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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">litosphere</journal-id><journal-title-group><journal-title xml:lang="ru">Литосфера</journal-title><trans-title-group xml:lang="en"><trans-title>LITHOSPHERE (Russia)</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1681-9004</issn><issn pub-type="epub">2500-302X</issn><publisher><publisher-name>A.N. Zavaritsky Institute of Geology and Geochemistry</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.24930/1681-9004-2019-19-5-659-686</article-id><article-id custom-type="elpub" pub-id-type="custom">litosphere-1210</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Статьи</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>Articles</subject></subj-group></article-categories><title-group><article-title>Укская свита верхнего рифея Южного Урала: седиментология и геохимия (первые результаты исследований)</article-title><trans-title-group xml:lang="en"><trans-title>Sedimentology and geochemistry of the Uk Formation, Upper Riphean, the Southern Urals</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Маслов</surname><given-names>А. B.</given-names></name><name name-style="western" xml:lang="en"><surname>Maslov</surname><given-names>A. V.</given-names></name></name-alternatives><bio xml:lang="ru"/><bio xml:lang="en"/><email xlink:type="simple">amas2004@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Гражданкин</surname><given-names>Д. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Grazhdankin</surname><given-names>D. V.</given-names></name></name-alternatives><bio xml:lang="ru"/><bio xml:lang="en"/><email xlink:type="simple">f6oeoua@mac.com</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Дуб</surname><given-names>С. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Dub</surname><given-names>S. A.</given-names></name></name-alternatives><bio xml:lang="ru"/><bio xml:lang="en"/><email xlink:type="simple">sapurin@igg.uran.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Мельник</surname><given-names>Д. С.</given-names></name><name name-style="western" xml:lang="en"><surname>Melnik</surname><given-names>D. S.</given-names></name></name-alternatives><bio xml:lang="ru"><p>630060, г. Новосибирск, просп. Акад. Коптюга, 3; </p><p>630090, г. Новосибирск, ул. Пирогова, 1</p></bio><bio xml:lang="en"><p>3 Koptug av., Novosibirsk, 630090;</p><p>1 Pirogova str., Novosibirsk, 630090</p></bio><email xlink:type="simple">mds7456@mail.ru</email><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Парфенова</surname><given-names>Т. М.</given-names></name><name name-style="western" xml:lang="en"><surname>Parfenova</surname><given-names>T. M.</given-names></name></name-alternatives><bio xml:lang="ru"><p>630060, г. Новосибирск, просп. Акад. Коптюга, 3; </p><p>630090, г. Новосибирск, ул. Пирогова, 1</p></bio><bio xml:lang="en"><p>3 Koptug av., Novosibirsk, 630090;</p><p>1 Pirogova str., Novosibirsk, 630090</p></bio><email xlink:type="simple">parfenovatm@ipgg.sbras.ru</email><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Колесников</surname><given-names>А. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Kolesnikov</surname><given-names>A. V.</given-names></name></name-alternatives><bio xml:lang="ru"/><bio xml:lang="en"/><email xlink:type="simple">ppp853@gmail.com</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Чередниченко</surname><given-names>Н. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Cherednichenko</surname><given-names>N. V.</given-names></name></name-alternatives><bio xml:lang="ru"/><bio xml:lang="en"/><xref ref-type="aff" rid="aff-4"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Киселева</surname><given-names>Д. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Kiseleva</surname><given-names>D. V.</given-names></name></name-alternatives><bio xml:lang="ru"/><bio xml:lang="en"/><email xlink:type="simple">kiseleva@igg.uran.ru</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Институт геологии и геохимии УрО РАН</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Zavaritsky Institute of Geology and Geochemistry, Urals Branch of RAS</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Институт нефтегазовой геологии и геофизики СО РАН</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of RAS</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-3"><aff xml:lang="ru"><institution>Институт нефтегазовой геологии и геофизики СО РАН; &#13;
Новосибирский государственный университет</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of RAS; &#13;
Novosibirsk State University</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-4"><aff xml:lang="ru"><institution>Институт геологии и геохимии УрО РАН</institution><country>Россия</country></aff><aff xml:lang="en"><institution>3 Koptug av., Novosibirsk, 630090</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2019</year></pub-date><pub-date pub-type="epub"><day>22</day><month>11</month><year>2019</year></pub-date><volume>19</volume><issue>5</issue><fpage>659</fpage><lpage>686</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Маслов А.B., Гражданкин Д.В., Дуб С.А., Мельник Д.С., Парфенова Т.М., Колесников А.В., Чередниченко Н.В., Киселева Д.В., 2019</copyright-statement><copyright-year>2019</copyright-year><copyright-holder xml:lang="ru">Маслов А.B., Гражданкин Д.В., Дуб С.А., Мельник Д.С., Парфенова Т.М., Колесников А.В., Чередниченко Н.В., Киселева Д.В.</copyright-holder><copyright-holder xml:lang="en">Maslov A.V., Grazhdankin D.V., Dub S.A., Melnik D.S., Parfenova T.M., Kolesnikov A.V., Cherednichenko N.V., Kiseleva D.V.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://www.lithosphere.ru/jour/article/view/1210">https://www.lithosphere.ru/jour/article/view/1210</self-uri><abstract><sec><title></title><p>.</p></sec><sec><title>Объект исследования</title><p>Объект исследования. В статье приведены новые данные о карбонатных фациях верхней подсвиты укской свиты верхнего рифея Южного Урала, а также особенностях распределения редкоземельных элементов (РЗЭ) и Y в строматолитовых, обломочных и карбонатно-глинистых породах (валовые пробы и уксуснокислотные вытяжки из них). Впервые обсуждаются особенности состава битумоидов и биомаркеров укской свиты.</p></sec><sec><title>Материал и методы</title><p>Материал и методы. Изучены литологические особенности известняков непосредственно в разрезе и по серии шлифов. Содержания малых элементов в породах определены методом ICP-MS в ИГГ УрО РАН (г. Екатеринбург), а состав органического вещества – в ИНГГ СО РАН (г. Новосибирск) методами газо-жидкостной хроматографии и хроматомасс-спектрометрии.</p></sec><sec><title>Результаты</title><p>Результаты. Показано, что в наиболее представительном разрезе верхнеукской подсвиты на восточной окраине г. Усть-Катав можно выделить несколько различающихся по литологии и по мощности толщ/пачек: 1) существенно биогермную, представленную преимущественно крупными органогенными постройками, разделенными межбиогермными фациями (обломочные известняки, биоламиниты и др.); 2) переходную, характеризующуюся частым чередованием органогенных построек и других типов карбонатных пород; 3) зернистых известняков, чередующихся с прослоями микрозернистых известняков. Выше указанных толщ в разрезе вновь наблюдаются строматолитовые биогермы. Присутствие “molar tooth” текстур в карбонатных породах укской свиты дает основание считать, что данная литостратиграфическая единица типового разреза рифея имеет, скорее всего, докриогениевый возраст.