2000) Igneous formations of the Norilsk region. V. 1. Petrology of traps. Novosibirsk, Nonaprel’ Publ., 408 p. (In Russ.)Naldrett A.J. (2004) Magmatic sulfide deposits: Geology, geochemistry and exploration. Heidelberg, Berlin: Springer Verlag, 728 p.Rzhevskii V.F., Gablina I.F., Vasilovskaya L.V., Lur’e A.M. (1988) Genetic features of the Gravel copper deposit. Litol. Polez. Iskop., (2), 86-97. (In Russ.)Naldrett A.J., Fedorenko V.A., Lightfoot P.C., Kunilov V.I., Gorbachev N.S., Doherty W., Johan Z. (1995) Ni-Cu-PGE deposits of Noril’sk region, Siberia: Their formation in conduits for flood basalt volcanism. Trans. Inst. Min. Metall., 104, B18-B36.Rzhevsky V.F., Miroshnikov A.E., Dushatkin A.B., Shklyarik G.K. (1980) Copper mineralization in the Upper Precambrian of the Igarka Area. Processes governing the accumulation of sedimentary and volcanogenic-sedimentary deposits of nonferrous metals (Siberia and the Far East). Novosibirsk, Nauka Publ., 81-84. (In Russ.)Okuneva T.G., Karpova S.V., Streletskaya M.V., Soloshenko N.G., Kiseleva D.V. (2022) The method for Cu and Zn isotope ratio determination by MC-ICP-MS using the AG-MP-1 resin. Geodynam. Tectonophys., 13(2s), 0615. https://doi.org/10.5800/GT-2022-13-2s-0615Shields W.R., Goldich S.S., Garner E.L., Murphy T.J. (1965) Natural variations in the abundance ratio and the atomic weight of copper. J. Geophys. Res., 70, 479-491.Pirajno F. (2007) Mantle plumes, associated intraplate tectono-magmatic processes and ore systems. Episodes, 30(1), 6-19.Sluzhenikin S.F. (2000) Low-sulfide platinum mineralization in differentiated basic-ultrabasic intrusions of the Noril’sk region. Author’s abstract diss. ... cand. geol.-min. sciences. Moscow, IGEM RAN, 26 p. (In Russ.)Pushkarev Yu.D. (1999) The nature of super large ore deposits: a concept of crust-mantle interaction within the mantle. Mineral Deposits: Processes to Processing. Balkema, Rotterdam, 1291-1294.Sluzhenikin S.F., Distler V.V., Dyuzhikov O.A., Kravtsov V.F., Kunilov V.E., Laputina I.P., Turovtsev D.M. (1994) Low-sulphide platinum mineralization of the Noril’sk differentiated intrusions. Geol. Rud. Mestorozhd., 36(3), 195-217. (In Russ.)Ripley E.M., Dong S., Li C., Wasylenki L.E. (2015) Cu isotope variations between conduit and sheet-style Ni-Cu-PGE sulfide mineralization in the Midcontinent Rift System, North America. Chem. Geol., 414, 59-68.Sluzhenikin S.F., Krivolutskaya N.A., Rad’ko V.A., Malitch K.N., Distler V.V., Fedorenko V.A. (2014) Ultramafic-mafic intrusions, volcanic rocks and PGE-Cu-Ni sulfide deposits of the Noril’sk province, Polar Siberia. Field trip guidebook. 12th International Platinum Symposium. Ekaterinburg, IGG UB RAS, 80 p.Ripley E.M., Li C. (2013) Sulfide saturation in mafic magmas: is external sulfur required for magmatic Ni-Cu-(PGE) ore genesis? Econ. Geol., 108, 45-58.Sluzhenikin S.F., Malitch K.N., Turovtsev D.M., Grigor’eva A.V., Badanina I.Yu. (2020) Differentiated mafic-ultramafic intrusions of the Zubovsky type in the Noril’sk area: petrochemistry, geochemistry, and ore potential. Petrology, 28(5), 458-489 (translated from Petrologiya, 28(5), 511-544).Ripley E.M., Li C. (2003) Sulfur isotope exchange and metal enrichment in the formation of magmatic Cu-Ni-(PGE) deposits. Econ. Geol., 98, 635-641.Sluzhenikin S.F., Malitch K.N., Yudovskaya M.A., Turovtsev D.M., Antsiferova T.N., Mikhalev S.K., Badanina I.Yu., Soloshenko N.G. (2023) Low Talnakh type intrusions of the Noril’sk ore region. Petrology, 31(5), 492-518. https://doi.org/10.1134/S0869591123050065 (translated from Petrologiya, 31(5), 482-509).Ripley E.M., Li C., Moore C.H., Schmitt A.K. (2010) Micro-scale S isotope studies of the Kharaelakh intrusion, Noril’sk region, Siberia: Constraints on the genesis of coexisting anhydrite and sulfide minerals. Geochim. Cosmochim. Acta, 74, 634-644.Spiridonov E.M. (2010) Ore-magmatic systems of the Noril’sk ore field. Geol. Geofiz., 51(9), 1356-1378. (In Russ.)Ripley E.M., Lightfoot P.C., Li C., Elswick E.R. (2003) Sulfur isotopic studies of continental flood basalts in the Noril’sk region: Implications for the association between lavas and ore-bearing intrusions. Geochim. Cosmochim. Acta, 67, 2805-2817.Tang D., Qin K., Su B., Mao Y., Evans N.J., Niu Y., Kang Z. (2020) Sulfur and copper isotopic signatures of chalcopyrite at Kalatongke and Baishiquan: Insights into the origin of magmatic Ni-Cu sulfide deposits. Geochim. Cosmochim. Acta, 275, 209-228.Rosman K.J.R. (1972) A survey of the isotopic and elemental abundance of zinc. Geochim. Cosmochim. Acta, 36(7), 801-819.Tuganova E.V. (1991) Petrological geodynamical model of formation of sulfide copper-nickel deposits. Geol. Geophys., 32, 1-7 (translated from Geol. Geofiz., 32(6), 3-11).Rouxel O., Fouquet Y., Ludden J.N. (2004) Copper isotope systematics of the Lucky Strike, Rainbow, and Logatchev seafloor hydrothermal fields on the Mid-Atlantic Ridge. Econ. Geol., 99, 585-600.Tuganova E.V. (2000) Petrographic types, genesis and distribution patterns of sulphide Ni-Cu-PGE deposits. St.Petersburg, VSEGEI Publ., 102 p. (In Russ.)Shields W.R., Goldich S.S., Garner E.L., Murphy T.J. (1965) Natural variations in the abundance ratio and the atomic weight of copper. J. Geophys. Res., 70, 479-491.Walker R.J., Morgan J.W., Horan M.F., Czamanske G.K., Krogstad E.J., Fedorenko V.A., Kunilov V.E. (1994) Re-Os isotopic evidence for an enriched-mantle source for the Noril’sk-type, ore-bearing intrusion, Siberia. Geochim. Cosmochim. Acta, 58, 4179-4197.Sluzhenikin S.F., Krivolutskaya N.A., Rad’ko V.A., Malitch K.N., Distler V.V., Fedorenko V.A. (2014) Ultramafic-mafic intrusions, volcanic rocks and PGE-Cu-Ni sulfide deposits of the Noril’sk province, Polar Siberia. Field trip guidebook. 12th International Platinum Symposium. Ekaterinburg, Russia: Institute of Geology and Geochemistry, Ural Branch of the Russian Academy of Sciences (IGG UB RAS), 80 p.Wang D., Sun X., Zheng Y., Wu S., Xia S., Chang H., Yu M. (2017) Two pulses of mineralization and genesis of the Zhaxikang Sb–Pb–Zn–Ag deposit in southern Tibet: constraints from Fe–Zn isotopes. Ore Geol. Rev., 84, 347-363.Tang D., Qin K., Su B., Mao Y., Evans N.J., Niu Y., Kang Z. (2020) Sulfur and copper isotopic signatures of chalcopyrite at Kalatongke and Baishiquan: Insights into the origin of magmatic Ni-Cu sulfide deposits. Geochim. Cosmochim. Acta, 275, 209-228.Wilkinson J.J. (2023) The potential of Zn isotopes in the science and exploration of ore deposits. (Eds D. Huston, J. Gutzmer). Isotopes in Economic Geology, Metallogenesis and Exploration. Cham, Springer, 451-463.Walker R.J., Morgan J.W., Horan M.F., Czamanske G.K., Krogstad E.J., Fedorenko V.A., Kunilov V.E. (1994) Re-Os isotopic evidence for an enriched-mantle source for the Noril’sk-type, ore-bearing intrusion, Siberia. Geochim. Cosmochim. Acta, 58, 4179-4197.Wilkinson J.J., Weiss D.J., Mason T.F.D., Coles B.J. (2005) Zinc isotope variation in hydrothermal systems: preliminary evidence from the Irish Midlands ore field. Econ. Geol., 100, 583-590.Wang D., Sun X., Zheng Y., Wu S., Xia S., Chang H., Yu M. (2017) Two pulses of mineralization and genesis of the Zhaxikang Sb–Pb–Zn–Ag deposit in southern Tibet: constraints from Fe–Zn isotopes. Ore Geol. Rev., 84, 347-363.Wooden J.L., Czamanske G.K., Bouse R.M., Likhachev A.P., Kunilov V.E., Lyul’ko V. (1992) Pb isotope data indicate a complex mantle origin for the Norilsk-Talnakh ores, Siberia. Econ. Geol., 87, 1153-1165.Wilkinson J.J. (2023) The potential of Zn isotopes in the science and exploration of ore deposits. (Eds D. Huston, J. Gutzmer) Isotopes in Economic Geology, Metallogenesis and Exploration. Cham: Springer, 451-463.Wu L.