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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">litosphere</journal-id><journal-title-group><journal-title xml:lang="ru">Литосфера</journal-title><trans-title-group xml:lang="en"><trans-title>LITHOSPHERE (Russia)</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1681-9004</issn><issn pub-type="epub">2500-302X</issn><publisher><publisher-name>A.N. Zavaritsky Institute of Geology and Geochemistry</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.24930/1681-9004-2019-19-1-30-47</article-id><article-id custom-type="elpub" pub-id-type="custom">litosphere-1144</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Статьи</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>Articles</subject></subj-group></article-categories><title-group><article-title>Геохимические особенности и условия образования раннедевонских кремнисто-глинистых сланцев разреза Ишкильдино и подстилающих их базальтов (восточный склон Южного Урала)</article-title><trans-title-group xml:lang="en"><trans-title>Geochemical features and formation conditions of Early-Devonian cherty-argillaceous shales and the underlying basalts in the Ishkildino section (eastern slope of the Southern Urals)</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Фазлиахметов</surname><given-names>А. М.</given-names></name><name name-style="western" xml:lang="en"><surname>Fazliakhmetov</surname><given-names>A. M.</given-names></name></name-alternatives><bio xml:lang="ru"/><bio xml:lang="en"/><email xlink:type="simple">famrb@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru">Институт геологии Уфимского научного центра РАН<country>Россия</country></aff><aff xml:lang="en">Institute of geology Ufa Science Centre of RAS<country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2019</year></pub-date><pub-date pub-type="epub"><day>16</day><month>03</month><year>2019</year></pub-date><volume>0</volume><issue>1</issue><fpage>30</fpage><lpage>47</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Фазлиахметов А.М., 2019</copyright-statement><copyright-year>2019</copyright-year><copyright-holder xml:lang="ru">Фазлиахметов А.М.</copyright-holder><copyright-holder xml:lang="en">Fazliakhmetov A.M.</copyright-holder><license license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://www.lithosphere.ru/jour/article/view/1144">https://www.lithosphere.ru/jour/article/view/1144</self-uri><abstract><sec><title>Предмет исследований</title><p>Предмет исследований. В Западно-Магнитогорской зоне Южного Урала на окраине д. Ишкильдино обнажена последовательность базальтов и залегающих на них кремней и кремнисто-глинистых сланцев. Предполагается ордовикский возраст базальтов. Возраст вышележащих отложений – силурийско(?)–раннедевонский (до конодонтовой зоны excavatus включительно). Реконструкция условий формирования всех пород данного разреза по геохимическим данным является целью исследований.</p></sec><sec><title>Материалы и методы</title><p>Материалы и методы. Проанализировано 5 образцов базальтов (методы РФА и ИСП-МС), 27 – кремнисто-глинистых сланцев и 10 – кремней (методы РФА и ИСП-АЭС).</p></sec><sec><title>Результаты</title><p>Результаты. По соотношению кремнекислоты и щелочей вулканогенные породы нижней части разреза являются базальтами и трахибазальтами. Их геохимический состав соответствует N-MORB и близок к составу базальтов поляковской свиты (средний–верхний ордовик). Судя по соотношению макроэлементов, кремнисто-глинистые сланцы состоят из кремнезема и гидрослюды с незначительной примесью органического вещества, гётита, обломочных зерен кварц-полевошпатового состава и др. Степень выветривания осадочного материала, в соответсвии с величиной модулей CIA, CIW, ICV, умеренная. Величины модулей Страхова, Бострёма и цериевой аномалии соответствуют осадкам без примеси продуктов подводных гидротерм. Лишь в единичных пробах верхней части разреза по величинам модуля Страхова можно предполагать присутствие гидротермального вещества. Величины Cr/Al, V/Al и Zr/Al соответствуют отложениям глубоководных зон, удаленных от побережий континентов, островных дуг, базальтовых островов и областей, прилегающих к срединно-океаническим хребтам. Значения Ni/Co, V/Cr, Mo/Mn большинства проб свойственны отложениям хорошо аэрируемых бассейнов. В верхней части разреза, сопоставимой с конодонтовыми зонами kitabicus и excavatus, в нескольких образцах величины Ni/Co, V/Cr, Mo/Mn отвечают отложениям восстановительных обстановок. Предполагается, что их существование сопряжено с глобальным событием Bazal Zlichov.