</p></sec><sec><title>Выводы</title><p>Выводы. Установлено, что распределение РЗЭ и Y в относительно чистых от силикокластической примеси валовых пробах известняков и уксусно-кислотных вытяжках из них сопоставимо. Нормированные по PAAS спектры распределения РЗЭ + Y характеризуются положительными аномалиями La, Gd и Y и отрицательными аномалиями Eu и Ce. Последние позволяют предполагать, что накопление строматолитсодержащих известняков верхнеукской подсвиты происходило в морском бассейне. Показано, что карбонатные и карбонатно-глинистые породы обеднены органическим веществом. Его источником были два сообщества, в состав которых входили эукариоты и прокариоты, обитавшие в условиях нормальной аэрации и, возможно, пониженной солености вод морского бассейна. </p></sec></abstract><trans-abstract xml:lang="en"><sec><title>Research subject</title><p>Research subject. This article presents new data on carbonate facies of the upperUk subformation, Upper Riphean of theSouth Urals. A particular attention is paid to the distribution of rare-earth elements (REE) and yttrium (Y) in stromatolitic and intraclastic limestones and calcareous shales (bulk samples and their acetic acid leachates).</p></sec><sec><title>Materials and methods</title><p>Materials and methods. We have studied lithological features of limestones in the geological section and in thin sections. The contents of trace elements in rocks were determined by the ICP-MS method at the IGG UB RAS (Yekaterinburg), the composition of organic matter was determined at the IPGG SB RAS (Novosibirsk) by gas-liquid chromatography and chromatography-mass spectrometry.</p></sec><sec><title>Results</title><p>Results. The most representative section of the Upper Uk Subformation located along the eastern edge of the town Ust-Katav can be subdivided into several members of different lithology and thickness: (1) biohermdominated member comprising large microbialitic build-ups and inter-bioherm sediments (intraclastic limestones, calcareous biolaminites); (2) transitional member characterised by small bioherms alternating with other carbonates; (3) interbedded coarseand fine-grained limestones. The presence of molar-tooth structures in the carbonate rocks of Uk Formation made it possible to constrain the age of thisUpper Riphean formation to pre-Cryogenian</p></sec><sec><title>Conclusions</title><p>Conclusions. There are similarities in REE and Y distribution in both clean (devoid of siliciclastic component) bulk limestone samples and in their acetic acid leachates. PAAS-normalised REE + Y patterns demonstrate positive La, Gd, Y anomalies and negative Eu, Ce anomalies. The latter suggest marine depositional environments for theUpper Uk stromatolitic limestones. The results of the pioneering research into the composition of bitumens and biomarkers from the Upper Uk Subformation have shown that carbonates and shales are depleted in the organic matter. The source material for the organic matter was provided by two types of communities comprising both eukaryotes and prokaryotes and inhabiting well aerated environment, perhaps with lowered salinity of marine water. </p></sec></trans-abstract><kwd-group xml:lang="ru"><kwd>Южный Урал</kwd><kwd>верхний рифей</kwd><kwd>укская свита</kwd><kwd>карбонатные породы</kwd><kwd>седиментология</kwd><kwd>литология</kwd><kwd>геохимия</kwd><kwd>битумоиды</kwd><kwd>биомаркеры</kwd></kwd-group><kwd-group xml:lang="en"><kwd>South Urals</kwd><kwd>Upper Riphean</kwd><kwd>Uk Formation</kwd><kwd>carbonates</kwd><kwd>sedimentology</kwd><kwd>lithology</kwd><kwd>geochemistry</kwd><kwd>bitumoids</kwd><kwd>biomarkers</kwd></kwd-group><funding-group><funding-statement xml:lang="ru">Исследования выполнены при финансовой поддержке РФФИ (грант 18-05-00062).</funding-statement><funding-statement xml:lang="en">This work was supported by the Russian Foundation for Basic Research (project No. 18-05-00062)</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Беккер Ю.Р. (1958) О стратиграфическом положении укских отложений на Южном Урале. Докл. АН СССР, 122(5), 879-882.</mixed-citation><mixed-citation xml:lang="en">Alexander B.W., Bau M., Andersson P., Dulski P. (2008) Continentally-derived solutes in shallow Archean seawater: rare earth element and Nd isotope evidence in iron formation from the 2.9 Ga Pongola Supergroup, South Africa. Geochim. Cosmochim. Acta, 72, 378-394.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Беккер Ю.Р. (1961) Возраст и последовательность напластования отложений верхней части каратауской серии Южного Урала. Изв. АН СССР. Сер. геол., (9), 49-60.</mixed-citation><mixed-citation xml:lang="en">Anderson K.D., Beauchamp B. (2014) Paleobiology and paleoecology of Palaeoaplysina and Eopalaeoaplysina new genus in Arctic Canada. J. Paleontol., 88(5), 1056-1071.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Вассоевич Н.Б. (1973) Основные закономерности, характеризующие органическое вещество современных и ископаемых осадков. Природа органического вещества современных и ископаемых осадков. М.: Наука, 11-59.</mixed-citation><mixed-citation xml:lang="en">Bartley J.K., Kah L.C. (2004) Marine carbon reservoir, Corg–Ccarb coupling, and the Proterozoic carbon isotope record. Geology, 32, 129-132.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Гражданкин Д.В., Маслов А.В. (2015) Место венда в международной стратиграфической шкале. Геология и геофизика, 56(4), 703-717.</mixed-citation><mixed-citation xml:lang="en">Bau M., Dulski P. (1996) Distribution of yttrium and rareearth elements in the Penge and Kuruman iron-formations, Transvaal Supergroup, South Africa. Prec. Res., 79(1-2), 37-55.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Горожанин В.М. (1995) Rb-Sr метод в решении проблем геологии Южного Урала. Автореф. дис. … канд. геол.-мин. наук. Екатеринбург: ИГГ УрО РАН, 23 с.</mixed-citation><mixed-citation xml:lang="en">Bau M., Moller P. (1993) Rare earth element systematics of the chemically precipitated component in Early Precambrian iron formations and the evolution of the terrestrial atmosphere–hydrosphere–lithosphere system. Geochim. Cosmochim. Acta, 57, 2239-2249.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Домрачев С.М. (1952) Девон хр. Каратау и прилегающих районов Южного Урала. Девон Западного Приуралья. Л.; М.: Гостоптехиздат, Ленингр. отд-ние, 5-121.</mixed-citation><mixed-citation xml:lang="en">Becker Yu.R. (1961) Age and sequence of deposits in the upper part of the Karatau Group of the Southern Urals. Izv. Akad Nauk SSSR. Ser. Geol., (9), 49-60. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Зайцева Т.С., Горохов И.М., Ивановская Т.А., Семихатов М.А., Кузнецов А.Б., Мельников Н.Н., Аракелянц М.М., Яковлева О.В. (2008) Мессбауэровские характеристики, минералогия и изотопный возраст (Rb-Sr, K-Ar) верхнерифейских глауконитов укской свиты Южного Урала. Стратиграфия. Геол. корреляция, 16(3), 3-25.</mixed-citation><mixed-citation xml:lang="en">Becker Yu.R. (1958) On the stratigraphic position of Uk deposits in the Southern Urals. Dokl. Akad Nauk SSSR, 122(5), 879-882. (In Russian).</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Зайцева Т.