-Y., Hu R.-Z., Li X.-F., Liu S.-A., Tang Y.-W., Yong-Yong Tang Y.-Y. (2017) Copper isotopic compositions of the Zijinshan high-sulfidation epithermal Cu-Au deposit, South China: Implications for deposit origin. Ore Geol. Rev., 83, 191-199.Wilkinson J.J., Weiss D.J., Mason T.F.D., Coles B.J. (2005) Zinc isotope variation in hydrothermal systems: preliminary evidence from the Irish Midlands ore field. Econ. Geol., 100, 583-590.Zen’ko T.E. (1983) Mechanism of formation of the Noril’sk ore-bearing intrusions. Izvestiya Akademii Nauk SSSR. Ser. Geol., (11), 21-39. (In Russ.)Wooden J.L., Czamanske G.K., Bouse R.M., Likhachev A.P., Kunilov V.E., Lyul’ko V. (1992) Pb isotope data indicate a complex mantle origin for the Norilsk-Talnakh ores, Siberia. Econ. Geol., 87, 1153-1165.Zhao Y., Xue C.J., Liu S.A., Mathur R., Zhao X.B., Yang Y.Q., Dai J.F., Man R.H., Liu X.M. (2019) Redox reactions control Cu and Fe isotope fractionation in a magmatic Ni-Cu mineralization system. Geochim. Cosmochim. Acta, 249, 42-58.Wu L.-Y., Hu R.-Z., Li X.-F., Liu S.-A., Tang Y.-W., Yong-Yong Tang Y.-Y. (2017) Copper isotopic compositions of the Zijinshan high-sulfidation epithermal Cu-Au deposit, South China: Implications for deposit origin. Ore Geol. Rev., 83, 191-199.Zhao Y., Xue C., Liu S.-A., Symons D.T.A., Zhao X., Yang Y., Ke J. (2017) Copper isotope fractionation during sulfide-magma differentiation in the Tulaergen magmatic Ni-Cu deposit, NW China. Lithos, 286-287, 206-215.Zhao Y., Xue C.J., Liu S.A., Mathur R., Zhao X.B., Yang Y.Q., Dai J.F., Man R.H., Liu X.M. (2019) Redox reactions control Cu and Fe isotope fractionation in a magmatic Ni-Cu mineralization system. Geochim. Cosmochim. Acta, 249, 42-58.Zhou J.-X., Huang Z.-L., Zhou M.-F., Zhu X.-K., Muchez P. (2014) Zinc, sulfur and lead isotopic variations in carbonate-hosted Pb–Zn sulfide deposits, southwest China. Ore Geol. Rev., 58, 41-54.Zhao Y., Xue C., Liu S.-A., Symons D.T.A., Zhao X., Yang Y., Ke J. (2017) Copper isotope fractionation during sulfide-magma differentiation in the Tulaergen magmatic Ni-Cu deposit, NW China. Lithos, 286-287, 206-215.Zolotukhin V.V., Ryabov Y.A., Vasil’ev Y.R., Shatkov V.A. (1975) Petrology of the Talnakh ore-bearing differentiated trap intrusion. Novosibirsk, Nauka Publ., 432 p. (In Russ.)Zhou J.-X., Huang Z.-L., Zhou M.-F., Zhu X.-K., Muchez P. (2014) Zinc, sulfur and lead isotopic variations in carbonate-hosted Pb–Zn sulfide deposits, southwest China. Ore Geol. Rev., 58, 41-54.Zotov I.A. (1979) Genesis of trap intrusions and metamorphic formations of Talnakh. Moscow, Nauka Publ., 155 p. (In Russ.)Zhu X.K., Guo Y., Williams R.J.P., O’Nions R.K., Mat-thews A., Burgess B.K., Salvato B. (2002) Mass fractionation processes of transition metal isotopes. Earth. Planet. Sci. Lett., 200, 47-62.Zhu X.K., Guo Y., Williams R.J.P., O’Nions R.K., Mat-thews A., Burgess B.K., Salvato B. (2002) Mass fractionation processes of transition metal isotopes. Earth. Planet. Sci. Lett., 200, 47-62.Zhu X.K., O’Nions R.K., Guo Y., Belshaw N.S., Rickard D. (2000) Determination of natural Cu-isotope variation by plasma-source mass spectrometry: implications for use as geochemical tracers. Chem. Geol., 163, 139-149.Zhu X.K., O’Nions R.K., Guo Y., Belshaw N.S., Rickard D. (2000) Determination of natural Cu-isotope variation by plasma-source mass spectrometry: implications for use as geochemical tracers. Chem. Geol., 163, 139-149.

The authors declare that there are no conflicts of interest present.