</p></sec><sec><title>Выводы</title><p>Выводы. В доэмсских кремнисто-глинистых сланцах нет признаков вулканической деятельности в прилегающих областях. Изученные отложения соответствуют центральной части Уральского палеоокеана.</p></sec></abstract><trans-abstract xml:lang="en"><sec><title>Research subject</title><p>Research subject. The West Magnitogorsk zone of the Southern Urals in the vicinity of the Ishkildino village features a subaerially exposed basaltic sequence superposed by cherts and siliceous-clay shales. The basalts and the overlying shales are assumed to have formed during the Ordovician and Silurian (?)–Early Devonian (up to the conodont zone excavates inclusive) periods, respectively. The aim of this research was to reconstruct, using geochemical data, the conditions under which the rocks present in this geological location were formed.</p></sec><sec><title>Materials and methods</title><p>Materials and methods. Five samples of the basalts (XRD and ICP-MS methods), 27 samples of the siliceous-clay shales and 10 samples of the cherts (XRD and ICP-AES methods) were analyzed.</p></sec><sec><title>Results</title><p>Results. According to the ratio of SiO2, Na2O and K2O, the volcanic rocks from the lower part of the section are represented by basalts and trachybasalts. Their geochemical composition corresponds to the N-MORB and is established to be similar to that of the basalts in the Polyakovskaya formation (the Middle–Upper Ordovician). In terms of main elements, the shales under study consist of quartz and illite with a slight admixture of organic matter, goethite, quartzfeldspar fragments, etc. The degree of the sedimentary material weathering according to the CIA, CIW and ICV index values is shown to be moderate. The values of Strakhov’s and Boström’s moduli correspond to sediments without the admixture of underwater hydrothermal vent products. The values of Cr/Al, V/Al and Zr/Al correspond to those characteristic of deposits in deep-water zones remote from the coasts of passive and active continental margins, basalt islands and areas adjacent to mid-ocean ridges. For most samples, the values of Ni/Co, V/Cr, Mo/Mn are typical of deposits formed under oxidative conditions. However, several samples from the upper part of the section, which is comparable to the kitabicus and excavatus conodont zones, demonstrate the Ni/Co, V/Cr, and Mo/Mn values corresponding to deposits formed under reducing atmospheres. An assumption is made that the existence of these deposits can be associated with the Bazal Zlichov event.</p></sec><sec><title>Conclusion</title><p>Conclusion. The investigated pre-Emsian shales have shown no signs of volcanic activity in the adjacent areas. The studied deposits are established to correspond to the central part of the Ural Paleoocean.</p></sec></trans-abstract><kwd-group xml:lang="ru"><kwd>кремни</kwd><kwd>глинистые сланцы</kwd><kwd>базальты</kwd><kwd>N-MORB</kwd><kwd>ордовик</kwd><kwd>силур</kwd><kwd>нижний девон</kwd><kwd>ранний эмс</kwd><kwd>окислительно-восстановительные обстановки</kwd><kwd>океаническая кора</kwd><kwd>Bazal Zlihov</kwd></kwd-group><kwd-group xml:lang="en"><kwd>cherts</kwd><kwd>shales</kwd><kwd>basalts</kwd><kwd>N-MORB</kwd><kwd>the Ordovician</kwd><kwd>the Silurian</kwd><kwd>the Lower Devonian</kwd><kwd>the Early Emsian</kwd><kwd>redox conditions</kwd><kwd>oceanic crust</kwd><kwd>Bazal Zlihov</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Аристов В.А., Ружинцев С.В., Дегтярев К.Е., Борисенок Д.В., Латышева И.В. 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