С., Горохов И.М., Кузнецов А.Б., Константинова Г.В., Турченко Т.Л., Мельников Н.Н. (2012) RbSr изотопная систематика глинистых минералов из осадочных пород венда Южного Урала. Ленинградская школа литологии. Т. II. СПб: СПбГУ, 57-59.</mixed-citation><mixed-citation xml:lang="en">Bishop J.W., Sumner D.Y. (2006) Molar tooth structures of the Neoarchean Monteville Formation, Transvaal Supergroup, South Africa. I: Constraints on microcrystalline CaCO3 precipitation. Sedimentology, 53, 1049-1068.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Козлов В.И. (1973) К вопросу о строении укских и ашинских отложений верхнего протерозоя Южного Урала. Изв. АН СССР. Сер. геол., (7), 112-123. Козлов В.И. (1982) Верхний рифей и венд Южного Урала. М.: Наука, 128 с.</mixed-citation><mixed-citation xml:lang="en">Bolhar R., Kamber B.S., Moorbath S., Fedo C.M., Whitehouse M.J. (2004) Characterisation of Early Archaean chemical sediments by trace element signatures. Earth Planet. Sci. Lett., 222(1), 43-60.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Конторович А.Э. (1976) Геохимические методы количественного прогноза нефтегазоносности. М.: Недра, 250 с.</mixed-citation><mixed-citation xml:lang="en">Bolhar R., Van Kranendonk M.J. (2007) A non-marine depositional setting for the northern Fortescue Group, Pilbara Craton, inferred from trace element geochemistry of stromatolitic carbonates. Prec. Res., 155, 229-250.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Крылов И.Н. (1963) Столбчатые ветвящиеся строматолиты рифейских отложений Южного Урала и их значение для стратиграфии верхнего докембрия. М.: Наука, 243 с.</mixed-citation><mixed-citation xml:lang="en">Botting J.P., Muir L.A. (2017) Early sponge evolution: A review and phylogenetic framework. Palaeoworld, 27(1), 1-29.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Крылов И.Н. (1967) Рифейские и нижнекембрийские строматолиты Тянь-Шаня и Каратау. М.: Наука, 78 с.</mixed-citation><mixed-citation xml:lang="en">Brocks J.J., Jarret A.J.M., Sirantoine E., Kenig F., Moczydlowska M., Porter S., Hope J. (2016) Early sponges and toxic protists: possible sources of cryostane, an age diagnostic biomarker antedating Sturtian Snowball Earth. Geobiology, 14, 129-149.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Крылов И.Н. (1975) Строматолиты рифея и фанерозоя СССР. М.: Наука, 243 с.</mixed-citation><mixed-citation xml:lang="en">Burgsdorf I., Slaby B.M., Handley K.M., Haber M., Blom J., Marshal C.W., Gilbert J.A., Hentschel U., Steindler L. (2015) Lifestyle evolution in cyanobacterial symbionts of sponges. MBio, 6(3):e00391-15. doi:10.1128/mBio.00391-15.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Кузнецов А.Б. (2013) Эволюция изотопного состава стронция в протерозойском океане. Автореф. дис. … докт. геол.-мин. наук. СПб: ИГГД РАН, 43 с.</mixed-citation><mixed-citation xml:lang="en">Chen Y.J., Zhao Y.C. (1997) Geochemical characteristics and evolution of REE in the Early Precambrian sediments: evidences from the southern margin of the North China Craton. Episodes, 20, 109-116.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Кузнецов А.Б., Семихатов М.А., Горохов И.М., Мельников Н.Н., Константинова Г.В., Кутявин Э.П. (2003) Изотопный состав Sr в карбонатных породах каратавской серии Южного Урала и стандартная кривая вариаций отношения 87Sr/86Sr в позднерифейском океане. Стратиграфия. Геол. корреляция, 11(5), 3-39.</mixed-citation><mixed-citation xml:lang="en">Clark J.P. Philp R.P. (1989) Geochemical characterization of evaporite and carbonate depositional environments and correlation of associated crude oils in the Black Creek Basin, Alberta. Can. Petrol. Geol. Bull., 37, 401-416.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Кузнецов А.Б., Семихатов М.А., Маслов А.В., Горохов И.М., Прасолов Э.М., Крупенин М.Т., Кислова И.В. (2006) Srи С-изотопная хемостратиграфия типового разреза верхнего рифея (Южный Урал): новые данные. Стратиграфия. Геол. корреляция, 14(6), 25-53.</mixed-citation><mixed-citation xml:lang="en">Davies G.R., Nassichuk W.W. (1973) The Hydrozoan? Palaeoaplysina from the Upper Paleozoic of Ellesmere Island, Arctic Canada. J. Paleontol., 47 (2), 251-265.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Кузнецов В.Г. (2005) Molar tooth structure – своеобразная текстура рифейских карбонатных пород. Литосфера, (4), 136-150.</mixed-citation><mixed-citation xml:lang="en">De Baar H.J.W., Bacon M.P., Brewer P.G. (1985) Rare earth elements in the Pacific and Atlantic Oceans. Geochim. Cosmochim. Acta, 49, 1943-1959.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Маслов А.В. (2004) Molar-tooth текстуры: эволюция взглядов на генезис. Карбонатные осадочные последовательности Урала и сопредельных территорий: седиментои литогенез, минерагения. Екатеринбург: ИГГ УрО РАН, 98-101.</mixed-citation><mixed-citation xml:lang="en">Domrachev S.M. (1952) Devonian of the Karatau Range and adjacent areas of the Southern Urals. Devonian of the West Ural. Leningrad; Moscow, Gostoptekhizdat Publ., Leningr. division, 5-121. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Маслов А.В., Меерт Дж., Левашова Н.М., Ронкин Ю.Л., Гражданкин Д.В., Кузнецов Н.Б., Крупенин М.Т., Федорова Н.М., Ипатьева И.С. (2013) Новые данные о возрасте ледниковых отложений венда Среднего Урала. Докл. АН, 449(3), 322-327.</mixed-citation><mixed-citation xml:lang="en">Dragastan O., Kube B., Richter D.K. (1999) New Late Triassic calcareous algae from Hydra, Greece. Acta Palaeontol. Rom., 2, 139-156.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Овчинникова Г.В., Васильева И.М., Семихатов М.А. (2000) Возможности Pb-Pb датирования карбонатных пород с открытыми U-Pb системами: миньярская свита стратотипа верхнего рифея, Южный Урал. Стратиграфия. Геол. корреляция, 8(6), 3-19.</mixed-citation><mixed-citation xml:lang="en">Elderfield H. (1988) The oceanic chemistry of the rare-earth elements. Phil. Trans. Royal Soc. London, A325, 105-126.</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Овчинникова Г.В., Васильева И.М., Семихатов М.А. Кузнецов А.Б., Горохов И.М., Гороховский Б.М., Левский Л.К. (1998) U-Pb систематика протерозойских карбонатных пород: инзерская свита уральского стратотипа рифея (Южный Урал). Стратиграфия. Геол. корреляция, 6(4), 20-31.</mixed-citation><mixed-citation xml:lang="en">Frei R., Dahl P.S., Duke E.F., Frei K.M., Hansen T.R., Frandsson M.M., Jensen L.A. (2008) Trace element and isotopic characterization of Neoarchean and Paleoproterozoic iron formations in the Black Hills (South Dakota, USA): assessment of chemical change during 2.9–1.9 Ga deposition bracketing the 2.4–2.2 Ga first rise of atmospheric oxygen. Prec. Res. 162, 441-474.</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Парфенова Т.М., Коровников И.В., Эдер В.Г., Меленевский В.Н. (2017) Органическая геохимия синской свиты нижнего кембрия (северный склон Алданской антеклизы). Геология и геофизика, (5), 723-738.</mixed-citation><mixed-citation xml:lang="en">Frimmel H.E. (2009) Trace element distribution in Neoproterozoic carbonates as palaeoenvironmental indicator. Chem. Geol., 258, 338-353.</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Петров А.А. (1984) Углеводороды нефти. М.: Наука, 264 с.</mixed-citation><mixed-citation xml:lang="en">Ge L., Jiang S.-Y., Swennen R., Yang T., Yang J.-H., Wu N.-Y., Liu J., Chen D.-H. (2010) Chemical environment of cold seep carbonate formation on the northern continental slope of South China Sea: evidence from trace and rare earth element geochemistry. Mar. Geol., 277, 21-30.</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Петров П.Ю. (2016) Molar tooth structures и происхождение пелоидов протерозойских карбонатных платформ (средний рифей Туруханского поднятия Сибири). Литология и полез. ископаемые, (4), 336-358.</mixed-citation><mixed-citation xml:lang="en">Gold D.A., Grabenstatter J., Mendoza A., Riesgo A., RuizTrillo I., Summons R.E. (2016) Sterol and genomic analyses validate the sponge biomarker hypothesis. PNAS, 113(10), 2684-2689.</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Путеводитель геологической экскурсии по разрезам палеозоя и верхнего докембрия западного склона Южного Урала и Приуралья (1995) Уфа: ИГ УНЦ РАН, 176 с.</mixed-citation><mixed-citation xml:lang="en">Gorozhanin V.M. (1995) Rb-Sr metod v reshenii problem geologii Yuzhnogo Urala. Diss. kand. geol-min nauk [Rb-Sr method in solving problems of the geology of the Southern Urals. Cand. geol. and min. sci. diss.] Ekaterinburg, IGG Ural Branch of RAS, 23 p. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit26"><label>26</label><citation-alternatives><mixed-citation xml:lang="ru">Раабен М.Е., Забродин В.Е. (1972) Водорослевая проблематика верхнего рифея (строматолиты, онколиты). М.: Наука, 130 с. С</mixed-citation><mixed-citation xml:lang="en">Grazhdankin D.V., Maslov A.V. (2015) The room for the Vendian in the International Chronostratigraphic Scale. Russ. Geol. Geophys., 56, 549-559.</mixed-citation></citation-alternatives></ref><ref id="cit27"><label>27</label><citation-alternatives><mixed-citation xml:lang="ru">емихатов М.А., Кузнецов А.Б., Чумаков Н.М. (2015) Изотопный возраст границ общих стратиграфических подразделений верхнего протерозоя (рифея и венда) России: эволюция взглядов и современная оценка. Стратиграфия. Геол. корреляция, 23(6), 16-27.</mixed-citation><mixed-citation xml:lang="en">Grotzinger J.P., James N.P. (2000) Precambrian carbonates: evolution of understanding. Carbonate Sedimentation and Diagenesis in the Evolving Precambrian World. SEPM Spec. Publ., 67. Tulsa SEPM, 3-20.</mixed-citation></citation-alternatives></ref><ref id="cit28"><label>28</label><citation-alternatives><mixed-citation xml:lang="ru">Стратотип рифея. Палеонтология. Палеомагнетизм (1982) (Отв. ред. Б.М. Келлер, Н.М. Чумаков). М.: Наука, 176 с.</mixed-citation><mixed-citation xml:lang="en">Hill D. (1981) Rugosa and Tabulata. Treatise on Invertebrate Paleontology, Pt F. Teichert C. (Ed.), 762 p.</mixed-citation></citation-alternatives></ref><ref id="cit29"><label>29</label><citation-alternatives><mixed-citation xml:lang="ru">Стратотип рифея. Стратиграфия. Геохронология (1983) (Отв. ред. Б.М. Келлер, Н.М. Чумаков). М.: Наука, 184 с.</mixed-citation><mixed-citation xml:lang="en">James N.P., Narbonne G.M., Sherman A.G. (1998) Molartooth carbonates: Shallow subtidal facies of the Midto Late Proterozoic. J. Sed. Res., 68, 716-722.</mixed-citation></citation-alternatives></ref><ref id="cit30"><label>30</label><citation-alternatives><mixed-citation xml:lang="ru">Alexander B.W., Bau M., Andersson P., Dulski P. (2008) Continentally-derived solutes in shallow Archean seawater: rare earth element and Nd isotope evidence in iron formation from the 2.9 Ga Pongola Supergroup, South Africa. Geochim. Cosmochim. Acta, 72, 378-394.</mixed-citation><mixed-citation xml:lang="en">Kamber B.S., Webb G.E. (2001) The geochemistry of Late Archaean microbial carbonate: implications for ocean chemistry and continental erosion history. Geochim. Cosmochim. Acta, 65, 2509-2525.</mixed-citation></citation-alternatives></ref><ref id="cit31"><label>31</label><citation-alternatives><mixed-citation xml:lang="ru">Anderson K. D., Beauchamp B. (2014) Paleobiology and paleoecology of Palaeoaplysina and Eopalaeoaplysina new genus in Arctic Canada. J. Paleontol., 88(5), 1056-1071.</mixed-citation><mixed-citation xml:lang="en">Kozlov V.I. (1982) Verkhnii rifei i vend Yuzhnogo Urala [Upper Riphean and Vendian of the Southern Urals]. Moscow, Nauka Publ., 128 p. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit32"><label>32</label><citation-alternatives><mixed-citation xml:lang="ru">Bartley J.K., Kah L.C. (2004) Marine carbon reservoir, Corg–Ccarb coupling, and the Proterozoic carbon isotope record. Geology, 32, 129-132.</mixed-citation><mixed-citation xml:lang="en">Kozlov V.I. (1973) On the question of the structure of the Uk and Asha deposits of the Upper Proterozoic of the Southern Urals. Izv. Akad Nauk SSSR. Ser. Geol., (7), 112-123. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit33"><label>33</label><citation-alternatives><mixed-citation xml:lang="ru">Bau M., Dulski P. (1996) Distribution of yttrium and rareearth elements in the Penge and Kuruman iron-formations, Transvaal Supergroup, South Africa. Prec. Res., 79(1-2), 37-55.</mixed-citation><mixed-citation xml:lang="en">Kontorovich A.E. (1976) Geokhimicheskie metody colichestvennogo prognoza neftegazonosnosti [Geochemical methods for quantitative prediction of petroleum potential]. Moscow, Nedra Publ., 250 p. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit34"><label>34</label><citation-alternatives><mixed-citation xml:lang="ru">Bau M., Moller P. (1993) Rare earth element systematics of the chemically precipitated component in Early Precambrian iron formations and the evolution of the terrestrial atmosphere–hydrosphere–lithosphere system. Geochim. Cosmochim. Acta, 57, 2239-2249.</mixed-citation><mixed-citation xml:lang="en">Krylov I.N. (1963) Stolbchatye i vetvyashchiesya stromatolity rifeiskikh otlozhenii Yuzhogo Urala i ikh znachenie dlya stratigrafii verkhnego dokembriya [Columnar branching stromatolites of the Riphean deposits of the Southern Urals and their significance for Upper Precambrian stratigraphy]. Moscow, Nauka Publ., 243 p. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit35"><label>35</label><citation-alternatives><mixed-citation xml:lang="ru">Bishop J.W., Sumner D.Y. (2006) Molar tooth structures of the Neoarchean Monteville Formation, Transvaal Supergroup, South Africa. I: Constraints on microcrystalline CaCO3 precipitation. Sedimentology, 53, 1049-1068.</mixed-citation><mixed-citation xml:lang="en">Krylov I.N. (1967) Rifeiskie i nizhnekembriiskie stromatolity Tyan’-Shanya i Karatau [Riphean and Lower Cambrian stromatolites from Tian Shan and Karatau]. Moscow, Nauka Publ., 78 p.</mixed-citation></citation-alternatives></ref><ref id="cit36"><label>36</label><citation-alternatives><mixed-citation xml:lang="ru">Bolhar R., Kamber B.S., Moorbath S., Fedo C.M., Whitehouse M.J. (2004) Characterisation of Early Archaean chemical sediments by trace element signatures. Earth Planet. Sci. Lett., 222(1), 43-60.</mixed-citation><mixed-citation xml:lang="en">Krylov I.N. (1975) Stromatolity rifeya i fanerozoya SSSR [Riphean and Phanerozoic stromatolites from the USSR]. Moscow, Nauka Publ., 243 p. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit37"><label>37</label><citation-alternatives><mixed-citation xml:lang="ru">Bolhar R., Van Kranendonk M.J. (2007) A non-marine depositional setting for the northern Fortescue Group, Pilbara Craton, inferred from trace element geochemistry of stromatolitic carbonates. Prec. Res., 155, 229-250.</mixed-citation><mixed-citation xml:lang="en">Kuang H-W., Hu X.-F. (2014) Review of molar tooth structure research. J. Palaeogeography, 3, 359-383.</mixed-citation></citation-alternatives></ref><ref id="cit38"><label>38</label><citation-alternatives><mixed-citation xml:lang="ru">Botting J.P., Muir L.A. (2017) Early sponge evolution: A review and phylogenetic framework. Palaeoworld, 27(1), 1-29.</mixed-citation><mixed-citation xml:lang="en">Kuznetsov A.B. (2013) Evolutsiya izotopnogo sostava strontsiya v proterozoiskom okeane. Diss. dokt. geolmin nauk [Evolution of strontium isotopic composition in the Proterozoic ocean. Dr. geol.and min. sci. diss.] St.Petersburg, IGGD RAN, 43 p. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit39"><label>39</label><citation-alternatives><mixed-citation xml:lang="ru">Brocks J.J., Jarret A.J.M., Sirantoine E., Kenig F., Moczydlowska M., Porter S., Hope J. (2016) Early sponges and toxic protists: possible sources of cryostane, an age diagnostic biomarker antedating Sturtian Snowball Earth. Geobiology, 14, 129-149.</mixed-citation><mixed-citation xml:lang="en">Kuznetsov A.B., Bekker A., Ovchinnikova G.V., Gorokhov I.M., Vasilyeva I.M. (2017) Unradiogenic strontium and moderate-amplitude carbon isotope variations in early Tonian seawater after the assembly of Rodinia and before the Bitter Springs Excursion. Prec. Res. 298, 157-173.</mixed-citation></citation-alternatives></ref><ref id="cit40"><label>40</label><citation-alternatives><mixed-citation xml:lang="ru">Burgsdorf I., Slaby B.M., Handley K.M., Haber M., Blom J., Marshal C.W., Gilbert J.A., Hentschel U., Steindler L. (2015) Lifestyle evolution in cyanobacterial symbionts of sponges. MBio, 6(3):e00391-15. doi:10.1128/ mBio.00391-15.</mixed-citation><mixed-citation xml:lang="en">Kuznetsov A.B., Gorokhov I.M., Mel’nikov N.N., Konstantinova G.V., Kutyavin E.P., Semikhatov M.A. (2003) Sr isotope composition in carbonates of the Karatau Group,the outhern Urals, and standard curve of 87Sr/86Sr variations in the Late Riphean Ocean. Stratigr. Geol. Correl., 11(5), 415-449.</mixed-citation></citation-alternatives></ref><ref id="cit41"><label>41</label><citation-alternatives><mixed-citation xml:lang="ru">Chen Y.J., Zhao Y.C. (1997) Geochemical characteristics and evolution of REE in the Early Precambrian sediments: evidences from the southern margin of the North China Craton. Episodes, 20, 109-116.</mixed-citation><mixed-citation xml:lang="en">Kuznetsov A.B., Gorokhov I.M., Semikhatov M.A., Kislova I.V., Maslov A.V., Krupenin M.T., Prasolov E.M. (2006) New data on Sr-and C-isotopic chemostratigraphy of the Upper Riphean type section (southern Urals). Stratigr. Geol. Correl., 14(6), 602-628.</mixed-citation></citation-alternatives></ref><ref id="cit42"><label>42</label><citation-alternatives><mixed-citation xml:lang="ru">Clark J.P. Philp R.P. (1989) Geochemical characterization of evaporite and carbonate depositional environments and correlation of associated crude oils in the Black Creek Basin, Alberta. Can. Petrol. Geol. Bull., 37, 401-416.</mixed-citation><mixed-citation xml:lang="en">Kuznetsov V.G. (2005) Molar tooth structure – is a specific structure of the Riphean sediments. Lithosfera, (4), 136-150. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit43"><label>43</label><citation-alternatives><mixed-citation xml:lang="ru">Davies G.R., Nassichuk W.W. (1973) The Hydrozoan? Palaeoaplysina from the Upper Paleozoic of Ellesmere Island, Arctic Canada. J. Paleontol., 47(2), 251-265.</mixed-citation><mixed-citation xml:lang="en">Lee J.H., Byrne R.H. (1992) Complexation of trivalent rare earth elements (Ce, Eu, Gd, Tb, Yb) by carbonate ions. Geochim. Cosmochim. Acta, 57, 295-302.</mixed-citation></citation-alternatives></ref><ref id="cit44"><label>44</label><citation-alternatives><mixed-citation xml:lang="ru">De Baar H.J.W., Bacon M.P., Brewer P.G. (1985) Rare earth elements in the Pacific and Atlantic Oceans. Geochim. Cosmochim. Acta, 49, 1943-1959.</mixed-citation><mixed-citation xml:lang="en">Levashova N.M., Bazhenov M.L., Meert J.G., Kuznetsov N.B., Golovanova I.V., Danukalov K.N., Fedorova N.M. (2013) Paleogeography of Baltica in the Ediacaran: Paleomagnetic and geochronological data from the clastic Zigan Formation, South Urals. Prec. Res., 236, 16-30.</mixed-citation></citation-alternatives></ref><ref id="cit45"><label>45</label><citation-alternatives><mixed-citation xml:lang="ru">Dragastan O., Kube B., Richter D.K. (1999) New Late Triassic calcareous algae from Hydra, Greece. Acta Palaeontol. Rom., 2, 139-156.</mixed-citation><mixed-citation xml:lang="en">Love G.D., Grosjean E., Stalvies C., Fike D.A., Grotzinger J.P., Bradley A.S., Kelly A.E., Bhatia M., Meredith W., Snape C.E., Bowring S.A., Condon D.J., Summons R.E. (2009) Fossil steroids record the appearance of Demospongiae during the Cryogenian period. Nature, 457(7230), 718-721.</mixed-citation></citation-alternatives></ref><ref id="cit46"><label>46</label><citation-alternatives><mixed-citation xml:lang="ru">Elderfield H. (1988) The oceanic chemistry of the rare-earth elements. Phil. Trans. Royal Soc. London, A325, 105-126.</mixed-citation><mixed-citation xml:lang="en">Luo C., Reitner J. (2014) First report of fossil “keratose” demosponges in Phanerozoic carbonates: preservation and 3-D reconstruction. Naturwissenschaften, 101, 467-477</mixed-citation></citation-alternatives></ref><ref id="cit47"><label>47</label><citation-alternatives><mixed-citation xml:lang="ru">Frei R., Dahl P.S., Duke E.F., Frei K.M., Hansen T.R., Frandsson M.M., Jensen L.A. (2008) Trace element and isotopic characterization of Neoarchean and Paleoproterozoic iron formations in the Black Hills (South Dakota, USA): assessment of chemical change during 2.9–1.9 Ga deposition bracketing the 2.4–2.2 Ga first rise of atmospheric oxygen. Prec. Res. 162, 441-474.</mixed-citation><mixed-citation xml:lang="en">Luo C., Reitner J. (2015) “Stromatolites” built by sponges and microbes – a new type of Phanerozoic bioconstruction. Lethaia, 49(4). 555-570.</mixed-citation></citation-alternatives></ref><ref id="cit48"><label>48</label><citation-alternatives><mixed-citation xml:lang="ru">Frimmel H.E. (2009) Trace element distribution in Neoproterozoic carbonates as palaeoenvironmental indicator. Chem. Geol., 258, 338-353.</mixed-citation><mixed-citation xml:lang="en">Maslov A.V. (2004) Molar-tooth structures: evolution of views on the genesis. Karbonatnye i osadochnye posledovatel’nosti Urala i sopredel’nykh territorii: sedimentoi litogenez , minerageniya [Carbonate sedimentary sequences of the Urals and adjacent territories: sedimentoand lithogenesis, minerageny]. Ekaterinburg, IGG, Ural Branch of RAS, 98-101. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit49"><label>49</label><citation-alternatives><mixed-citation xml:lang="ru">Ge L., Jiang S.-Y., Swennen R., Yang T., Yang J.-H., Wu N.-Y., Liu J., Chen D.-H. (2010) Chemical environment of cold seep carbonate formation on the northern continental slope of South China Sea: evidence from trace and rare earth element geochemistry. Mar. Geol., 277, 21-30.</mixed-citation><mixed-citation xml:lang="en">Maslov A.V., Meert J., Levashova N.M., Ronkin Yu.L., Grazhdankin D.V., Kuznetsov N.B., Krupenin M.T., Fedorova N.M., Ipat’eva I.S. (2013) New Constraints for the Age of Vendian Glacial Deposits (Central Urals). Doklady Earth Sciences, 449, 303-308.</mixed-citation></citation-alternatives></ref><ref id="cit50"><label>50</label><citation-alternatives><mixed-citation xml:lang="ru">Gold D.A., Grabenstatter J., Mendoza A., Riesgo A., RuizTrillo I., Summons R.E. (2016) Sterol and genomic analyses validate the sponge biomarker hypothesis. PNAS, 113(10), 2684-2689.</mixed-citation><mixed-citation xml:lang="en">McCaffrey M.A., Moldowan J.M., Lipton P.A., Summons R.E., Peters K.E., Jeganathan A., Watt D.S. (1994) Paleoenvironmental implications of novel C30 steranes in Precambrian to Cenozoic age petroleum and bitumen. Geochim. Cosmochim. Acta, 58, 529-532.</mixed-citation></citation-alternatives></ref><ref id="cit51"><label>51</label><citation-alternatives><mixed-citation xml:lang="ru">Grotzinger J.P., James N.P. (2000) Precambrian carbonates: evolution of understanding.Carbonate Sedimentation and Diagenesis in the Evolving Precambrian World. SEPM Spec. Publ., 67. Tulsa: SEPM, 3-20.</mixed-citation><mixed-citation xml:lang="en">Moller P., Bau M. (1993) Rare-earth patterns with positive cerium anomaly in alkaline waters from Lake Van, Turkey. Earth Planet. Sci. Lett., 117(3–4), 671-676.</mixed-citation></citation-alternatives></ref><ref id="cit52"><label>52</label><citation-alternatives><mixed-citation xml:lang="ru">Hill D. (1981) Rugosa and Tabulata. Treatise on Invertebrate Paleontology, Pt F. Teichert C. (Ed.). 762 p.</mixed-citation><mixed-citation xml:lang="en">Nosenko T., Schreiber F., Adamska M., Adamski M., Eitel M., Hammel J., Maldonado M., Muller W.E.G., Nickel M., Schierwater B., Vacelet J., Wiens M., Worheide G. (2013) Deep metazoan phylogeny: When different genes tell different stories. Mol. Phylogen. Evol., 67, 223-233.</mixed-citation></citation-alternatives></ref><ref id="cit53"><label>53</label><citation-alternatives><mixed-citation xml:lang="ru">James N.P., Narbonne G.M., Sherman A.G. (1998) Molartooth carbonates: Shallow subtidal facies of the Midto Late Proterozoic. J. Sed. Res., 68, 716-722.</mixed-citation><mixed-citation xml:lang="en">Nothdurft L.D., Webb G.E., Kamber B.S. (2004) Rare earth element geochemistry of Late Devonian reefal carbonates, Canning Basin, Western Australia: confirmation of a seawater REE proxy in ancient limestones. Geochim. Cosmochim. Acta, 68, 263-283.</mixed-citation></citation-alternatives></ref><ref id="cit54"><label>54</label><citation-alternatives><mixed-citation xml:lang="ru">Kamber B.S., Webb G.E. (2001) The geochemistry of Late Archaean microbial carbonate: implications for ocean chemistry and continental erosion history. Geochim. Cosmochim. Acta, 65, 2509-2525.</mixed-citation><mixed-citation xml:lang="en">Nozaki Y., Zhang J., Amakawa H. (1997) The fractionation between Y and Ho in the marine environment. Earth Planet. Sci. Lett., 148(1-2), 329-340.</mixed-citation></citation-alternatives></ref><ref id="cit55"><label>55</label><citation-alternatives><mixed-citation xml:lang="ru">Kuang H-W., Hu X.-F. (2014) Review of molar tooth structure research. J. Palaeogeography, 3, 359-383.</mixed-citation><mixed-citation xml:lang="en">Ovchinnikova G.V., Vasilyeva I.M., Semikhatov M.A., Kuznetsov A.B., Gorokhov I.M., Gorokhovskii B.M., Levskii L.K. (1998) U-Pb systematics of Proterozoic carbonate rocks: the Inzer Formation of the Upper Riphean stratotype (Southern Urals). Stratigr. Geol. Correl. 6, 336-347.</mixed-citation></citation-alternatives></ref><ref id="cit56"><label>56</label><citation-alternatives><mixed-citation xml:lang="ru">Kuznetsov A.B., Bekker A., Ovchinnikova G.V., Gorokhov I.M., Vasilyeva I.M. (2017) Unradiogenic strontium and moderate-amplitude carbon isotope variations in early Tonian seawater after the assembly of Rodinia and before the Bitter Springs Excursion. Prec. Res. 298, 157-173.</mixed-citation><mixed-citation xml:lang="en">Ovchinnikova G.V., Vasilyeva I.M., Semikhatov M.A., Gorokhov I.M., Kuznetsov A.B., Gorokhovskii B.M., Levskii L.R. (2000) The Pb-Pb trail dating of carbonates with open U-Pb systems: the Myn’yar Formation of the Upper Riphean stratotype, Southern Urals. Stratigr. Geol. Correl., 8, 529-543.</mixed-citation></citation-alternatives></ref><ref id="cit57"><label>57</label><citation-alternatives><mixed-citation xml:lang="ru">Lee J.H., Byrne R.H. (1992) Complexation of trivalent rare earth elements (Ce, Eu, Gd, Tb, Yb) by carbonate ions. Geochim. Cosmochim. Acta, 57, 295-302.</mixed-citation><mixed-citation xml:lang="en">Parekh P.P., Moller P., Dulski P., Bausch W.M. (1977) Distribution of trace elements between carbonate and noncarbonate phases of limestone. Earth Planet. Sci. Lett., 34, 39-50.</mixed-citation></citation-alternatives></ref><ref id="cit58"><label>58</label><citation-alternatives><mixed-citation xml:lang="ru">Levashova N.M., Bazhenov M.L., Meert J.G., Kuznetsov N.B., Golovanova I.V., Danukalov K.N., Fedorova N.M. (2013) Paleogeography of Baltica in the Ediacaran: Paleomagnetic and geochronological data from the clastic Zigan Formation, South Urals. Prec. Res., 236, 16-30.</mixed-citation><mixed-citation xml:lang="en">Parfenova T.M., Korovnikov I.V., Eder V.G., Melenevskii V.N. (2017) Organic geochemistry of the Lower Cambrian Sinyaya Formation (northern slope of the Aldan anteclise). Russ. Geol. Geophys., 58(5), 586-599.</mixed-citation></citation-alternatives></ref><ref id="cit59"><label>59</label><citation-alternatives><mixed-citation xml:lang="ru">Love G.D., Grosjean E., Stalvies C., Fike D.A., Grotzinger J.P., Bradley A.S., Kelly A.E., Bhatia M., Meredith W., Snape C.E., Bowring S.A., Condon D.J., Summons R.E. (2009) Fossil steroids record the appearance of Demospongiae during the Cryogenian period. Nature, 457(7230), 718-721.</mixed-citation><mixed-citation xml:lang="en">Pawlowska M.M., Butterfild N.J., Brocks J.J. (2012) Lipid taphonomy in the Proterozoic and the effect of microbial mats on biomarker preservation. Geology, 41(2), 103-106.</mixed-citation></citation-alternatives></ref><ref id="cit60"><label>60</label><citation-alternatives><mixed-citation xml:lang="ru">Luo C., Reitner J. (2014) First report of fossil “keratose” demosponges in Phanerozoic carbonates: preservation and 3-D reconstruction. Naturwissenschaften, 101, 467-477</mixed-citation><mixed-citation xml:lang="en">Peters K.E., Moldowan J.M. (1993) The biomarker Guide: Interpreting molecular fossils in petroleum and ancient sediments. New Jersey: Prentis Hall, Englewood Cliffs, 363 с.</mixed-citation></citation-alternatives></ref><ref id="cit61"><label>61</label><citation-alternatives><mixed-citation xml:lang="ru">Luo C., Reitner J. (2015) “Stromatolites” built by sponges and microbes – a new type of Phanerozoic bioconstruction. Lethaia, 49(4), 555-570.</mixed-citation><mixed-citation xml:lang="en">Petrov A.A. (1984) Uglevodorody nefti [Oil hydrocarbons]. Moscow, Nauka Publ., 264 p. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit62"><label>62</label><citation-alternatives><mixed-citation xml:lang="ru">McCaffrey M.A., Moldowan J.M., Lipton P.A., Summons R.E., Peters K.E., Jeganathan A., Watt D.S. (1994) Paleoenvironmental implications of novel C30 steranes in Precambrian to Cenozoic age petroleum and bitumen. Geochim. Cosmochim. Acta, 58, 529-532.</mixed-citation><mixed-citation xml:lang="en">Petrov P.Y. (2016) Molar tooth structures and origin of peloids in Proterozoic carbonate platforms (Middle Riphean of the Turukhansk Uplift, Siberia). Lithol. Miner. Resour., 51(4), 290-309.</mixed-citation></citation-alternatives></ref><ref id="cit63"><label>63</label><citation-alternatives><mixed-citation xml:lang="ru">Moller P., Bau M. (1993) Rare-earth patterns with positive cerium anomaly in alkaline waters from Lake Van, Turkey. Earth Planet. Sci. Lett., 117(3-4), 671-676</mixed-citation><mixed-citation xml:lang="en">Pollock M.D., Kah L.C., Bartley J.K. (2006) Morphology of molar-tooth structures in Precambrian carbonates: Influence of substrate rheology and implications for genesis. J. Sed. Res., 76, 310-323.</mixed-citation></citation-alternatives></ref><ref id="cit64"><label>64</label><citation-alternatives><mixed-citation xml:lang="ru">. Nosenko T., Schreiber F., Adamska M., Adamski M., Eitel M., Hammel J., Maldonado M., Muller W.E.G., Nickel M., Schierwater B., Vacelet J., Wiens M., Worheide G. (2013) Deep metazoan phylogeny: When different genes tell different stories. Molecular Phylogenetics and Evolution, 67, 223-233.</mixed-citation><mixed-citation xml:lang="en">Putevoditel’ geologicheskoi ekskursii po razrezam verkhnego paleozoya i verkhnego dokembriya zapadnogo sklona Yuzhnogo Urala i Priural’ya. [Guidebook of the geological excursion on the Paleozoic and Upper Precambrian sections of the western slope of the Southern Urals and Cis-Urals] (1995) Ufa, IG, Ufumian Scientific Centre of RAS, 176 p. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit65"><label>65</label><citation-alternatives><mixed-citation xml:lang="ru">Nothdurft L.D., Webb G.E., Kamber B.S. (2004) Rare earth element geochemistry of Late Devonian reefal carbonates, Canning Basin, Western Australia: confirmation of a seawater REE proxy in ancient limestones. Geochim. Cosmochim. Acta, 68, 263-283.</mixed-citation><mixed-citation xml:lang="en">Raaben M.E., Zabrodin V.E. (1972) Vodoroslevaya problematika verkhnego rifeya (stromatolity, onkolity) [Upper Riphean algal problematic fossils (stromatolites, oncolites)]. Moscow, Nauka Publ., 130 p. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit66"><label>66</label><citation-alternatives><mixed-citation xml:lang="ru">Nozaki Y., Zhang J., Amakawa H. (1997) The fractionation between Y and Ho in the marine environment. Earth Planet. Sci. Lett., 148(1–2), 329-340.</mixed-citation><mixed-citation xml:lang="en">Riding R. (2004) Solenopora is a chaetetid sponge, not an alga. Palaeontology, 47(1), 117-122.</mixed-citation></citation-alternatives></ref><ref id="cit67"><label>67</label><citation-alternatives><mixed-citation xml:lang="ru">Parekh P.P., Moller P., Dulski P., Bausch W.M. (1977) Distribution of trace elements between carbonate and noncarbonate phases of limestone. Earth Planet. Sci. Lett., 34, 39-50.</mixed-citation><mixed-citation xml:lang="en">Semikhatov M.A., Chumakov N.M., Kuznetsov A.B. (2015) Isotope age of boundaries between the general stratigraphic subdivisions of the Upper Proterozoic (Riphean and Vendian) in Russia: The evolution of opinions and the current estimate. Stratigr. Geol. Correl., 23(6), 568-579.</mixed-citation></citation-alternatives></ref><ref id="cit68"><label>68</label><citation-alternatives><mixed-citation xml:lang="ru">Pawlowska M.M., Butterfild N.J., Brocks J.J. (2012) Lipid taphonomy in the Proterozoic and the effect of microbial mats on biomarker preservation. Geology, 41(2), 103-106.</mixed-citation><mixed-citation xml:lang="en">Shaw H.F., Wasserburg G.J. (1985) Sm-Nd in marine carbonates and phosphates: Implications for Nd isotopes in seawater and crustal ages. Geochim. Cosmochim. Acta, 49, 503-518.</mixed-citation></citation-alternatives></ref><ref id="cit69"><label>69</label><citation-alternatives><mixed-citation xml:lang="ru">Peters K.E., Moldowan J.M. (1993) The biomarker Guide: Interpreting molecular fossils in petroleum and ancient sediments. New Jersey: Prentis Hall, Englewood Cliffs, 363 с.</mixed-citation><mixed-citation xml:lang="en">Shields G.A. (2002) ”Molar-tooth microspar”: a chemical explanation for its disappearance ~750 Ma. Terra Nova, 14(2), 108-113.</mixed-citation></citation-alternatives></ref><ref id="cit70"><label>70</label><citation-alternatives><mixed-citation xml:lang="ru">ollock M.D., Kah L.C., Bartley J.K. (2006) Morphology of molar-tooth structures in Precambrian carbonates: Influence of substrate rheology and implications for genesis. J. Sed. Res., 76, 310-323.</mixed-citation><mixed-citation xml:lang="en">Shields G.A., Webb G.E. (2004) Has the REE composition of seawater changed over geological time? Chem. Geol., 204, 103-107.</mixed-citation></citation-alternatives></ref><ref id="cit71"><label>71</label><citation-alternatives><mixed-citation xml:lang="ru">Riding R. (2004) Solenopora is a chaetetid sponge, not an alga. Palaeontology, 47(1), 117-122. S</mixed-citation><mixed-citation xml:lang="en">Shields-Zhou G.A., Hill A.C., Macgabhann B.A. (2012) The Cryogenian Period. A Concise Geologic Time Scale / J.G. Ogg, G.M. Ogg, F.M. Gradstein (Eds). Amsterdam, Elsevier, 393-411.</mixed-citation></citation-alternatives></ref><ref id="cit72"><label>72</label><citation-alternatives><mixed-citation xml:lang="ru">haw H.F., Wasserburg G.J. (1985) Sm-Nd in marine carbonates and phosphates: Implications for Nd isotopes in seawater and crustal ages. Geochim. Cosmochim. Acta, 49, 503-518.</mixed-citation><mixed-citation xml:lang="en">Sholkovitz E.R., Landing W.M., Lewis B.L. (1994) Ocean particle chemistry – the fractionation of rare-earth elements between suspended particles and seawater. Geochim. Cosmochim. Acta, 58(6), 1567-1579.</mixed-citation></citation-alternatives></ref><ref id="cit73"><label>73</label><citation-alternatives><mixed-citation xml:lang="ru">Shields G.A. (2002) ”Molar-tooth microspar”: a chemical explanation for its disappearance ~750 Ma. Terra Nova, 14(2), 108-113.</mixed-citation><mixed-citation xml:lang="en">Sinninghe Damsté J.S., van Duin A.C.T., Hollander D., Kohnen M.E.L., de Leeuw J.W. (1995) Early diagenesis of bacteriohopanepolyol derives: Formation of fossil homohopanoids. Geochim. Cosmochim. Acta, 59, 5141-5147.</mixed-citation></citation-alternatives></ref><ref id="cit74"><label>74</label><citation-alternatives><mixed-citation xml:lang="ru">Shields G.A., Webb G.E. (2004) Has the REE composition of seawater changed over geological time? Chem. Geol., 204, 103-107.</mixed-citation><mixed-citation xml:lang="en">Smith A.G. (2016) A review of molar-tooth structures with some speculations on their origin. Belt Basin: Window to Mesoproterozoic Earth / MacLean J.S., Sears J.W. (Eds). Geol. Soc. Am. Spec. Paper, 522, 71-99.</mixed-citation></citation-alternatives></ref><ref id="cit75"><label>75</label><citation-alternatives><mixed-citation xml:lang="ru">Shields-Zhou G.A., Hill A.C., Macgabhann B.A. (2012) The Cryogenian Period. A Concise Geologic Time Scale (J.G. Ogg, G.M. Ogg, F.M. Gradstein Eds). Amsterdam: Elsevier, 393-411.</mixed-citation><mixed-citation xml:lang="en">Stratotip rifeya. Paleontologiya. Paleomagnetizm. [Stratotype of the Riphean: Paleontology and Paleomagnetism] (1982). (Keller B.M. Ed.). Moscow, Nauka Publ., 176 p. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit76"><label>76</label><citation-alternatives><mixed-citation xml:lang="ru">Sholkovitz E.R., Landing W.M., Lewis B.L. (1994) Ocean particle chemistry – the fractionation of rare-earth elements between suspended particles and seawater. Geochim. Cosmochim. Acta, 58(6), 1567-1579.</mixed-citation><mixed-citation xml:lang="en">Stratotip rifeya. Stratigrafiya. Geokhronologiya [Stratotype of the Riphean: Stratigraphy and Geochronology] (1983). (Eds: Keller B.M., Chumakov N.M.). Moscow, Nauka Publ., 184 p. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit77"><label>77</label><citation-alternatives><mixed-citation xml:lang="ru">Sinninghe Damsté J.S., van Duin A.C.T., Hollander D., Kohnen M.E.L., de Leeuw J.W. (1995) Early diagenesis of bacteriohopanepolyol derives: Formation of fossil homohopanoids. Geochim. Cosmochim. Acta, 59, 5141-5147.</mixed-citation><mixed-citation xml:lang="en">Tang H.-S., Chen Y.-J., Santosh M., Zhong H., Yang T. (2013) REE geochemistry of carbonates from the Guanmenshan Formation, Liaohe Group, NE Sino-Korean Craton: Implications for seawater compositional change during the Great Oxidation Event. Prec. Res., 227, 316-336.</mixed-citation></citation-alternatives></ref><ref id="cit78"><label>78</label><citation-alternatives><mixed-citation xml:lang="ru">Smith A.G. (2016) A review of molar-tooth structures with some speculations on their origin. Belt Basin: Window to Mesoproterozoic Earth (MacLean J.S., Sears J.W. (Eds). Geol. Soc. Am. Spec. Paper 522, 71-99.</mixed-citation><mixed-citation xml:lang="en">Taylor M.W., Radax R., Steger D., Wagner M. (2007) Sponge-associated microorganisms: evolution, ecology, and biotechnological potential. Microbiol. Mol. Biol. Rev., 71, 295-347.</mixed-citation></citation-alternatives></ref><ref id="cit79"><label>79</label><citation-alternatives><mixed-citation xml:lang="ru">Tang H.-S., Chen Y.-J., Santosh M., Zhong H., Yang T. (2013) REE geochemistry of carbonates from the Guanmenshan Formation, Liaohe Group, NE Sino-Korean Craton: Implications for seawater compositional change during the Great Oxidation Event. Prec. Res., 227, 316-336.</mixed-citation><mixed-citation xml:lang="en">Taylor S.R., McLennan S.M. (1985) The Continental Crust: Its Composition and Evolution. Oxford, Blackwell, 312 p.</mixed-citation></citation-alternatives></ref><ref id="cit80"><label>80</label><citation-alternatives><mixed-citation xml:lang="ru">Taylor M.W., Radax R., Steger D., Wagner M. (2007) Sponge-associated microorganisms: evolution, ecology, and biotechnological potential. Microbiol. Mol. Biol. Rev., 71, 295-347.</mixed-citation><mixed-citation xml:lang="en">Terakado Y., Masuda A. (1988) The coprecipitation of rare-earth elements with calcite and aragonite. Chem. Geol., 69, 103-110.</mixed-citation></citation-alternatives></ref><ref id="cit81"><label>81</label><citation-alternatives><mixed-citation xml:lang="ru">Taylor S.R., McLennan S.M. (1985) The Continental Crust: Its Composition and Evolution. Oxford: Blackwell, 312 p.</mixed-citation><mixed-citation xml:lang="en">Van Kranendonk M.J., Webb G.E., Kamber B.S. (2003) New geological and trace element evidence from 3.45 Ga stromatolitic carbonates in the Pilbara Craton: support of a marine, biogenic origin and for a reducing Archaean ocean. Geobiology, 1, 91-108.</mixed-citation></citation-alternatives></ref><ref id="cit82"><label>82</label><citation-alternatives><mixed-citation xml:lang="ru">Terakado Y., Masuda A. (1988) The coprecipitation of rareearth elements with calcite and aragonite. Chem. Geol., 69, 103-110.</mixed-citation><mixed-citation xml:lang="en">Vassoevich N.B. (1973) The main laws that characterize the organic matter of modern and fossil sediments. Priroda organicheskogo veshchestva sovremennykh i iskopaemykh osadkov [The nature of the organic matter of modern and fossil sediments]. Moscow, Nauka Publ., 11-59. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit83"><label>83</label><citation-alternatives><mixed-citation xml:lang="ru">Van Kranendonk M.J., Webb G.E., Kamber B.S. (2003) New geological and trace element evidence from 3.45 Ga stromatolitic carbonates in the Pilbara Craton: support of a marine, biogenic origin and for a reducing Archaean ocean. Geobiology, 1, 91-108.</mixed-citation><mixed-citation xml:lang="en">Webb G.E., Kamber B.S. (2000) Rare earth elements in Holocene reefal microbialites: a new shallow seawater proxy. Geochim. Cosmochim. Acta, 64, 1557-1565. Wilkinson C.R. (1979) Nutrient translocation from symbiotic cyanobacteria to coral reef sponges. Biologie des Spongiarires, 291. (Lévi C., Boury-Esnault N. Eds). Colloques du Centre National Reserche Scientifique, Paris: 373-380.</mixed-citation></citation-alternatives></ref><ref id="cit84"><label>84</label><citation-alternatives><mixed-citation xml:lang="ru">Webb G.E., Kamber B.S. (2000) Rare earth elements in Holocene reefal microbialites: a new shallow seawater proxy. Geochim. Cosmochim. Acta, 64, 1557-1565.</mixed-citation><mixed-citation xml:lang="en">Wright J., Schrader H., Holser W.T. (1987) Paleoredox variations in ancient oceans recorded by rare earth elements in fossil Apatite. Geochim. Cosmochim. Acta, 51, 631-644.</mixed-citation></citation-alternatives></ref><ref id="cit85"><label>85</label><citation-alternatives><mixed-citation xml:lang="ru">Wilkinson C.R. (1979) Nutrient translocation from symbiotic cyanobacteria to coral reef sponges. Biologie des Spongiarires, 291. Lévi C., Boury-Esnault N. (Eds). Colloques du Centre National Recherche Scientifique, Paris, 373-380.</mixed-citation><mixed-citation xml:lang="en">Zaitseva T.S., Gorokhov I.M., Kuznetsov A.B., Mel’nikov N.N., Yakovleva O.V., Ivanovskaya T.A., Semikhatov M.A., Arakelyants M.M. (2008) Mössbauer characteristics, mineralogy and isotopic age (Rb-Sr, K-Ar) of Upper Riphean glauconites from the UK Formation, the southern Urals. Stratigr. Geol. Correl., 16(3), 227-247.</mixed-citation></citation-alternatives></ref><ref id="cit86"><label>86</label><citation-alternatives><mixed-citation xml:lang="ru">Wright J., Schrader H., Holser W.T. (1987) Paleoredox variations in ancient oceans recorded by rare earth elements in fossil Apatite. Geochim. Cosmochim. Acta, 51, 631-644.</mixed-citation><mixed-citation xml:lang="en">Zaitseva T.S., Gorokhov I.M., Kuznetsov A.B., Konstantinova G.V., Turchenko T.L., Melnikov N.N. (2012) Rb-Sr isotopic systematics of clay minerals from sedimentary rocks of the Vendian of the Southern Urals. Leningrad School of Lithology. V. II. St. Petersburg, SPbSU Publ., 57-59. (In Russian)</mixed-citation></citation-alternatives></ref><ref id="cit87"><label>87</label><citation-alternatives><mixed-citation xml:lang="ru">Zhong S., Mucci A. (1995) Partitioning of rare earth elements (REEs) between calcite and seawater solutions at 25°C and 1 atm, and high dissolved REE concentrations. Geochim. Cosmochim. Acta, 59, 443-453.</mixed-citation><mixed-citation xml:lang="en">Zhong S., Mucci A. (1995) Partitioning of rare earth elements (REEs) between calcite and seawater solutions at 25°C and 1 atm, and high dissolved REE concentrations. Geochim. Cosmochim. Acta, 59, 443-453.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
